Electromagnetic Properties of Lanthanum Manganese Oxides Doped with Iron

The mechanism of GMR effects in La(Mn_1–x Fe _x )O₃ (x=0, 0.01, 0.03) oxides has been investigated by means of magnetic measurements, resistivity measurements in magnetic field and Mössbauer spectroscopy. For the x=0.01 sample, the GMR behavior is similar to that of the conventional (La, A)MnO₃ (A: divalent cations) oxides. For the x=0.03 sample, even though the temperature dependence of the Mössbauer spectra was similar to that of the x=0.01 sample, the mechanism for the occurrence of the GMR effect seems to be different. The x=0 sample shows a similar behavior to the x=0.03 sample. A thermal stabilization of spin fluctuation is proposed for the x=0 and x=0.03 sample.     

Reaction of O6-methylguanosine with nitrite in the presence of carboxylic acid: synthesis of the purin-2-yl carboxylate

O6-Methylguanosine derivative was treated with sodium nitrite or isoamylnitrite in the presence of carboxylic acid to give the purin-2-yl carboxylate, an unusual product bearing a carboxylic group at the 2-position of the purine moiety.     

Nuclear shapes and interaction potentials of two colliding208Pb nuclei at finite temperature

The effect of nuclear and Coulomb interactions on the shapes of two colliding²⁰⁸Pb nuclei at finite temperature is investigated. The complex potential energy density derived by Faessler and collaborators and the kinetic energy density and entropy density for two Fermi spheres at finite temperature are used to calculate the free energy of the²⁰⁸Pb +²⁰⁸Pb system in the energy density formalism. Shell corrections are added to the free energy in the framework of the Strutinsky method. The total free energy is minimized with respect to the quadrupole deformation and the diffuseness to determine the density distribution of²⁰⁸Pb nucleus at certain distanceR and temperatureT assuming the deformed Woods-Saxon shape for each nucleus. It is found that the nucleus acquires larger deformation and diffuseness as the temperature increases. The interaction potential between two²⁰⁸Pb nuclei is calculated from the minimized free energy. The total (nuclear + Coulomb) potential is found to decrease with increasing temperature, whereas the real part of the nuclear potential becomes more repulsive as the temperature increases.     

Beyond the standard model physics at RHIC in polarized pp collision

An polarized hadron collider experiment must have a great discovery potential for a search of physics beyond the standard model. Experimental data of various symmetry tests at RHIC are going to be obtained within a few years. The author developed a simulation tool, studying a sensitivity of hunting contact interaction at RHIC by measuring parity violating spin asymmetries.     

Nuclear photoabsorption and Compton scattering at intermediate energy

Intermediate energy nuclear photoabsorption and Compton scattering within the Δ-hole approach are studied. The same Δ-nucleus dynamics used to describe a variety of pion-induced reactions are employed. A dynamical model for the photon-nucleon amplitude is constructed, including both resonant-channel and nonresonant backgrounds in addition to Δ-excitation. Medium corrections to the full amplitude are included for nuclear seattering. A doorway state expansion allows one to discuss quantitatively the role of various contributions to the Δ-hole Hamiltonian, thereby clarifying the level of sensitivity to the structure of the Δ spreading potential. The reactive content of the total cross section is diseussed. The results are compared with available photoabsorption data for ⁴He, ¹²C and ¹⁶O. We present results for the Δ contribution to the electron seattering transverse response function, for coherent π⁰ photoproduction, and for nuclear elastic Compton seattering. The photoabsorption strength is spread over a larger energy range by the Δ dynamics, in agreement with the data, but is centered at too high an energy. The helicity flip Compton cross section is especially sensitive to the Δ-nucleus interaction, such as the spin-orbit potential strength.     

Gas permeation through hydrogels : I. Gel cellophane membranes

Permeabilities and diffusion coefficients of various gases, Ar, N₂, O₂, CO₂, CH₄, C₂H₄, C₃H₈ and C₄H₁₀, were measured for Water-swollen gel cellophane membranes. No dependence of permeabilities on gas pressure below 1 atm was found. It was observed that the permeability coefficients were not related linearly to the coefficients in bulk water. For the two states of water in the membrane, an analytical method is presented to estimate the diffusion coefficients and the solubilities in free water and non-freezing water. It was found that the diffusion coefficients in non-freezing water were lower than those in free water, and the solubilities in non-freezing water were higher than in free water for all gases studied except CO₂ and C₂H₄, which gave reverse results.     

XPS for in situ observation of an Ag electrode on a solid electrolyte used as oxygen sensor

The Ag electrode surface of a solid electrolyte in its working state has been studied by X-ray photoelectron spectroscopy. The nature of the AgO system on the electrode is dependent on the temperature. There are three types of AgO systems at 400°C. Type 1 with an O is binding energy of 532.6 eV only appeared at 325°C. However, when the temperature was raised to 400°C, types II and III (with BEs 531.1 and 529.2 eV) appeared. These O is signals are discussed in detail.