Current Status of the X + C2H6 [X ≡ H,F(2P), Cl(2P), O(3P), OH] Hydrogen Abstraction Reactions: A Theoretical Review

This paper is a detailed review of the chemistry of medium-size reactive systems using the following hydrogen abstraction reactions with ethane, X + C₂H₆ → HX + C₂H₅; X ≡ H, F(²P), Cl(²P), O(³P) and OH, and focusing attention mainly on the theoretical developments. These bimolecular reactions range from exothermic to endothermic systems and from barrierless to high classical barriers of activation. Thus, the topography of the reactive systems changes from reaction to reaction with the presence or not of stabilized intermediate complexes in the entrance and exit channels. The review begins with some reflections on the inherent problems in the theory/experiment comparison. When one compares kinetics or dynamics theoretical results with experimental measures, one is testing both the potential energy surface describing the nuclei motion and the kinetics or dynamics method used. Discrepancies in the comparison may be due to inaccuracies of the surface, limitations of the kinetics or dynamics methods, and experimental uncertainties that also cannot be ruled out. The paper continues with a detailed review of some bimolecular reactions with ethane, beginning with the reactions with hydrogen atoms. The reactions with halogens present a challenge owing to the presence of stabilized intermediate complexes in the entrance and exit channels and the influence of the spin-orbit states on reactivity. Reactions with O(³P) atoms lead to three surfaces, which is an additional difficulty in the theoretical study. Finally, the reactions with the hydroxyl radical correspond to a reactive system with ten atoms and twenty-four degrees of freedom. Throughout this review, different strategies in the development of analytical potential energy surfaces describing these bimolecular reactions have been critically analyzed, showing their advantages and limitations. These surfaces are fitted to a large number of ab initio calculations, and we found that a huge number of calculations leads to accurate surfaces, but this information does not guarantee that the kinetics and dynamics results match the experimental measurements.     

Kinetic and thermodynamic aspects of miniemulsion copolymerization

Miniemulsion polymerization involves initiation of polymerization in preformed stable monomer emulsion droplets with average droplet diameter of 50–500 nm. At the end of the polymerization, only a fraction of the initial number of monomer droplets become polymer particles. The emulsifier system used for the preparation of such emulsions comprises a mixture of ionic surfactant and a fatty alcohol or long chain alkane (termed cosurfactant). The cosurfactant is essential for the formation of stable emulsion droplets and in addition it plays an important role in the interparticle monomer transport. Kinetic results are presented on conventional emulsion and miniemulsion copolymerization of different pairs of monomers, showing the main differences for both processes. These differences were related to the particle formation mechanism and the influence of the cosurfactant in the miniemulsion process. A theoretical model was developed, based on mass balances and equilibrium thermodynamics, which was found to describe accurately the experimentally generated data on comonomer distribution during the course of the copolymerization process and the interdroplet mass transport process.