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41.
We study linear dynamical systems with multidimensional time in Banach spaces. Using Taylor functional calculus we prove that under additional assumptions hyperbolic systems have shadowing property. 相似文献
42.
43.
Orotic acid (vitamin B13) is a key intermediate in biosynthesis of the pyrimidine nucleotides in living organisms, moreover, it may serve as the biological carrier for some metal ions. cis-Diammine(orotato)platinum(II), cis-[Pt(C5H2N2O4)(NH3)2] can be considered as a new potential cisplatin analogue. The FT-Raman and FT-IR spectra of the title complex are reported, for the first time. The molecular structure, vibrational frequencies, and the theoretical infrared and Raman intensities have been calculated by the density functional mPW1PW91 method. The detailed vibrational assignment has been made on the basis of the calculated potential energy distribution. The theoretically predicted IR and Raman spectra show very good agreement with experiment. Natural bond orbital (NBO) analyses were performed for cisplatin, carboplatin and the title complex. The results provided new data on the nature of platinum–ligand bonding in these compounds. Strong intramolecular hydrogen bond between the orotate ligand and the coordinated ammonia group stabilizes the structure of the platinum(II) complex. Thus, it is suggested that the orotate ligand in the title complex is more inert to the substitution reactions than the chloride ligands in cisplatin. 相似文献
44.
45.
Tomasz Stawski Janusz Szklarzewicz Krzysztof Lewiński 《Transition Metal Chemistry》2006,31(3):353-361
The single crystal X-ray structure of (AsPh4)[W(bpy)(CN)6] is described. The structure of octa- and hepta-coordinated intermediates of substitutional photolysis of [Mo(CN)8]4− ion in aqueous media were determined by performing semi-empirical calculations. On the basis of obtained results as well
as on empirical data the photolysis scheme has been postulated. 相似文献
46.
Zdzisław Denkowski Leszek Gasiński Nikolaos S. Papageorgiou 《Journal of Global Optimization》2006,34(3):317-337
We study a resonant semilinear elliptic hemivariational inequality. Under some assumptions of strong resonance on the Clarke
subdifferential of the superpotential, and using nonsmooth critical point theory, the existence of a nontrivial solution of
the problem is shown.
This paper has been partially supported by the State Committee for Scientific Research of Poland (KBN) under research grants
no. 2 P03A 003 25 and no. 4 T07A 027 26. 相似文献
47.
We give characterizations of continuous distributions in terms of moments of order statistics when the sample size is random.
In particular, we characterize uniform, exponential, Pareto, and logistic distributions. Special cases of a random sample
size (logarithmic series, geometrical, truncated binomial, truncated negative binomial, and truncated Poisson distribution)
are also considered.
Proceedings of the XVII Seminar on Stability Problems for Stochastic Models, Kazan, Russia, 1995, Part I. 相似文献
48.
49.
50.
Boena N. Kolarz Maria Wojaczyska Jan Kaczmarczyk Teresa Siemieniewska Kazimierz Tomkw 《Journal of Polymer Science.Polymer Physics》1994,32(12):1977-1990
Sulfonic cation exchangers with two ion exchange group concentrations (0.5 and 2.4 mmol/g, samples A and B, respectively) were obtained by sulfonation of a porous styrene (S) and divinylbenzene (DVB) copolymer with chlorosulfonic acid. Strong thermal decomposition of the sulfonated copolymer A, accompanied by significant changes in its porous structure, starts at ca. 400°C. The char has no sulfonic groups. After heat treatment at 400°C in steam, a sorbent was obtained (yield 65%) that shows higher phenol sorption than the untreated sample when related to the bed volume. The chlorosulfonic derivatives of the initial copolymer were less thermally resistant than the sulfonic ones obtained by hydrolysis. Pyrolysis of the cation exchanger B, in its H+ and Ca2+ forms, was carried out at 900°C (yield of both chars close to 30%). By subsequent steam activation at 800°C to a 50% burn-off of the char, sorbents with well-developed, but distinctly different, porous structures were obtained. The activated char from the sulfonated copolymer in its hydrogen form was highly microporous and indicated an effective surface area of 1180 m2/g. However, because of a low contribution of mesopores, its ability to adsorb phenol from the liquid phase was not very high. The activated char from the calcium-doped copolymer, indicating a smaller surface area (580 m2/g) but characterized by a well-developed mesoporosity, was a better sorbent for phenol. © 1994 John Wiley & Sons, Inc. 相似文献