Ionothermal synthesis and structure analysis of an open-framework zirconium phosphate with a high CO2/CH4 adsorption ratio

Less is more: an open-framework zirconium phosphate with unusual 7-ring channels was synthesized ionothermally from a deep-eutectic solvent. This small-pore material displays a CO(2)/CH(4) adsorption ratio (17.3 at 1 bar) that is significantly higher than that of typical 8-ring materials, making it highly attractive for CO(2)/CH(4) separations.     

Cross-section measurements for the 58,60,61Ni(n, α)55,57,58Fe reactions at 8.50, 9.50 and 10.50 MeV neutron energies

Cross sections of the ^58,60,61Ni(n, α)^55,57,58Fe reactions were measured at 8.50, 9.50 and 10.50 MeV neutron energies based on the HI-13 tandem accelerator of China Institute of Atomic Energy (CIAE) with enriched ⁵⁸Ni, ⁶⁰Ni, and ⁶¹Ni foil samples with backings. A twin gridded ionization chamber (GIC) was used as the charged particle detector, and an EJ-309 liquid scintillator was used to obtain the neutron energy spectra. The relative and absolute neutron fluxes were determined via three highly enriched ²³⁸U₃O₈ samples inside the GIC. The uncertainty of the present data of the ⁵⁸Ni(n, α)⁵⁵Fe reaction is smaller than most existing measurements. The present data of ⁶⁰Ni(n, α)⁵⁷Fe and ⁶¹Ni(n, α)⁵⁸Fe reactions are the first measurement results above 8 MeV. The present experimental data could be reasonably reproduced by calculations with TALYS-1.9 by adjusting several default values of theoretical model parameters.     

含孔正交各向异性复合材料板的动应力集中

运用一种改进的非结构化四边形格子法,对含孔正交各向异性板条受面内冲击拉伸时弹性应力波的传播过程和孔边的动应力集中进行了研究．非结构化格子法采用与有限元类似的网格剖分方法,并基于围绕每个节点的积分平衡方程,并自然满足复杂边界的自由边界条件．计算中不需存储刚度矩阵,因而计算速度快、效率高、节省内存,在解决应力波传播问题中具有显著的优越性．通过对多种工况进行数值模拟,分析了材料的各向异性性质、纤维方向、孔径比、加载脉冲周期等参数对孔边动应力的影响,得到了一些规律性的结果．并与现有实验结果进行对比,验证了该方法的有效性．     

合肥光源40kW高频固态发射机的研制进展

介绍了用于合肥光源800 MeV电子储存环高频系统的204 MHz,40 kW固态发射机的研制进展。该发射机为双塔结构,由130个330 W功放模块进行三级合成。其关键部件的样件包括10路功放和2.5kW八合一,20 kW八合一以及40 kW二合一功率合成器各1件的制作和测试已完成。测得各合成器输出端驻波比不超过1.05,功放模块的增益达到26 dB,幅相偏差小于0.1 dB和5°,达到设计要求。     

MCM－41中孔分子筛的合成及其性质

以十六烷基三甲基溴化铵（ＣＴＡＢ）作模板剂，研究了水热体系中中孔ＭＣＭ－４１分子筛的合成条件。在Ｈ_２Ｏ／Ｓｉ介于１２～１００，Ｓｉ／Ａｌ介于１０～∞，ＣＴＡＢ／Ｓｉ介于０．０８～０．２时，可以合成出ＭＣＭ－４１分子筛。在加入煤油等混合烃的合成体系中，可以合成出孔径大于４ｎｍ的ＭＣＭ－４１分子筛。用ＸＲＤ、ＳＥＭ、Ｎ_２吸附对合成样品加以表征，证明它们具有典型的中孔分子筛特性。探针反应证明它具有中强酸中心。     

Determination of lead by hydride generation atomic absorption spectrometry : Part 1. A new medium for generating hydride

A new medium, used to generate lead hydride, was optimized as 0.3% (w/v) oxalic acid-2% (w/v) ammonium cerium (III) nitrate-8% (w/v) potassium tetrahydroborate-1% (w/v) sodium hydroxide solution; 950°C is used for atomization. The characteristic concentration (0.0044 absorbance) obtained under these conditions was 0.04 ng ml^?1. The application of this medium to soil and ferromagano-brass samples is illustrated.     

在极浓体系中合成中孔(MESOPOROUS)Si-MCM-41分子筛及其性质

由无定形凝胶体系Na₂O-SiO₂-CTAB(十六烷基三甲基溴化铵)-H₂O，在控制H₂O/Si≤5.0的极浓条件下，研究了Si-MCM-41分子筛的合成条件。在H₂O/Si=1.0-5.0, CTAB/Si=0.0125-0.125; Na/Si=0.05-0.15时，均可合成Si-MCM-41分子筛。该体系特点是CTAB消耗明显降低。XRD、SEM、TG-DTA和N₂吸附性质表征了合成的MCM-41分子筛，证明本法合成产物具有典型的MCM-41分子筛特性。     

Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions

Reactions of the hydrido‐butenylcarbyne complex [OsHCl₂(≡CC(PPh₃)=CHEt)(PPh₃)₂]BF₄ ( 1 ) with nitriles RC≡N (R=2‐cyclopropyl‐2‐oxopropyl, 3‐amino‐2‐oxobutyl) lead to six‐membered cyclic vinylidene complexes 3 and azavinylidene complexes 4 , that is, iso‐osmapyridiniums. Treatment of 1 with excess 2‐formylbenzonitrile at reflux temperature in CHCl₃ in the presence of air produces a fused osmapyridinium 8 , which is first oxidized to the tricyclic iso‐osmapyridinium derivative 7 , then to iso‐osmapyridinium 9 , which contains a fused naphthalenone fragment. The conversion of iso‐osmapyridinium 9 (with a vinylidene segment) to the iso‐osmapyridinium compounds 10 and 11 (with azavinylidene segments) was achieved in the presence of a hydrogen halide, such as HCl or HI. The molecular structures of the complexes synthesized were confirmed by X‐ray studies. Moreover, the aromatic stabilization energy and nucleus‐independent chemical‐shift values of the osmapyridiniums and the strain in the iso‐osmapyridinium rings were investigated by DFT calculations.     

Research on warehouse design and performance evaluation: A comprehensive review

This paper presents a detailed survey of the research on warehouse design, performance evaluation, practical case studies, and computational support tools. This and an earlier survey on warehouse operation provide a comprehensive review of existing academic research results in the framework of a systematic classification. Each research area within this framework is discussed, including the identification of the limits of previous research and of potential future research directions.     

Ionothermal Synthesis of Zirconium Phosphates and Their Catalytic Behavior in the Selective Oxidation of Cyclohexane

On their best behavior : Three zirconium compounds with one‐, two‐, and three‐dimensional structures have been successfully synthesized by the ionothermal approach. The 3D zirconium phosphate (see picture; F green, H white, O red, P pink, Zr yellow) exhibits high catalytic performance, with a cyclohexane conversion ratio of 32 % and cyclohexanone selectivity of up to 83 %.