全文获取类型
收费全文 | 1969篇 |
免费 | 116篇 |
国内免费 | 23篇 |
专业分类
化学 | 1540篇 |
晶体学 | 23篇 |
力学 | 41篇 |
数学 | 148篇 |
物理学 | 356篇 |
出版年
2023年 | 13篇 |
2022年 | 26篇 |
2021年 | 49篇 |
2020年 | 46篇 |
2019年 | 47篇 |
2018年 | 27篇 |
2017年 | 38篇 |
2016年 | 74篇 |
2015年 | 59篇 |
2014年 | 89篇 |
2013年 | 129篇 |
2012年 | 194篇 |
2011年 | 177篇 |
2010年 | 115篇 |
2009年 | 82篇 |
2008年 | 128篇 |
2007年 | 122篇 |
2006年 | 109篇 |
2005年 | 89篇 |
2004年 | 82篇 |
2003年 | 66篇 |
2002年 | 61篇 |
2001年 | 42篇 |
2000年 | 49篇 |
1999年 | 22篇 |
1998年 | 23篇 |
1997年 | 17篇 |
1996年 | 14篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 10篇 |
1992年 | 7篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 3篇 |
1983年 | 7篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1933年 | 2篇 |
排序方式: 共有2108条查询结果,搜索用时 15 毫秒
111.
Tae Woo Kim Eun‐Jin Oh Ah‐Young Jee Seung Tae Lim Dae Hoon Park Minyung Lee Sang‐Hoon Hyun Prof. Jin‐Ho Choy Prof. Seong‐Ju Hwang Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(41):10752-10761
A colloidal suspension of exfoliated, layered cobalt oxide nanosheets has been synthesized through the intercalation of quaternary tetramethylammonium ions into protonated lithium cobalt oxide. According to atomic force microscopy, exfoliated nanosheets of layered cobalt oxide show a plateau‐like height profile with nanometer‐level height, underscoring the formation of unilamellar 2D nanosheets. The exfoliation of layered cobalt oxide was cross‐confirmed by X‐ray diffraction, UV/Vis spectroscopy, and transmission electron microscopy. The maintenance of the hexagonal in‐plane structure of the cobalt oxide lattice after the exfoliation process was evidenced by selected‐area electron diffraction and Co K‐edge X‐ray absorption near‐edge structure analysis. The zeta‐potential measurements clearly demonstrated the negative surface charge of cobalt oxide nanosheets. Adopting the nanosheets of layered cobalt oxide as a precursor, we were able to prepare the monodisperse CoO nanocrystals with a particle size of ≈10 nm as well as the heterolayered film composed of cobalt oxide monolayer and polycation. 相似文献
112.
A temperature dependent thermal expansion coefficient is introduced into the Lee, Rogers and Woo linear viscoelastic model for calculating thermal stresses in glass. Volumetric strain, is calculated as follows: ? = αliq (Tf - TO) + αgl (T - Tf) where αliq and αgl are the thermal expansion coefficients for the liquid and glassy states respectively, T is the glass temperature, TO is the initial temperature, and Tf is the fictive temperature as defined by Tool. Fictive temperatures are calculatedfrom theory and measurements independent of thermal stress experiments. Comparison of calculated with experimentally measured stresses shows that the modified model is useful for predicting thermal tempering propensity for different glass compositions as well as different processing parameters. 相似文献
113.
114.
115.
Dokyung Yoon Daekwang Woo Jung Heon Kim Moon Ki Kim Taesung Kim Eung-Soo Hwang Seunghyun Baik 《Journal of nanoparticle research》2011,13(6):2543-2551
The cytotoxicity of alumina nanoparticles (NPs) was investigated for a wide range of concentration (25–200 μg/mL) and incubation
time (0–72 h) using floating cells (THP-1) and adherent cells (J774A.1, A549, and 293). Alumina NPs were gradually agglomerated
over time although a significant portion of sedimentation occurred at the early stage within 6 h. A decrease of the viability
was found in floating (THP-1) and adherent (J774A.1 and A549) cells in a dose-dependent manner. However, the time-dependent
decrease in cell viability was observed only in adherent cells (J774A.1 and A549), which is predominantly related with the
sedimentation of alumina NPs in cell culture medium. The uptake of alumina NPs in macrophages and an increased cell-to-cell
adhesion in adherent cells were observed. There was no significant change in the viability of 293 cells. This in vitro test
suggests that the agglomeration and sedimentation of alumina NPs affected cellular viability depending on cell types such
as monocytes (THP-1), macrophages (J774A.1), lung carcinoma cells (A549), and embryonic kidney cells (293). 相似文献
116.
117.
Noble C. Woo Kunigunde Cherenack Gerhard Tr?ster Ralph Spolenak 《Applied Physics A: Materials Science & Processing》2010,100(1):281-285
Reducing the strain in brittle device layers is critical in the fabrication of robust flexible electronic devices. In this
study, the cracking behavior of micro-patterned 500-nm-thick Ti films was investigated via uniaxial tensile testing by in
situ SEM and 4-point probe measurements. Both visual observations by SEM and 4-pt resistance measurements showed that strategically
patterned oval holes, off-set and rotated by 45°, had a significant effect on limiting the extent of cracking, specifically,
in preventing cracks from converging. Failure with regard to electrical conduction was delayed from less than 2% to more than
10% strain. 相似文献
118.
119.
Template‐Engaged Solid‐State Synthesis of Barium Magnesium Silicate Yolk@Shell Particles and Their High Photoluminescence Efficiency
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Xuncai Chen Prof. Dr. Woo‐Sik Kim 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(21):7190-7197
This study presents a new synthetic method for fabricating yolk@shell‐structured barium magnesium silicate (BMS) particles through a template‐engaged solid‐state reaction. First, as the core template, (BaMg)CO3 spherical particles were prepared based on the coprecipitation of Ba2+ and Mg2+. These core particles were then uniformly shelled with silica (SiO2) by using CTAB as the structure‐directing template to form (BaMg)CO3@SiO2 particles with a core@shell structure. The (BaMg)CO3@SiO2 particles were then converted to yolk@shell barium magnesium silicate (BMS) particles by an interfacial solid‐state reaction between the (BaMg)CO3 (core) and the SiO2 (shell) at 750 °C. During this interfacial solid‐state reaction, Kirkendall diffusion contributed to the formation of yolk@shell BMS particles. Thus, the synthetic temperature for the (BaMg)SiO4:Eu3+ phosphor is significantly reduced from 1200 °C with the conventional method to 750 °C with the proposed method. In addition, the photoluminescence intensity of the yolk@shell (BaMg)SiO4:Eu3+phosphor was found to be 9.8 times higher than that of the conventional (BaMg)SiO4:Eu3+ phosphor. The higher absorption of excitation light by the structure of the yolk@shell phosphor is induced by multiple light‐reflection and ‐scattering events in the interstitial void between the yolk and the shell. When preparing the yolk@shell (BaMg)SiO4:Eu3+ phosphor, a hydrogen environment for the solid‐state reaction results in higher photoluminescence efficiency than nitrogen and air environments. The proposed synthetic method can be easily extended to the synthesis of other yolk@shell multicomponent metal silicates. 相似文献
120.