Highly Efficient Ultrasonic‐Assisted CuCl‐Catalyzed 1,3‐Dipolar Cycloaddition Reactions in Water: Synthesis of Coumarin Derivatives Linked with 1,2,3‐Triazole Moiety

By introducing ultrasound irradiation into “on water” CuCl‐catalyzed 1,3‐dipolar Huisgen cycloaddition, the reaction efficiencies were notably promoted toward a wide variety of applicable azides and alkynes at room temperature, and a series of coumarin derivatives linked with 1,2,3‐triazole moiety were synthesized using the optimized conditions.     

H2Pc-VOPc二元体系的制备和表征

八十年代,国外Canon,IBM,HP,Ricoh,Xerox等公司开发出由计算机控制、数字扫描、激光成像的高分辨激光打印机,并逐渐占领市场。这种激光打印机具有印刷质量高、寿命长、印刷速度快、版面可任意调制、噪音小等特点。     

几种方酸菁染料的NMR及光谱特性研究

研究了几种方酸菁染料的核磁、可见、荧光光谱。通过二维核磁共振谱和¹³CNMR确定了分子的结构和构型。测定了其在不同溶剂中吸收光谱和荧光发射光谱及其发射的荧光量子产率。发现它具有微弱的正向溶致变色特性,通过光谱特征分析得出整个分子处于平面结构并形成一个长的共轭体系,其激发态和基态的结构相近的结论。同时,讨论了结构对分子电荷分布及相应荧光光谱特征的影响。     

两种新型阳离子吲哚啉螺吡喃的合成、表征和光致变色性质的研究

螺吡喃是一类重要的光致变色化合物．螺吡喃的正向光致变色是指在紫外光照下,螺吡喃分子的Ｃ—Ｏ键异裂,由闭环无色体（ＳＰ）可逆地变成开环有色体（ＭＣ）．所形成的有色体可以在暗条件下热致褪色或在可见光照下褪成无色体（示意图１）．它的逆向光致变色是指某一类螺...     

HL—1M装置器壁硅化对电子速率分布的影响

在欧姆加热和低混杂波电流驱动条件下,利用磺化汞半导体探测器和碘化钠和探测器测出了ＨＬ－１Ｍ装置的Ｘ射线能谱,研究了器壁硅化前后电子速率分布和电子温度变化的特点,给出了Ｘ射线辐射强度与ＬＨＣＤ能量沉积的关系。     

Improved Deep Q-Network for User-Side Battery Energy Storage Charging and Discharging Strategy in Industrial Parks

Battery energy storage technology is an important part of the industrial parks to ensure the stable power supply, and its rough charging and discharging mode is difficult to meet the application requirements of energy saving, emission reduction, cost reduction, and efficiency increase. As a classic method of deep reinforcement learning, the deep Q-network is widely used to solve the problem of user-side battery energy storage charging and discharging. In some scenarios, its performance has reached the level of human expert. However, the updating of storage priority in experience memory often lags behind updating of Q-network parameters. In response to the need for lean management of battery charging and discharging, this paper proposes an improved deep Q-network to update the priority of sequence samples and the training performance of deep neural network, which reduces the cost of charging and discharging action and energy consumption in the park. The proposed method considers factors such as real-time electricity price, battery status, and time. The energy consumption state, charging and discharging behavior, reward function, and neural network structure are designed to meet the flexible scheduling of charging and discharging strategies, and can finally realize the optimization of battery energy storage benefits. The proposed method can solve the problem of priority update lag, and improve the utilization efficiency and learning performance of the experience pool samples. The paper selects electricity price data from the United States and some regions of China for simulation experiments. Experimental results show that compared with the traditional algorithm, the proposed approach can achieve better performance in both electricity price systems, thereby greatly reducing the cost of battery energy storage and providing a stronger guarantee for the safe and stable operation of battery energy storage systems in industrial parks.     

化学探头法与荧光光谱法测定水中溶解氧量

探讨了化学探头法和荧光光谱法测定水中溶解氧的关系。分别用F检验和t检验对两组数据进行了比较,结果表明两组数据的精密度和系统误差都没有显著差异,两种方法测定溶解氧的相对标准偏差(RSD,n=9)分别为0.35%,0.33%。进而又探讨了溶解氧与NaCl含量、温度之间的关系,结果表明溶解氧含量随NaCl含量的增加、温度的升高而逐渐降低。     

A novel parallel quantum genetic algorithm for stochastic job shop scheduling

In this paper, a Novel Parallel Quantum Genetic Algorithm (NPQGA) is proposed for the stochastic Job Shop Scheduling Problem with the objective of minimizing the expected value of makespan, where the processing times are subjected to independent normal distributions. Based on the parallel evolutionary idea and some concepts of quantum theory, we simulate a model of parallel quantum computation. In this frame, there are some demes (sub-populations) and some universes (groups of populations), which are structured in super star-shaped topologies. A new migration scheme based on penetration theory is developed to control migration rate and direction adaptively between demes, and a novel quantum crossover strategy is devised among universes. The quantum evolution is executed in every deme by applying some improvement operators (the coding mechanism aiming at job shop, the new quantum rotation angle and the catastrophe operator). Experiment results show NPQGA's effectiveness and applicability.     

可靠性数值模拟的不确定度量化

根据可靠性认证对不确定度量化的技术要求,结合复杂工程系统的层级结构和数值模拟从校准、验证与确认到最终具有预测能力的历程,对可靠性数值模拟不确定度量化的要求和方法进行探索,并结合爆轰算例对这些方法进行演示和验证.     

Mechanism of the Selective Catalytic Reduction of NOx with NH3 over W-Doped Fe/TiO2 Catalyst

The W-doped Fe/TiO2 catalyst prepared by an impregnation method exhibited a good NH3-selective cata- lytic reduction（SCR） activity and N2 selectivity with broad operation temperature window. The interaction between Fe and W could increase the amount of surface chemisorbed oxygen, and thus enhances the low temperature SCR activity by facilitating the fast SCR of 2NH3＋NO＋NO2 →2N2＋3H2O. The NH3-SCR reaction mechanism over the W-Fe/TiO2 was fully investigated via in situ diffuse reflectance infrared Fourier transform spectroscopy（in situ DRIFTS）. In the low temperature range（〈250 ℃）, the reactive surface species were mainly coordinated NH3, ionic NH~ and adsorbed NO2 species, and the SCR mainly followed the Langmuir-Hinshelwood mechanism, during which the adsorbed NO2 species became the important active sites. In the high temperature range（〉250 ℃）, the reactive surface species were mainly NH2, and the SCR mainly followed the Eley-Rideal mechanism, during which the for- mation of NH2NO intermediate species after H-abstraction of NH3 was the rate-determining step.