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81.
NANOPERM-type alloy with chemical composition Fe76Mo8CuB15 was studied by combination of 57Fe Mössbauer spectroscopy and 57Fe(10B, 11B) nuclear magnetic resonance in order to determine distribution of hyperfine magnetic fields and evolution of relative concentration of Fe-containing crystalline phases within the surface layer and the volume of the nanocrystallized ribbons with annealing temperature. Differential scanning calorimetry revealed two crystallization stages at Tx1 ~ 510 °C and Tx2 ~ 640 °C, connected to precipitation of α-Fe and Fe(Mo,B) nanocrystals, respectively. The amorphous and partially crystalline state was obtained by annealing at several temperatures in the range 510-650 °C. The combination of conversion electron (CEMS) and transmission Mössbauer spectrometry (TMS) showed that annealing induces crystallization starting from both surfaces of the ribbons. For the as-quenched sample, scanning electron microscopy (SEM) and CEMS revealed significant differences in the “air” and “wheel” sides of the ribbons, crystallites were preferentially formed at the latter. While SEM micrographs of annealed samples showed various mean diameters of the crystals at opposite sides of the ribbons, the amounts of crystalline volume derived from the CEMS spectra approximately equaled. Mössbauer spectra of annealed samples contained narrow sextet ascribed to crystalline α-Fe phase, three sextets with distribution of hyperfine field assigned to the interface regions of the nanocrystals and the contribution of the amorphous phases. In-field TMS performed at 4.2 K with magnetic moments aligned by external magnetic field enabled to properly determine in particular the contribution of the amorphous phases in the samples. Resulting distributions of the hyperfine fields were compared with 57Fe(10B, 11B) nuclear magnetic resonance (NMR) spectra.  相似文献   
82.
Magnetic nanoparticles have found broad applications in medicine, especially for cell targeting and transport, and as contrast agents in MRI. Our samples of ??-Fe2O3 nanoparticles were prepared by annealing in silica matrix, which was leached off and the bare particles were then coated with amorphous silica layers of various thicknesses. The distribution of particle sizes was determined from the TEM pictures giving the average size ~20 nm and the thickness of silica coating ~5; 8; 12; 19 nm. The particles were further characterized by the XRPD and DC magnetic measurements. The nanoparticles consisted mainly of ??-Fe2O3 with admixtures of ~1 % of the α phase and less than 1 % of the γ phase. The hysteresis loops displayed coercivities of ~2 T at room temperature. The parameters of hyperfine interactions were derived from transmission Mössbauer spectra. Observed differences of hyperfine fields for nanoparticles in the matrix and the bare ones are ascribed to strains produced during cooling of the composite. This interpretation is supported by slight changes of their lattice parameters and increase of the elementary cell volume deduced from XRD. The temperature dependence of the magnetization indicated a two-step magnetic transition of the ??-Fe2O3 nanoparticles spread between ~85 K and ~150 K, which is slightly modified by remanent tensile stresses in the case of nanoparticles in the matrix. The subsequent coating of the bare particles by silica produced no further change in hyperfine parameters, which indicates that this procedure does not modify magnetic properties of nanoparticles.  相似文献   
83.
New procedures for the determination of pesticide carboxin were developed using differential pulse voltammetry, HPLC with amperometric detection and chronopotentiometry at carbon paste electrode and reticulated vitreous carbon electrode, respectively. Developed procedures based on electrochemical oxidation of carboxin were successfully applied on the determination of carboxin in the model samples of drinking and river water. Limits of detection in samples of river water were in 10?7 mol L?1 concentration range for all procedures and electrodes used. All developed procedures proved to be sensitive, accurate and, due to the resistance of the electrode to the passivation, also simple to handle.  相似文献   
84.
In this report, we describe design, synthesis, evaluation and molecular dynamics simulations of synthetic multifunctional pores with pi-acidic naphthalenediimide clamps. Experimental evidence is provided for the formation of unstable but inert, heterogeneous and acid-insensitive dynamic tetrameric pores that are sensitive to base and ionic strength. Blockage experiments reveal that the introduction of aromatic electron donor-acceptor interactions provides access to the selective recognition of pi-basic intercalators within the pore. This breakthrough is important for the application of synthetic pores as multianalyte sensors.  相似文献   
85.
The effect of lithium ion on the ordering of water in water-saturated nitrobenzene has been probed by 2H NMR, diffusion ordered spectroscopy and neutron scattering. It was shown that increased water concentration in LiClO4/wet nitrobenzene results in the formation of a metastable solvatomer with mixed water and nitrobenzene character, Li+(W/NB). This species is shown to decay over hours to two solvatomers, one dominated by nitrobenzene Li+(NB) and the other dominated by water Li+(W). To confirm the assignment of these solvation states, diffusion ordered deuterium NMR spectroscopy has been used to elucidate the hydrodynamic radii of these solvatomers. Neutron scattering yields vibrational spectroscopy information that shows how addition of lithium to the nitrobenzene/water system results in relatively slow self-organization of the water environment (hours).  相似文献   
86.
Barek J  Jandová K  Pecková K  Zima J 《Talanta》2007,74(3):421-426
Voltammetric behavior of 2-aminobiphenyl, 3-aminobiphenyl, and 4-aminobiphenyl at a boron-doped nanocrystalline diamond film electrode was investigated using cyclic voltammetry and differential pulse voltammetry. Optimum conditions have been found for the determination of those genotoxic substances by differential pulse voltammetry at the above given electrode in the concentration range of 2 × 10−7 to 1 × 10−5 mol/L.  相似文献   
87.
A common problem in the calculation of electrostatic potentials with the Poisson-Boltzmann equation using finite difference methods is the effect of molecular position relative to the grid. Previously a uniform charging method was shown to reduce the grid dependence substantially over the point charge model used in commercially available codes. In this article we demonstrate that smoothing the charge and dielectric values on the grid can improve the grid independence, as measured by the spread of calculated values, by another order of magnitude. Calculations of Born ion solvation energies, small molecule solvation energies, the electrostatic field of superoxide dismutase, and protein-protein binding energies are used to demonstrate that this method yields the same results as the point charge model while reducing the positional errors by several orders of magnitude. © 1997 by John Wiley & Sons, Inc.  相似文献   
88.
The electron localization function (ELF) shows too-high values when computed from valence densities only (instead of using the total density). This effect is mainly found when d electrons are present in the outermost shell of the core. Although no pronounced qualitative differences could be noticed in the examples studied up to now, it is found that the quantitative differences between the values of ELF obtained from the valence densities only or from the total densities can be large. We also show, for the first time, an example (the Be atom) where ELF is obtained directly from the density. This exemplifies the possibility of computing ELF from highly accurate calculations (or from experimental data). © 1997 John Wiley & Sons, Inc. J Comput Chem 18 : 1431–1439, 1997  相似文献   
89.
Electron localizability indicators based on the parallel‐spin electron pair density (ELI–D) and the antiparallel‐spin electron pair density (ELIA) are studied for the correlated ground‐state wavefunctions of Li2, Be2, B2, and C2 diatomic molecules. Different basis sets and reference spaces are used for the multireference configuration interaction method following the complete active space calculations to investigate the local effect of electron correlation on the extent of electron localizability in position space determined by the two functionals. The results are complemented by calculations of effective bond order, vibrational frequency, and Laplacian of the electron density at the bond midpoint. It turns out that for Li2, B2, and C2 the reliable topology of ELI–D is obtained only at the correlated level of theory. © 2009 Wiley Periodicals, Inc. J Comput Chem, 2010  相似文献   
90.
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