全文获取类型
收费全文 | 370篇 |
免费 | 36篇 |
国内免费 | 65篇 |
专业分类
化学 | 320篇 |
晶体学 | 3篇 |
力学 | 44篇 |
数学 | 32篇 |
物理学 | 72篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 11篇 |
2020年 | 12篇 |
2019年 | 8篇 |
2018年 | 14篇 |
2017年 | 7篇 |
2016年 | 18篇 |
2015年 | 14篇 |
2014年 | 17篇 |
2013年 | 21篇 |
2012年 | 33篇 |
2011年 | 27篇 |
2010年 | 24篇 |
2009年 | 23篇 |
2008年 | 33篇 |
2007年 | 36篇 |
2006年 | 19篇 |
2005年 | 17篇 |
2004年 | 19篇 |
2003年 | 18篇 |
2002年 | 17篇 |
2001年 | 10篇 |
2000年 | 15篇 |
1999年 | 8篇 |
1998年 | 9篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 5篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有471条查询结果,搜索用时 15 毫秒
121.
122.
123.
Determination of bisphenol A, 4‐octylphenol,and 4‐nonylphenol in soft drinks and dairy products by ultrasound‐assisted dispersive liquid–liquid microextraction combined with derivatization and high‐performance liquid chromatography with fluorescence detection 下载免费PDF全文
Tao Lv Xian‐En Zhao Shuyun Zhu Fei Qu Cuihua Song Jinmao You Yourui Suo 《Journal of separation science》2014,37(19):2757-2763
A novel hyphenated method based on ultrasound‐assisted dispersive liquid–liquid microextraction coupled to precolumn derivatization has been established for the simultaneous determination of bisphenol A, 4‐octylphenol, and 4‐nonylphenol by high‐performance liquid chromatography with fluorescence detection. Different parameters that influence microextraction and derivatization have been optimized. The quantitative linear range of analytes is 5.0–400.0 ng/L, and the correlation coefficients are more than 0.9998. Limits of detection for soft drinks and dairy products have been obtained in the range of 0.5–1.2 ng/kg and 0.01–0.04 μg/kg, respectively. Relative standard deviations of intra‐ and inter‐day precision for retention time and peak area are in the range of 0.47–2.31 and 2.76–8.79%, respectively. Accuracy is satisfactory in the range of 81.5–118.7%. Relative standard deviations of repeatability are in the range of 0.35–1.43 and 2.36–4.75% for retention time and peak area, respectively. Enrichment factors for bisphenol A, 4‐octylphenol, and 4‐nonylphenol are 170.5, 240.3, and 283.2, respectively. The results of recovery and matrix effect are in the range of 82.7–114.9 and 92.0–109.0%, respectively. The proposed method has been applied to the determination of bisphenol A, 4‐octylphenol, and 4‐nonylphenol in soft drinks and dairy products with much higher sensitivity than many other methods. 相似文献
124.
125.
Daoming Zhu Yanhong Duo Meng Suo Yonghua Zhao Ligang Xia Zheng Zheng Yang Li Ben Zhong Tang 《Angewandte Chemie (International ed. in English)》2020,59(33):13836-13843
The development of novel photosensitizing agents with aggregation‐induced emission (AIE) properties has fueled significant advances in the field of photodynamic therapy (PDT). An electroporation method was used to prepare tumor‐exocytosed exosome/AIE luminogen (AIEgen) hybrid nanovesicles (DES) that could facilitate efficient tumor penetration. Dexamethasone was then used to normalize vascular function within the tumor microenvironment (TME) to reduce local hypoxia, thereby significantly enhancing the PDT efficacy of DES nanovesicles, and allowing them to effectively inhibit tumor growth. The hybridization of AIEgen and biological tumor‐exocytosed exosomes was achieved for the first time, and combined with PDT approaches by normalizing the intratumoral vasculature as a means of reducing local tissue hypoxia. This work highlights a new approach to the design of AIEgen‐based PDT systems and underscores the potential clinical value of AIEgens. 相似文献
126.
An unusual yuzurine-type alkaloid daphnilongerine (1), with an unprecedented fused pentacyclic skeleton in addition to seven known ones, daphnigracine (2), daphnezomine R, daphnigraciline, yuzurine, longistylumphyllines A, daphnilongeranin C, and calycinine A, was isolated from the fruits of Daphniphyllum longeracemosum. The structure and relative stereochemistry of 1 were determined by spectroscopic analysis. 相似文献
127.
(3R,5R)-3,5-二羟基-6-取代己酸不对称合成研究进展 总被引:1,自引:0,他引:1
概述近 2 0年来 ( 3R ,5R) 3 ,5 二羟基 6 取代己酸不对称合成进展 ,并提出其研究方向 . 相似文献
128.
Sulfamic acid has been used as an efficient catalyst and green alternative for metal-containing acidic materials to promote the acetolysis reaction of THF to produce 1,4-diacetoxybutane. This method is also applicable to the acetolysis of other cyclic ethers, such as methyl substituted THF and tetrahydropyran and 1,4-dioxane, which is less reactive. 相似文献
129.
Eremophilane Sesquiterpenes from Cacalia Roborowskii 总被引:3,自引:0,他引:3
Themajorityofphytochemicalstudiesonsenencioneace(compositae)specieshavebeenconcentratedonthepyrrolizidinealkaloidsandsesquiteIPenesbecauseoftheirpotentialbioactivitiesandCytotoalcactivities.lCacaliaroborowskii(maxim)LinginslongbeenusedasfolkremedyinnorthwestemChina.Recently,wehadisolatedseveralneweremophilenolides'fromtherootsofthisplant.Asacontinuahonofourinvestigationontillsspecies,wenowpresenttileisolationandsmicturalelucid.ltionoffouraddihonalneweremophilanesesquiterpenes.Theirsmicturesw… 相似文献
130.
Y. -L. Li C. -X. Ding H. -L. Wang Y. -R. Suo J. -M. You G. -C. Chen 《Journal of Analytical Chemistry》2008,63(6):574-579
The contents of five pharmacologically active flavone and xanthone glycosides, namely, swertianolin, swertisin, isoorientin,
mangiferin, and 7-O-[α-L-rhamnopyranosyl-(1 → 2)-β-D-xylopyranosyl]-1,8-dihydroxy-3-methoxyxanthone, extracted from Tibetan
folk medicinal species Swertia mussotii and S. franchetiana were determined by capillary electrophoresis with diode-array detection. The separation of five components has been optimized
with a capillary column with a total length of 48.5 cm and effective length of 40 cm (50 μm i.d). The influence of the running
buffer, the sodium dodecyl sulfonate (SDS) concentration, organic modifier, etc. on the resolution was evaluated. The background electrolyte contained 30 mM borate
buffer, 28 mM SDS, 1.0% (v/v) acetonitrile, and was adjusted to pH 9.0 with 0.1 M NaOH. A good baseline resolution was obtained
for the separation of five components within 5 min with the working voltage of 24 kV and a column temperature of 25°C. The
established method was rapid and reproducible for the separation and determination of five flavone and xanthone glycosides
from the extracts of S. mussotii and franchetiana plant samples.
The text was submitted by the authors in English. 相似文献