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Pawel Uznanski Agnieszka Walkiewicz-Pietrzykowska Krzysztof Jankowski Joanna Zakrzewska Aleksander M. Wrobel Jacek Balcerzak Jacek Tyczkowski 《应用有机金属化学》2020,34(8):e5674
Amorphous silicon oxycarbide (a-SiOC:H) films produced by remote plasma RPCVD from diethoxymethylsilane (DEMS) were characterized in terms of their basic properties related to the coatings deposited using conventional plasma enhanced PECVD method. The effect of substrate temperature (TS) on the growth rate, chemical composition, structure, and properties of resulting a-SiOC:H films is reported. Film growth is an adsorption-controlled process, wherein two mechanisms can be distinguished with a transition at about TS=70°C. Depending on the temperature, films of different nature can be obtained, from polymer-like to highly crosslinked material with C-Si-O network. The chemical structure of a-SiOC:H films was characterized by FTIR, 13C and 29Si solid-state NMR, and X-ray photoelectron spectroscopes. The a-SiOC:H films were also characterized in terms of their density, refractive index, surface morphology, conformality of coverage, hardness, adhesion to a substrate, and friction coefficient. The films were found to be morphologically homogeneous materials exhibiting good conformality of coverage and small surface roughness. Their refractive index exhibits anomalous effect revealing a minimum value at TS=125°C. Due to their exceptional physical properties a-SiOC:H films produced by RPCVD from DEMS precursor seems to be useful as potential dielectric materials or coatings for various encapsulation applications. 相似文献
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Xi Yao Stuart S. Dunn Philseok Kim Meredith Duffy Jack Alvarenga Joanna Aizenberg 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(17):4507-4511
Omniphobic fluorogel elastomers were prepared by photocuring perfluorinated acrylates and a perfluoropolyether crosslinker. By tuning either the chemical composition or the temperature that control the crystallinity of the resulting polymer chains, a broad range of optical and mechanical properties of the fluorogel can be achieved. After infusing with fluorinated lubricants, the fluorogels showed excellent resistance to wetting by various liquids and anti‐biofouling behavior, while maintaining cytocompatiblity. 相似文献
56.
Green synthesis and antibacterial effects of aqueous colloidal solutions of silver nanoparticles using clove eugenol
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Magdalena Parlinska‐Wojtan Joanna Depciuch Bartosz Fryc Małgorzata Kus‐Liskiewicz 《应用有机金属化学》2018,32(4)
Silver nanoparticles were synthesized using clove extract (CE). Scanning transmission electron microscopy (STEM) revealed the morphology of the metallic Ag nanoparticles obtained via the clove extract synthesis (Ag NPs‐CE), which had a uniform distribution and average sizes varying from 10 nm to 100 nm. Fourier transform infra‐red (FTIR) spectroscopy showed that clove eugenol acts as a capping and reducing agent being adsorbed on the surface of Ag NPs‐CE, enabling their reduction from Ag+ and preventing their agglomeration. Formation of the Ag0 structure is also confirmed in the FTIR spectrum by the presence in the Ag NPs‐CE sample of the –C=O and –C=C vibrations at wavenumbers 1600 and 2915 cm‐1, respectively. Antibacterial and antifungal tests using three strains of bacteria and one fungi strain showed that the Ag NPs‐CE performed better compared to pure clove extract (CE) sample. 相似文献
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The liquid‐crystalline polymorphism of the homologous series of 4‐hexyloxybenzylidene‐4′‐alkyloxyanilines is investigated. Basing on the polarization microscopy (POM, TOA), the DSC calorimetry and miscibility studies the following mesophases were detected: nematic, smectic A, smectic C and smectic I. The phase diagrams of the compounds of these series with 4‐hexyloxybenylidene‐4′‐pentylaniline (as the standard of mesophases) show induction of the smectic F mesophases. Their dependence on the alkyl chain length and mole fraction is shown. 相似文献
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Ryszard Krzyminiewski Bernadeta Dobosz Grzegorz Schroeder Joanna Kurczewska 《Physics letters. A》2018,382(44):3192-3196
The paper shows the application of a new method – Magnetic Nanoparticles Focusing 3D, MNF-3D – for focusing of magnetic nanoparticles at any point in a three-dimensional space between the rotating magnet system. The results of focusing process of nanoparticles in water, human blood, human serum and polyurethane sponge are presented. Additionally, blood flow was also considered. The effectiveness of nanoparticle focusing was monitored optically and quantitatively by electron spin resonance method. The method enabled focusing of magnetic nanoparticles within a few minutes in different environments. A good efficiency of focusing process was observed for all the samples. 相似文献
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Korać Jelena Todorović Nina Zakrzewska Joanna Žižić Milan Spasojević Ivan 《Structural chemistry》2018,29(5):1533-1541
Structural Chemistry - Epinephrine (Epi) is a physiologically important catecholamine. Molecular conformation of Epi controls the interactions with other molecules and its biological effects. There... 相似文献
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Karolina Wieszczycka Agata Gorzelańczyk Joanna Zembrzuska 《Research on Chemical Intermediates》2013,39(3):853-868
Photodegradation of the oximes of alkyl-2-, -3-, and -4-pyridylketones and identification of possible degradation products using LC–MS/MS and GC–MS techniques were performed. The influence of copper(II) and iron(III) ions on the stability of the oxime under UV–Vis radiation exposure were also studied. It was found that the photodegradation of the pyridylketoximes resulted in the photoisomerization, photofragmentation and photosubstitution to a pyridine ring. Based on these results, a hypothetical mechanism of photodegradation of pyridylketoximes was proposed. 相似文献