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51.
Knecht MR Garcia-Martinez JC Crooks RM 《Langmuir : the ACS journal of surfaces and colloids》2005,21(25):11981-11986
We report the synthesis, characterization, and extraction of Au dendrimer-encapsulated nanoparticles (DENs) prepared in organic solvents. DENs composed of 31 and 55 Au atoms were prepared using organic solvents and poly(amidoamine) (PAMAM) dendrimer templates modified on their periphery with dodecyl groups. The spectral and microscopic properties of the resulting materials were identical to those prepared using water-soluble PAMAM dendrimers. It was possible to extract the organic-soluble DENs into water using the water-soluble thiols tiopronin and glutathione. The properties of the resulting monolayer-protected clusters were nearly identical to those of the precursor DENs. A mechanistic model for the extraction process is discussed. The synthetic methodology reported here provides a convenient method for preparing DENs of non noble metals such as Ni and Fe. 相似文献
52.
Summary Cobalt(II), nickel(II) and copper(II) complexes [M(CM)2]X2 (X = BF4 or NO3) have been prepared with cimetidine (CM). Powder data, molar conductivities, magnetic moments, i.r. and electronic spectra support apseudo-octahedral stereochemistry with MN2N
2
S2 chromophore and tentative structures are proposed for the complexes. Their properties are compared with these of previously prepared complexes. 相似文献
53.
Benito Alcaide Gerardo Escobar JoséL. González-Simó Carmen López-Mardomingo Rafael Pérez-Ossorio Joaquin Plumet 《Tetrahedron letters》1982,23(19):2033-2036
Total stereoselectivity is observed in the sodium borohydride reduction of α-aminodeoxybenzoins and their hydrochlorides in various hydroxylic solvents. RS - SR isomer (erythro) was the only aminoalcohol obtained. 相似文献
54.
The kinetics of the permanganate oxidation of formic acid in aqueous perchloric acid has been studied. The results indicate that this reaction is autocatalyzed by both manganese(II) ion (formed as a reaction product) and colloidal manganese dioxide (formed as an intermediate). The apparent rate constants corresponding to the noncatalytic and autocatalytic reaction pathways are given, respectively, by the following equations The activation energies associated with the true rate constants, ??, ??, ??, ??, ??, and ?? are 37.2, 62.5, 70.9, 52.5, 40.8, and 59.9 kJ mol?1, respectively. The percentage of the total reaction corresponding to each pathway is given for typical experimental conditions. Mechanisms in agreement with the kinetic data are proposed for the six different reaction pathways observed. 相似文献
55.
The differences in color coordinates obtained from the use of different spectral features in the calculation are studied. Seven groups of food (olive oil, vanilla milkshake, brandy, honey, grape juice, vinegar, and orange juice) and an anthocyanin petunidin solution (natural pigment present in several vegetables) with different pH values were selected. Tristimulus values were calculated by considering the different sources of errors (truncation, abridgement, or different bandwidths). Results obtained were corrected by using the methods recommended (see References). These methods of abridgment work well in general, although in some circumstances (20 nm bandwidth or larger), specific spectral weighting functions have to be used to obtain a negligible error. Therefore, it is interesting to know how much difference can be expected from those factors in order to avoid confusion between color differences attributable to instruments and those attributable to actual color changes. 相似文献
56.
The ammonium removal efficiency (ARE) and cell viability was investigated in freshly isolated rat hepatocytes exposed to increasing ammonium loads (0.1-2.0 mM). No difference was observed in both ARE and cell viability at the different ammonium concentrations tested. Storage of hepatocytes at 0 degrees C for 72 hours inhibited ammonium removal and urea synthesis. Rewarming of cells at 37 degrees C for 120 min was followed by an ARE fully comparable to freshly isolated hepatocytes. These data indicated that cold preservation of rat hepatocytes for 3 days in UW followed by a rewarming is associated with normal ammonium detoxification efficiency. 相似文献
57.
We devised a simple method for determining the cryoprotectant agents 1,4-butanediol or 2,3-butanediol in isolated rat hepatocytes. After extraction of of hepatocytes with water (containing internal standard - ethylene glycol 1.25 mg/mL) the diol content was analyzed by gas chromatography. The method shows a linear response in the range 0.125 to 2.50 mg/mL for 1,4-butanediol and 0.25 to 3.75 mg/mL for 2,3-butanediol. The accuracy and precision of the method were evaluated and the coefficients of variation were found to be within = 6.0 %. The recoveries from hepatocyte samples containing 0.50, 1.00 and 2.00 mg/mL were 91.0 to 108 % for 1,4-butanediol and 80.6 to 100.3 % for 2,3-butanediol, respectively. This method allowed the determination of the intracellular concentration of diols in hepatocytes preserved for up to 120 hours at - 4 (C in UW solution + 8 % w/v 1,4-butanediol (or 2,3-butanediol). 相似文献
58.
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60.
Alexandre S. Shcherbakov A.Yu. Kosarsky Pedro Moreno Zarate Joaquin Campos Acosta Yurij V. Il’in Il’ya S. Tarasov 《Optik》2011,122(2):136-141
The specific approach to characterizing the train-average parameters of low-power picosecond optical pulses with the frequency chirp, arranged in high-repetition-frequency trains, in both time and frequency domains is elaborated for the important case when the semiconductor laser is matched by an external single-mode fiber cavity and operates in the active mode-locking regime. This approach involves the joint Wigner time-frequency distributions, which can be created for those pulses due to exploitation of a novel interferometric technique. Practically, the InGaAsP/InP-heterolaser generating at the wavelength 1320 nm was used during the experiments carried out and an opportunity of reconstructing the corresponding joint Wigner time-frequency distributions was successfully demonstrated. 相似文献