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141.
Ming Zhao Yuji Wang Caixia Huo Chunyu Li Xiaoyi Zhang Li Peng Shiqi Peng 《Tetrahedron: Asymmetry》2009,20(2):247-258
In lead detoxification, the α-anomer of N-glycocyl-l-amino acid is more potent than its β-anomer. Here a six-step-reaction route for stereoselectively preparing N-(α-l-arabinose-1-yl)-l-amino acids is reported. Treating l-arabinose with acetic anhydride and sodium acetate provided 1,2,3,5-tetra-O-acetyl-l-arabinofuranose in 90% yield. After removing the 1-acetyl group, the thus formed 2,3,5-tri-O-acetyl-l-arabinofuranose and N-(2-nitrophenylsulfonyl)-l-amino acid t-butylesters were treated with triphenylphosphine to perform Mitsunobu dehydration and form 2,3,5-tri-O-acetyl-l-arabinofuranosyl-l-[N-(2-nitrophenylsulfonyl)]amino acid t-butylesters 2a–f, and the ratios of their α- to β-anomer ranged from 8/1 to 9/1. Chromatographic separation provided epimerically pure 2a–f-α and 2a–f-β. In the presence of CF3CO2H, 2a–f-α and 2a–f-β were converted to α- and β-anomers of N-(2,3,5-tri-O-acetyl-l-arabinofuranosyl)-N-(2-nitrobenzenesulfonyl)-l-amino acids, 3a–f-α and 3a–f-β, in 87–92% yields. While in the presence of NaOCH3, 3a–f-α and 3a–f-β were converted to α- and β-anomers of N-(l-arabinofuranosyl)-N-(2-nitrobenzenesulfonyl)-l-amino acids, 4a–f-α and 4a–f-β, in 90–96% yields. Treating 4a–f-α and 4a–f-β with N-ethyldiisopropylamine (DIPEA) and thiophenol, their 2-nitrophenylsulfonyl groups were removed, and the α- and β-anomers of N-(l-arabinose-1-yl)-l-amino acids were formed in 70–79% yields. The bioassay confirmed that the lead detoxification activity of the α-anomer was significantly higher than that of the β-anomer. 相似文献
142.
Daniel Chiew Judy Qiu Sirimon Treepongkaruna Jiping Yang Chenxiao Shi 《Entropy (Basel, Switzerland)》2021,23(4)
Yang and Qiu proposed and reframed an expected utility–entropy (EU-E) based decision model. Later on, a similar numerical representation for a risky choice was axiomatically developed by Luce et al. under the condition of segregation. Recently, we established a fund rating approach based on the EU-E decision model and Morningstar ratings. In this paper, we apply the approach to US mutual funds and construct portfolios using the best rating funds. Furthermore, we evaluate the performance of the fund ratings based on the EU-E decision model against Morningstar ratings by examining the performance of the three models in portfolio selection. The conclusions show that portfolios constructed using the ratings based on the EU-E models with moderate tradeoff coefficients perform better than those constructed using Morningstar. The conclusion is robust to different rebalancing intervals. 相似文献
143.
The collision frequencies of electron-neutral-particle in weakly ionized complex plasmas with the non-Maxwellian velocity distributions are studied. The average collision frequencies of electron-neutral-particle in plasmas are accurately derived. We find that these collision frequencies are significantly dependent on the power-law spectral indices of non-Maxwellian distribution functions and so they are generally different from the collision frequencies in plasmas with a Maxwellian velocity distribution, which will affect the transport properties of the charged particles in plasmas. Numerically analyses are made to show the roles of the spectral indices in the average collision frequencies respectively. 相似文献
144.
给定寿命下的焊趾疲劳裂纹深度尺寸分析 总被引:1,自引:0,他引:1
本文提供并用统计方法研究了焊趾疲劳裂纹扩展的N~α曲线族,给出了联系给定裂纹尺寸下的疲劳分布,给定疲劳寿命下的裂纹尺寸分布以及随机初始条件的概率相容条件。研究表明,给定寿命下的焊趾疲劳裂纹深度尺寸α服从分布Ф[(μ(a)-logN)/σ(a)]。 相似文献
145.
146.
Synthesis,Characterization and Thermal Behaviors of 4-Amino-5-nitro-1,2,3-triazole(ANTZ)and Its Derivatives 总被引:1,自引:0,他引:1
4‐Amino‐5‐nitro‐1,2,3‐triazole (ANTZ) and its derivatives, such as 2‐(4‐amino‐5‐nitro‐1,2,3‐trazole‐1‐yl)‐1,3,5‐trinitrobenzene (T‐ANTZ) and 4‐amino‐5‐nitro‐1,2,3‐triazole (M‐ANTZ), were synthesized and characterized, whose structures were confirmed by IR, NMR and elemental analysis. The thermal behaviors of ANTZ, T‐ANTZ and M‐ANTZ were studied by the methods of DSC and TG‐DTG, and the results showed that there is an obvious melting process of ANTZ with melting point of 278.38°C, while there is no melting process in the thermal behavior of T‐ANTZ and M‐ANTZ (the derivatives of ATNZ). 相似文献
147.
Chang-Hong Huo Li-Ru Shen Françoise Sauriol Man-Li Zhang Hiromasa Kiyota 《Tetrahedron letters》2010,51(4):754-7522
One novel tetranortriterpenoid derivative, xylocarponoid A, representing the first example of C28 skeleton limonoid, was isolated from the seeds of the Chinese mangrove, Xylocarpus granatum. Its C-1′-epimer, xylocarponoid B, was formed in CDCl3. Their structures were elucidated by extensive spectroscopic analysis. A plausible biosynthetic pathway of xylocarponoid A was proposed. 相似文献
148.
The hydrothermal reaction of Cd(NO3) · 4H2O with 4,4′‐bipyridine (bipy) and 3‐carboxyphenoxyacetatic acid (3‐H2CPOA) afforded a 3D metal‐organic framework (MOF) [Cd(3‐CPOA)(bipy)]n · 3.5nH2O, which was characterized by elemental analyses, IR spectroscopy, thermogravimetric analyses, and X‐ray diffraction. The single‐crystal structural analysis revealed that it has a Cds‐type topological network with 1D channels that contain encapsulated water molecular tapes. 相似文献
149.
Jing Jin Zhiping Zhang Jincheng Wang Peipei Qi Jiping Chen 《Journal of separation science》2010,33(12):1836-1841
Magnesium oxide microspheres were developed as a novel SPE sorbent for the determination of benzo[a]pyrene (BaP), one of the most potent carcinogenic agents, in environmental water samples. The parameters controlling the extraction efficiency, such as elution volume, flow rate, pH values, and breakthrough volume, were investigated in detail. Considering the facile preparation and satisfying recovery, a corresponding analytical method has been developed to determine the concentration of BaP in real tap water, river water, and seawater. The recoveries for the spiked BaP were excellent (94–101%). 相似文献