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61.
István Szilágyi László. Horváth Imre Labádi Klara Hernadi István Pálinkó Tamás Kiss 《Central European Journal of Chemistry》2006,4(1):118-134
An imidazolate-bridged copper(II)-zinc(II) complex (Cu(II)-diethylenetriamino-μ-imidazolato-Zn(II)-tris(2-aminoethyl)amine perchlorate (denoted as “Cu,Zn complex”) and a simple copper(II) complex (Cu(II)-tris(2-aminoethyl)
amine chloride (“Cu-tren”) were prepared and immobilised on silica gel (by hydrogen or covalent bonds) and montmorillonite
(by ion exchange). The immobilised substances were characterised by FT-IR spectroscopy and their thermal characteristics were
also studied. The obtained materials were tested in two probe reactions: catalytic oxidation of 3,5-di-tert-butyl catechol (DTBC) (catecholase activity) and the decomposition of hydrogen peroxide (catalase activity). It was found
that the catecholase activity of the Cu,Zn complex increased considerably upon immobilization on silica gel via hydrogen bonds and intercalation by ion exchange among the layers of montmorillonite. The imidazolate-bridged copper(II)-zinc(II)
complex and its immobilised versions were inactive in hydrogen peroxide decomposition. The Cu(II)-tris(2-aminoethyl)amine
chloride complex displayed good catalase activity; however, immobilisation could not improve it. 相似文献
62.
63.
Zólomy A. Berceli T. Járó G. Hilt A. Marozsák T. 《Optical and Quantum Electronics》1998,30(11-12):969-983
Optical and Quantum Electronics - A new approach for the design and construction of low noise broadband optical receivers is presented utilizing distributed amplification based on hybrid integrated... 相似文献
64.
A simple field sampling-preconcentration method for zinc determination in seawater is described. Seawater was collected in situ by pumping it through a minicolumn packed with a chelating resin (Chelite P) connected to a field flow preconcentration system (FFPS). These packed minicolumns retain the dissolved zinc, and once are loaded with the analyte, they are returned to the laboratory where they are sequentially inserted into a flow injection system for on-line zinc elution with diluted hydrochloric acid and flame atomic absorption spectrometric detection. A factorial design has been used to optimize the FFPS and the flow injection elution process. The proposed method has a linear calibration range from 0.07 to at least 9.4 microg L(-1) of zinc, with a detection limit of 0.02 microg L(-1) and a throughput of 26 samples h(-1). Validation was carried out against certified reference water samples. This procedure has been successfully applied to the determination of Zn in seawater samples from Galicia (Spain). 相似文献
65.
B. Giner I. Gascón A. Villares C. Lafuente 《Journal of Thermal Analysis and Calorimetry》2006,83(3):735-745
The
relation between refractive index deviations and excess volumes for binary
mixtures formed by a cyclic ether and a haloalkane has been tested using several
methods: refractive index mixing rules and equations of state. Refractive
index deviations, excess volumes and molar refractions have been calculated
from experimental data of refractive indices and densities at two temperatures
298.15 and 313.15 K. Results obtained have been discussed in terms of intermolecular
interactions. Refractive indices were compared with those predicted by several
mixing rules. Excess volumes have also been correlated using several cubic
equations of state and finally a relation between parameter b
from equations of state and molar refraction has been provided. 相似文献
66.
67.
J. Balogh D. Kaptás L. F. Kiss T. Kemény L. Bujdosó I. Vincze 《Hyperfine Interactions》2006,169(1-3):1343-1347
Magnetic multilayers of 57Fe with nominal thickness, T
nom, between 0.4 and 1.0 nm separated by 3.0 nm Al spacer layers were prepared by alternate deposition of the constituents in
high vacuum. The samples were investigated at 4.2 K in external magnetic field. A fraction of Fe atoms corresponding to about
0.3 nm equivalent Fe-thickness was found to mix into the Al spacer. The extremely strong magnetic anisotropy observed for
T
nom < 0.8 nm is attributed to Fe layers of approximately two atomic planes thick. The anisotropy decreases considerably after
the building up of the third Fe atomic layer starts at T
nom = 0.8 nm, but full saturation was not achieved even for T
nom = 1 nm and 3 T magnetic field applied perpendicularly to the sample plane. 相似文献
68.
B. E. López M. A. Rodriguez S. L. A. Fucugauchi 《Journal of Radioanalytical and Nuclear Chemistry》1993,175(4):273-280
It has been established that the coexistence of chemical species structurally different from cerium, is a direct consequence of the time taken for its preparation. Its practical applications, within the scope of purifying uranium, may constitute the most important technological aspect in the process of ionic exchange, to separate141Ce from uranium. 相似文献
69.
Let F denote a family of pairwise disjoint convex sets in the plane. F is said to be in convex position if none of its members is contained in the convex hull of the union of the others. For any fixed k≥ 3 , we estimate P
k
(n) , the maximum size of a family F with the property that any k members of F are in convex position, but no n are. In particular, for k=3 , we improve the triply exponential upper bound of T. Bisztriczky and G. Fejes Tóth by showing that P
3
(n) < 16
n
.
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<onlinepub>26 June, 1998
<editor>Editors-in-Chief: &lsilt;a href=../edboard.html#chiefs&lsigt;Jacob E. Goodman, Richard Pollack&lsilt;/a&lsigt;
<pdfname>19n3p437.pdf
<pdfexist>yes
<htmlexist>no
<htmlfexist>no
<texexist>yes
<sectionname>
</lsiheader>
Received March 27, 1997, and in revised form July 10, 1997. 相似文献
70.
M. A. Morón C. Romero F. R. Ruiz del Portal 《Journal of Optimization Theory and Applications》1996,91(3):643-649
The purpose of this paper is to seek utility functions satisfying a weak condition which guarantees that the utility optimum always belongs to the compromise set. This set is a special subset of the attainable or feasible set, which is generated through the application of the well-known operational research approach called compromise programming. It is shown that there are large families of utility functions satisfying this condition, thus reinforcing the value of compromise programming as a good surrogate of the traditional utility optimum.Thanks are due to the reviewers for their helpful suggestions. The English editing by Ms. Christine Méndez is appreciated. The authors have been supported by the Comisión Interministerial de Ciencia y Tecnología (CICYT), Madrid, Spain. 相似文献