Medium modification of hadrons

I discuss pertinent aspects of the phase structure of strongly-interacting matter and their relation to the medium modifications of mesons. Special attention is paid to the critical endpoint in the phase diagram and the electromagnetic response in its vicinity.     

Expanded Prussian Blue Analogue Based on Octahedral {Nb<Subscript>6</Subscript>} Clusters and {K<Subscript>2</Subscript>} Dimers as Nodes

Abstract  The preparation, structures, and characterization of two new compounds containing octahedral niobium cyanochloride clusters as building units and (Et₄N)⁺ as cation are reported. The reaction between Nb₆Cl₁₄ · 8H₂O, KCN and (Et₄N)Cl led to the formation of (Et₄N)₄[Nb₆Cl₁₂(CN)₆] · 2.67H₂O (1) which crystallizes in triclinic P-1 space group (No. 2) with a = 12.552(2), b = 12.818(2), c = 12.919(2) ?, α = 105.157(3)°, β = 104.188(3)°, γ = 117.390(2)°, V = 1611.7(5) ?³ and Z = 1. 1 has a 2D hydrogen-bonded layer structure based on [Nb₆Cl₁₂(CN)₆]⁴⁻ units connected through hydrogen bonding between cyanide ligands and solvent water molecules. In the presence of large excess of K⁺ ions, similar reaction leads to formation of K₂(Et₄N)₂[Nb₆Cl₁₂(CN)₆] (2) which crystallizes in the tetragonal I4/m space group (No. 87) with a = b = 10.9597(3), c = 19.178(1) ?, V = 2303.6(2) ?³ and Z = 2. Its 3D structure is based on [Nb₆Cl₁₂]²⁺ and [K₂]²⁺ nodes bridged by cyanide ligands to form an expanded Prussian blue type framework with (Et₄N)⁺ acting as charge compensating ions. Index Abstract  An expanded Prussian blue type 3D framework based on hexanuclear {Nb₆} and dinuclear {K₂} units which are bridged by cyanide linker was synthesized and characterized. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Thin disk laser—Energy scaling

A time resolved numerical model of the interaction between pump absorption, excitation and amplified spontaneous emission (ASE) for the Thin Disk laser design was developed. The model accounts for the spectral distribution of the spontaneous emission, the spectral and spatial distribution of emission and absorption and the spectral and angular transmission of surfaces or coatings.     

Uniformization of {\mathcal {G}}-bundles

We show some of the conjectures of Pappas and Rapoport concerning the moduli stack Bun_G{{\rm Bun}_\mathcal {G}} of G{\mathcal {G}}-torsors on a curve C, where G{\mathcal {G}} is a semisimple Bruhat-Tits group scheme on C. In particular we prove the analog of the uniformization theorem of Drinfeld-Simpson in this setting. Furthermore we apply this to compute the connected components of these moduli stacks and to calculate the Picard group of Bun_G{{\rm Bun}_\mathcal {G}} in case G{\mathcal {G}} is simply connected.     

Large Eddy Simulations and Experiments of Flow Around Finite-Height Cylinders

The paper presents experimental and numerical results for the flow around a surface-mounted circular cylinder at the two height-to-diameter ratios of 2.5 and 5. The Reynolds number based on approach flow velocity and cylinder diameter is 43,000 and 22,000 for these two cases and the boundary layer of the approach flow has a thickness of about 10% of the cylinder height. The experiments comprise both flow visualizations with dye and laser Doppler velocimeter measurements of all mean velocity and fluctuation components. The numerical study is performed by an elaborate large eddy simulation on a staggered Cartesian grid using the immersed boundary method. The instantaneous flow behaviour including the shedding is analysed with information based on animations. For the long cylinder alternating shedding is found to occur over most of the height while for the shorter cylinder the shedding is observed mainly near the ground where it is also mostly alternating but intermittently also symmetrical. The mean-flow behaviour is analysed with the aid of streamlines and contour plots of mean-velocity and fluctuation components in various planes and a detailed comparison of LES and LDV results is provided, showing generally good agreement. The LES with very fine resolution near the free end allow a detailed study of the complex flow in this region with owl-face topology on the end wall previously observed in experiments. Behind the cylinder, the longitudinal recirculation region, the downstream development of tip vortices and the emergence of trailing vortices further downstream are analysed. The sum of the results, together with those from previous studies that were reviewed extensively, provides a comprehensive picture of the very complex flow behaviour.     

A modified lead–matrix separation procedure shown for lead isotope analysis in Trojan silver artefacts as an example

A modified Pb–matrix separation procedure using NH₄HCO₃ solution as eluent has been developed and validated for determination of Pb isotope amount ratios by thermal ionization mass spectrometry. The procedure is based on chromatographic separation using the Pb·Spec resin and an in-house-prepared NH₄HCO₃ solution serving as eluent. The advantages of this eluent are low Pb blanks (<40 pg?mL^?1) and the property that NH₄HCO₃ can be easily removed by use of a heating step (>60 °C). Pb recovery is >95 % for water samples. For archaeological silver samples, however, the Pb recovery is reduced to approximately 50 %, but causes no bias in the determination of Pb isotope amount ratios. The validated procedure was used to determine lead isotope amount ratios in Trojan silver artefacts with expanded uncertainties (k?=?2) <0.09 %.     

Micro-Raman study of copper hydroxychlorides and other corrosion products of bronze samples mimicking archaeological coins

Three bronze samples created by CNR-ISMN (National Research Council—Institute of Nanostructured Materials) to be similar to Punic and Roman coins found in Tharros (OR, Sardinia, Italy) were studied to identify the corrosion products on their surfaces and to evaluate the reliability of the reproduction process. Micro-Raman spectroscopy was chosen to investigate the corroded surfaces because it is a non-destructive technique, it has high spatial resolution, and it gives the opportunity to discriminate between polymorphs and to correlate colour and chemical composition. A significant amount of green copper hydroxychlorides (Cu₂(OH)₃Cl) was detected on all the coins. Their discrimination by Raman spectroscopy was challenging because the literature on the topic is currently confusing. Thus, it was necessary to determine the characteristic peaks of atacamite, clinoatacamite, and the recently discovered anatacamite by acquiring Raman spectra of comparable natural mineral samples. Clinoatacamite, with different degrees of order in its structure, was the major component identified on the three coins. The most widespread corrosion product, besides hydroxychlorides, was the red copper oxide cuprite (Cu₂O). Other corrosion products of the elements of the alloy (laurionite, plumbonacrite, zinc carbonate) and those resulting from burial in the soil (anatase, calcite, hematite) were also found. This study shows that identification of corrosion products, including discrimination of copper hydroxychlorides, could be accomplished by micro-Raman on valuable objects, for example archaeological findings or works of art, avoiding any damage because of extraction of samples or the use of a destructive analytical technique.