全文获取类型
收费全文 | 434139篇 |
免费 | 4363篇 |
国内免费 | 1079篇 |
专业分类
化学 | 234097篇 |
晶体学 | 7178篇 |
力学 | 18916篇 |
综合类 | 19篇 |
数学 | 46993篇 |
物理学 | 132378篇 |
出版年
2019年 | 3901篇 |
2018年 | 4954篇 |
2017年 | 5018篇 |
2016年 | 7404篇 |
2015年 | 4523篇 |
2014年 | 7245篇 |
2013年 | 18454篇 |
2012年 | 13493篇 |
2011年 | 16539篇 |
2010年 | 11763篇 |
2009年 | 11597篇 |
2008年 | 15199篇 |
2007年 | 15277篇 |
2006年 | 14261篇 |
2005年 | 12902篇 |
2004年 | 11866篇 |
2003年 | 10880篇 |
2002年 | 10569篇 |
2001年 | 12289篇 |
2000年 | 9447篇 |
1999年 | 7267篇 |
1998年 | 6091篇 |
1997年 | 6068篇 |
1996年 | 5716篇 |
1995年 | 5363篇 |
1994年 | 5406篇 |
1993年 | 4992篇 |
1992年 | 6000篇 |
1991年 | 5917篇 |
1990年 | 5806篇 |
1989年 | 5680篇 |
1988年 | 5844篇 |
1987年 | 5710篇 |
1986年 | 5407篇 |
1985年 | 7108篇 |
1984年 | 7350篇 |
1983年 | 6033篇 |
1982年 | 6188篇 |
1981年 | 6177篇 |
1980年 | 5991篇 |
1979年 | 6241篇 |
1978年 | 6542篇 |
1977年 | 6522篇 |
1976年 | 6431篇 |
1975年 | 5917篇 |
1974年 | 5931篇 |
1973年 | 6037篇 |
1972年 | 4238篇 |
1968年 | 3573篇 |
1967年 | 3555篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
231.
A nonlinear, compressible, non-isothermal gravity wave model that involves photochemistry is used to study the effects of gravity wave on atmospheric chemical species distributions in this paper. The changes in the distributions of oxygen compound and hydrogen compound density induced by gravity wave propagation are simulated. The results indicate that when a gravity wave propagates through a mesopause region, even if it does not break, it can influence the background distributions of chemical species. The effect of gravity wave on chemical species at night is larger than in daytime. 相似文献
232.
E. C. Ferreira J. A. P. da Costa J. A. K. Freire G. A. Farias V. N. Freire 《Applied Surface Science》2002,190(1-4):191-194
Confined excitons in non-abrupt GaAs/AlxGa1−xAs single quantum wells are studied. The graded interfaces are described taking into account fluctuations in their thickness a and positioning with respect to the abrupt interface picture. Numerical results for confined (0,0),(1,1) and (0,2) excitons in GaAs/Al0.3Ga0.7As quantum wells show that while the interfacial fluctuations produce small changes (<0.5 meV) in the exciton binding energies, the confined exciton energies can be red- or blue-shifted as much as 25 meV for wells with mean width of 50 Å and 2 ML wide interfaces. 相似文献
233.
S.K. HAY.H. KIM 《Journal of sound and vibration》2002,253(5):1001-1014
Impedance and admittance matrices are presented for the analysis of the beam-type piezoelectric multimorph (PM). Each piezoelectric layer is polarized in the thickness direction. The stacking sequence can be arbitrary, and both the extensional and flexural motions are considered. The variational principle is used for deriving the lumped conjugate parameters: two mechanical ports for the extensional motion, four mechanical ports for the flexural motion, and m electrical ports for the m piezoelectric layers. The resonance and antiresonance frequencies are then easily calculated from the admittance matrices. For the case of all the piezoelectric layers either in series or parallel connection, them +6 ports reduce to the seven ports, and its impedance and admittance matrices are presented. The present methods are applied to the cantilevered PM and their electromechanical behavior is studied. The tip trajectory of the cantilevered piezomotor is also investigated using the presented matrices. It is found that the present methods are very effective in analyzing the multilayer piezoelectric transducers. 相似文献
234.
K. E. Mochalov O. A. Ustinova S. A. Strel’tsov S. L. Grokhovskii A. L. Zhuze I. R. Nabiev A. V. Sukhanova V. A. Oleinikov 《Optics and Spectroscopy》2002,93(4):493-500
Topotecan (TPT), a water-soluble derivative of camptothecin (inhibitor of human DNA topoiomerase I), has found wide application in cancer chemotherapy. The central problem in using topotecan is the presence of lactone rings in its molecules, which undergo hydrolysis at a physiological pH yielding an inactive and even toxic form of the drug. The analysis of Raman spectra of TPT in H2O and D2O solutions made it possible to assign the spectral bands to the vibrations of particular molecular groups. Spectral features indicative of the opening of the lactone rings of the TPT molecules, deprotonation of the hydroxyl groups in their quinoline fragments, and of possible participation of the hydroxyl and carbonyl groups in H bonding are found. The data obtained are necessary to study the molecular mechanisms of TPT-DNA interaction and the formation of ternary complexes between TPT, DNA, and DNA topoisomerase I. 相似文献
235.
G. E. Volovik 《JETP Letters》2002,76(5):240-244
An analogue of a black hole can be realized in the low-temperature laboratory. The horizon can be constructed for “relativistic” ripplons (surface waves) living on the brane. The brane is represented by the interface between two superfluid liquids, 3He-A and 3He-B, sliding along each other without friction. A similar experimental arrangement was recently used for the observation and investigation of the Kelvin-Helmholtz type of instability in superfluids [1]. The shear-flow instability in superfluids is characterized by two critical velocities. The lowest threshold measured in recent experiments [1] corresponds to the appearance of the ergoregion for ripplons. In the modified geometry, this will give rise to the black-hole event horizon in the effective metric experienced by ripplons. In the region behind the horizon, the brane vacuum is unstable due to interaction with the higher-dimensional world of bulk superfluids. The time of the development of instability can be made very long at low temperature. This will allow us to reach and investigate the second critical velocity—the proper Kelvin-Helmholtz instability threshold. The latter corresponds to the singularity inside the black hole, where the determinant of the effective metric becomes infinite. 相似文献
236.
The results of laser induced deposition of copper on polyimide substrate from copper electrolyte solution are reported. Unlike most work reported in the literatures where CW Ar+ lasers were used, a second harmonic (532 nm wavelength) Q-switch Nd:YAG laser was used for our experiments. The deposition process was conducted by laser-catalyzing of the polyimide surface and subsequent photothermal-accelerated reduction of copper-complex ions in an alkaline reducing environment. The characteristics of the deposited copper line were investigated in terms of laser beam scanning speed, and the number of scans. The surface morphology and chemical composition of the deposited copper were analyzed using field emission scanning electron microscope (FESEM) and energy dispersive spectrometer (EDX). The optimum processing conditions have been identified. The copper deposit was found to adhere well to the substrate. 相似文献
237.
R.S. Gonnelli A. CalzolariD. Daghero G.A. UmmarinoV.A. Stepanov P. FinoG. Giunchi S. CeresaraG. Ripamonti 《Journal of Physics and Chemistry of Solids》2002,63(12):2319-2323
We studied the voltage and temperature dependency of the dynamic conductance of normal metal-MgB2 junctions obtained either with the point-contact technique (with Au and Pt tips) or by making Ag-paint spots on the surface of MgB2 samples. The fit of the conductance curves with the generalized BTK model gives evidence of pure s-wave gap symmetry. The temperature dependency of the gap, measured in Ag-paint junctions (dirty limit), follows the standard BCS curve with 2Δ/kBTc=3.3. In out-of-plane, high-pressure point-contacts we obtained almost ideal Andreev reflection characteristics showing a single small s-wave gap Δ=2.6±0.2 meV (clean limit). 相似文献
238.
239.
Copper bromide was used as a catalyst for the addition of pyrroles to enones. When both the reactants were used in equimolar amounts, mono and dialkylated products were obtained. However, the use of excess enone furnished only dialkylated products. Thus, copper bromide was shown to be an efficient catalyst for the dialkylation of pyrroles. 相似文献
240.
P. Rudolf R. Raval P. Dumas G.P. Williams 《Applied Physics A: Materials Science & Processing》2002,75(1):147-153
Infrared (IR) spectroscopy of chemisorbed C60 on Ag (111), Au (110) and Cu (100) reveals that a non-IR-active mode becomes active upon adsorption, and that its frequency
shifts proportionally with the charge transferred from the metal to the molecule by about 5 cm-1 per electron. The temperature dependence of the frequency and the width of this IR feature have also been followed for C60/Cu (100) and were found to agree well with a weak anharmonic coupling (dephasing) to a low-frequency mode, which we suggest
to be the frustrated translational mode of the adsorbed molecules.
Additionally, the adsorption is accompanied by a broadband reflectance change, which is interpreted as due to the scattering
of conduction electrons of the metal surface by the adsorbate. The reflectance change allows determination of the friction
coefficient of the C60 molecules, which results in rather small values (∼2×109 s-1 for Ag and Au, and ∼1.6×109 s-1for Cu), consistent with a marked metallic character of the adsorbed molecules.
Pre-dosing of alkali atoms onto the metal substrates drastically changes the IR spectra recorded during subsequent C60 deposition: anti-absorption bands, as well as an increase of the broadband reflectance, occur and are interpreted as due
to strong electron–phonon coupling with induced surface states.
Received: 6 June 2001 / Accepted: 23 October 2001 / Published online: 3 April 2002 相似文献