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71.
Jingyan Si Ya Liu Shunzhou Chang Di Wu Baozhu Tian Jinlong Zhang 《Research on Chemical Intermediates》2017,43(4):2067-2080
AgBr@TiO2/GO (graphene oxide) ternary composite photocatalyst was synthesized by fabricating core–shell-structured AgBr@TiO2 and anchoring it onto the surface of GO. The obtained samples were characterized by transmission electron microscopy, X-ray diffraction analysis, X-ray photoelectron spectroscopy, ultraviolet–visible (UV–Vis) diffuse reflectance spectrum, and photoluminescence (PL) spectroscopy. It was found that the AgBr nanoparticles were prone to aggregation while the core–shell-structured AgBr@TiO2 possessed excellent dispersity. PL analysis revealed that the ternary-structured AgBr@TiO2/GO could effectively promote the separation rate of electron–hole pairs. Photocatalytic oxidation of benzyl alcohol to benzaldehyde under visible-light irradiation was selected as probe reaction to evaluate the photocatalytic activity of the different samples. It was found that the AgBr@TiO2/GO ternary composite exhibited evidently improved photocatalytic activity compared with AgBr, AgBr@TiO2, and AgBr/GO. On the basis of the experiment results, the photocatalytic oxidation mechanism of benzyl alcohol over AgBr@TiO2/GO is tentatively discussed. 相似文献
72.
The passive film of iron showed n‐type semiconductor characteristic in borate buffer solution, and its donor concentration increased slightly after tensile strain in the present study. However, comparing with solution‐annealed sample, the anodic passive film formed on tensile‐strained one was highly protective. The more dislocations on tensile‐strained sample promoted the diffusion of iron and oxygen vacancy. Moreover, more donor density (mainly oxygen vacancies) promoted the diffusion of oxygen. They all facilitated tensile‐strained sample to form Fe2O3 and thicker passive film on the surface. More Fe2O3 and thicker passive film on the surface of tensile‐strained iron could improve corrosion resistance. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
73.
A novel tunable chirped fiber Bragg grating is realized by bending a piece of D-shaped fiber Bragg grating into a specific shape like the character ‘Ω’. The principle of tuning is demonstrated by numerical simulation. The dispersion of the grating can be tuned while the center wavelength is kept nearly no shift. The experimental results match well with the numerical analysis. The influence from D-shaped fiber’s birefringence and polarization dependent loss is discussed theoretically and experimentally as well. This proposed tuning technique has potential applications in the optical communications and other fiber optics systems. 相似文献
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75.
YAN Liuqing FU Jiaxu LI Shuang ZHANG Jinlong WANG Shuang GU Qiang ZHANG Yumin LIN Feng 《高等学校化学研究》2021,37(3):639-646
An efficient and facile method was introduced for the synthesis of benzimidazoles in this paper. The optimum reaction conditions were determined. A series of benzimidazoles bearing phenolic hydroxyl(2a-2t) were synthesized in moderate to excellent yields starting from differently substituted hydroxyl benzaldehyde and 4-position substituted o-phenylenediamine via nucleophilic addition in the presence of catalyst Na2S2O5 under microwave irradiation condition. Herein, effects of the catalyst, molar ratio of reactants, reaction temperature and solvent were investigated. The optimal reaction condition was determined. The effect of DMF and EtOH solvent on the reaction was compared. The synthesized compounds were characterized by FTIR, HRMS, 1H NMR and 13C NMR spectroscopy. Further, the bacteriostatic activities of the synthesized compounds were evaluated with ciprofloxacin and itraconazole as a positive control, respectively. Compounds 2b, 2n, 2q and 2r exhi-bited some antibacterial activity. The lowest MIC of antibacterial activity of compound 2b was 32 μg/mL. Meanwhile, the luminescence property of compound 2b was studied. The antibacterial activity of compound 2b, along with their good fluorescence performance highlighted the potential of these compounds as lead structures and owned fluorescence trace for further study towards the development of novel drugs and functional mechanisms in living organisms. 相似文献
76.
Xianfeng?You Feng?Chen Jinlong?ZhangEmail author 《Journal of Sol-Gel Science and Technology》2005,34(2):181-187
TiO2 powders were prepared by sol–gel template method and calcined under different conditions. XRD, BET and TEM were used to characterize the TiO2 powders obtained. The photocatalytic activity of TiO2 was investigated by the degradation of methyl orange. It was found that TiO2 powder has the highest photocatalytic activity at a calcination temperature of 673 K. The effects of physical properties such as surface area, crystallinity and crystal phase on the photocatalytic activity of TiO2 were discussed. 相似文献
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78.
Assoc. Prof. Dr. Tuo Wang Prof. Dr. Jinlong Gong 《Angewandte Chemie (International ed. in English)》2015,54(37):10718-10732
Solar water splitting provides a clean and renewable approach to produce hydrogen energy. In recent years, single‐crystal semiconductors such as Si and InP with narrow band gaps have demonstrated excellent performance to drive the half reactions of water splitting through visible light due to their suitable band gaps and low bulk recombination. This Minireview describes recent research advances that successfully overcome the primary obstacles in using these semiconductors as photoelectrodes, including photocorrosion, sluggish reaction kinetics, low photovoltage, and unfavorable planar substrate surface. Surface modification strategies, such as surface protection, cocatalyst loading, surface energetics tuning, and surface texturization are highlighted as the solutions. 相似文献
79.
80.
Let D(G)=(di,j)n×n denote the distance matrix of a connected graph G with order n, where dij is equal to the distance between vi and vj in G. The largest eigenvalue of D(G) is called the distance spectral radius of graph G, denoted by ?(G). In this paper, we give some graft transformations that decrease and increase ?(G) and prove that the graph (obtained from the star Sn on n (n is not equal to 4, 5) vertices by adding an edge connecting two pendent vertices) has minimal distance spectral radius among unicyclic graphs on n vertices; while (obtained from a triangle K3 by attaching pendent path Pn−3 to one of its vertices) has maximal distance spectral radius among unicyclic graphs on n vertices. 相似文献