磁驱动高速飞片模拟中滑移界面处理

在二维单介质磁驱动数值模拟程序(MDSC2)的基础上,采用局部结构整体非结构的网格拼接方法,研制了处理滑移界面的二维多介质程序。二维多介质程序解决了单介质程序无法处理的电极与飞片之间相互作用的模拟问题,能更准确地模拟磁驱动发射实验的飞片状态。计算结果表明:发射飞片的自由面部分始终保持固体密度状态;自由面速度历史和VISAR测量的速度曲线相吻合;飞片中间部分在电流加载过程中始终具有良好的平面性,飞片两端出现拖尾质量,产生不稳定性,这是由于飞片两端与飞片中间部分的磁场强度分布不同造成的。     

Mg-CO(X1Σ+)体系的冷碰撞动力学

应用量子散射动力学方法, 研究了电场条件下Mg-CO体系的冷碰撞动力学性质, 探索了外电场对碰撞体系低场追索态的弹性和非弹性截面的影响, 为碱土金属Mg原子感应冷却CO分子提供理论预测.     

Ethylene/1‐Hexene Copolymerization with A Novel SiO2‐Supported Inorganic and Organic Hybrid Chromium‐based Catalyst

In this work, ethylene/1‐hexene copolymerization with a novel SiO₂‐supported inorganic and organic hybrid chromium‐based catalyst was investigated. This catalyst was prepared using the residual surface hydroxyl groups in Phillips catalyst to support bis(triphenylsilyl) chromate (BC) in order to get the merits from two important chromium‐based catalysts namely inorganic Phillips and organic S‐2 catalysts. The influences of addition amount of 1‐hexene and BC were systematically investigated. With increasing 1‐hexene from 0 to 7 vol%, the activity of HCat‐2 catalyst showed a decreasing tendency. Its copolymer also showed the better short chain branches distribution through the temperature rising elution fractionation cross successive self‐nucleation and annealing characterization.

     

无皂乳液聚合法合成阴离子PS微球及粒径控制

以苯乙烯(St)和丙烯酸(AA)为单体,过硫酸钾(KPS)为引发剂,采用无皂乳液聚合法合成了单分散阴离子聚苯乙烯(PS)微球,并对微球结构和影响单分散性的因素进行了研究。结果表明,AA单体也已共聚到聚合物链上,AA的加入使PS微球粒径减小,并赋予PS微球表面负电性;聚合反应的活化能为42.95kJ/mol,升高聚合温度提高了反应速率;随着KPS用量的增加,PS微球粒径减小,在用量为0.6%时呈现最好单分散性;随着反应介质中丙酮含量增加,聚合物在介质中溶解度增加,使PS微球粒径有所减小,但微球粒径分布有所变宽。     

一般型三维簇的三典范映射

研究了一般型三维射影代数簇的三典范映射性质.当几何亏格p_g≥2时,整数m≥4的多典范映射结构已经比较清晰,但是三典范映射的结构还有很多未知问题.如果三典范映射φ_3不是双有理的,本文证明了φ_3的映射次数(如果φ_3是一般有限映射)或者一般纤维中一般不可约分支的几何亏格(如果φ_3是纤维型)有一个上界.     

社会互动,投资者情绪传染与资产泡沫——基于股票论坛发帖的实证研究

在资本市场中,投资者并不是相互独立的个体,而是相互学习、相互交流的。随着互联网的迅猛发展,这种社会互动变得更为频繁和普遍,因此社会互动对资产价格的影响也不容小觑。本文先通过理论建模提出理论假设:社会互动存在条件下,投资者互动会加剧市场情绪的传染,进而增加资产泡沫;当投资者情绪高涨时,投资者互动强度显著正向影响泡沫;当投资者情绪低落时,投资者互动强度显著负向影响泡沫;受社会互动影响,投资者活跃的交易会加剧市场情绪的传染,进而增加资产泡沫。之后本文基于股票论坛发帖构建社会互动、投资者情绪指标,验证了中国股票市场中本文理论假设的正确性。     

Preparation and reducing-responsive property of a novel functional polyurethane nanoemulsion

As a kind of stimuli-responsive materials,the disulfide-containing material has received a tremendous amount of interest.A novel functional disulfide-containing waterborne polyurethane(DS-WPU)nanoemulsion was prepared via a one-step in situ phase inverse emulsification technique and its reducing-responsive prope rty was investigated using dithiothreitol as the reductant.Results showed that the DS-WPU nanoemulsion had a uniform particle size in nanoscale and a good film-forming characteristic,and the DS-WPU latex film exhibited great responsiveness along with a self-assembled behavior in the reducing environment to form WPU emulsion again,including a long-to-short process of the polymer chains.     

A Sodalite‐Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster

The synthesis and structure of a giant 102‐silver‐atom nanocluster (NC) 1 is presented. X‐ray structural analysis reveals that 1 features a multi‐shelled metallic core of Ag₆@Ag₂₄@Ag₆₀@Ag₁₂. An octahedral Ag₆ core is encaged by a truncated octahedral Ag₂₄ shell. The Ag₂₄ shell is composed of a hitherto unknown sodalite‐type silver orthophosphate cluster (SOC) {(Ag₃PO₄)₈}, reminiscent of the Ag₃PO₄ photocatalyst. The SOC is capped by six interstitial sulfur atoms, giving a unique anionic cluster [Ag₆@{(Ag₃PO₄)₈}S₆]^6?, which functions as an intricate polyhedral template with abundant surface O and S atoms guiding the formation of a rare rhombicosidodecahedral Ag₆₀ shell. An array of 6 linear Ag₂ staples further surround this Ag₆₀ shell. [Ag₆@{(Ag₃PO₄)₈}S₆]^6? is an unusual Ag‐based templating anion to induce the assembly of a SOC within silver NC. This finding provides molecular models for bulk Ag₃PO₄, and offers a fresh template strategy for the synthesis of silver NCs with high symmetry.     

A novel approach to prepare core/shell polymer latex particles with high sulphonate contents

Crosslinked x-P(St-MAA) seed latex was first prepared via soap-free emulsion copolymerization of styrene (St) and methyl methacrylic acid (MAA) with divinyl benzene as crosslinker and ammonium persulfate as initiator, and x-P(St-MAA)/x-P(St-NaSS) core/shell latex particles were then synthesized through a novel seeded emulsion copolymerization of St and sodium styrene sulphonate (NaSS) in the presence of water-soluble crosslinker N,N′-methylene bisacrylamide (BAA) using oil-soluble 2,2-azobis isobutyronitrile as initiator. TEM observation indicated that narrow dispersed core/shell latex particles were obtained, and element analysis showed that NaSS unit content in the whole particle and in the shell reached 22.8 wt% and 51.2 wt%, respectively.