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91.
In this research, a simple, sensitive chemiluminescence (CL) method for the determination of humic acid (HA) in water samples was first developed based on the redox reaction between humic acid and cerium(IV) in the acidic condition. Different with the former redox CL reaction which occurred in alkaline solution, no enhancers were needed and neither precipitation nor a second contamination would occur in the present CL system. Comparing with other spectrometric methods, we find that the proposed analysis system had better applicability and accuracy. Under the optimal experiment conditions, the CL peak height was linear with the concentration of HA in the range of 0.03 to 10.0 microg mL(-1). The detection limit is 0.01 microg mL(-1) (S/N = 3), and the relative standard deviation was 2.3% for 0.5 microg mL(-1) HA solution with eleven repeated measurements. The present CL method was successfully applied to the determination of HA in tap water, spring water and river water samples with good recovery from 90.0 to 110.0%. A possible CL mechanism was proposed based on the results of UV and fluorescence spectrometry and the CL spectrum of HA. It was speculated that the semi-quinone radicals in the excited state were the emitters. 相似文献
92.
Dorota G?azowska Janusz Matkowski 《Journal of Mathematical Analysis and Applications》2007,331(2):1187-1199
The invariance of the geometric mean G with respect to the Lagrangian mean-type mapping (Lf,Lg), i.e. the equation G○(Lf,Lg)=G, is considered. We show that the functions f and g must be of high class regularity. This fact allows to reduce the problem to a differential equation and determine the second derivatives of the generators f and g. 相似文献
93.
In the paper we indicate an error made in the proof of the main result of the paper [M.A. Darwish, On quadratic integral equation of fractional orders, J. Math. Anal. Appl. 311 (2005) 112-119]. Moreover, we provide correct proof of a slightly modified version of the mentioned result. The main tool used in our proof is the technique associated with the Hausdorff measure of noncompactness. 相似文献
94.
In this paper we deal with nonlinear second-order boundary value problems with impulses. The impulsive functions depend implicitly on the different considered variables and the boundary value conditions are nonlinear. In both cases functional dependence on the solution is allowed. The existence results follow from the existence of a pair of well-ordered lower and upper solutions. 相似文献
95.
S?awomir Solecki 《Topology and its Applications》2007,154(12):2462-2464
Let I0 be the σ-ideal of subsets of a Polish group generated by Borel sets which have perfectly many pairwise disjoint translates. We prove that a Fubini-type theorem holds between I0 and the σ-ideals of Haar measure zero sets and of meager sets. We use this result to give a simple proof of a generalization of a theorem of Balcerzak-Ros?anowski-Shelah stating that I0 on N2 strongly violates the countable chain condition. 相似文献
96.
Lanju Xu 《Discrete and Computational Geometry》2007,37(3):485-491
The lower bounds for the translative kissing numbers of superballs are studied in this note. We improve the bound given by
Larman and Zong. Furthermore, we give a constructive bound based on algebraic-geometry codes that also improves the bound
by Larman and Zong in almost all cases. 相似文献
97.
98.
R. Knizikevi?ius 《Applied Surface Science》2006,253(3):1581-1583
The ion-beam-assisted etching of silicon in Cl2 environment is considered. The theoretically calculated dependences of silicon etching rate on the flux of Cl2 molecules at different ion current densities are compared with experimentally measured. The composition of the adsorbed layer is determined. It is found that SiCl2 molecules prevail in the adsorbed layer. The reciprocal of relative concentration of SiCl2 molecules in the adsorbed layer linearly depends on the ion-to-neutral flux ratio. 相似文献
99.
In this paper we formulate a theorem on the persistence of elliptic lower-dimensional invariant tori for nearly integrable analytic Hamiltonian systems under the first Melnikov condition and Rüssmann’s non-degeneracy condition, and give the measure estimates of parameters for the non-resonance conditions under Rüssmann’s non-degeneracy condition, which is essential for the proof of our result. 相似文献
100.
This work reports a new synthetic approach for single‐phase TiO2 nanomaterials by solvothermal treatment of titanium tetrachloride in acetone at 80–110 °C. Small, uniform, and yet size‐tunable (5–10 nm) anatase titania nanocrystallites were obtained using a low concentration of TiCl4 in acetone (i.e., at molar ratios of TiCl4/acetone ≤ 1:15) in the temperature range of 80–110 °C, while rutile nanofibers were synthesized using a high concentration of TiCl4 (e.g., TiCl4/acetone = 1:10) at 110 °C. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献