Using the tricyano precursor (Bu(4)N)[(Tp)Cr(CN)(3)] (Bu(4)N(+) = tetrabutylammonium cation; Tp = tris(pyrazolyl)hydroborate), a pentanuclear heterometallic cluster [(Tp)(2)Cr(2)(CN)(6)Cu(3)(Me(3)tacn)(3)][(Tp)Cr(CN)(3)](ClO(4))(3)·5H(2)O (1, Me(3)tacn = N,N',N'-trimethyl-1,4,7-triazacyclononane), three tetranuclear heterometallic clusters [(Tp)(2)Cr(2)(CN)(6)Cu(2)(L(OEt))(2)]·2.5CH(3)CN (2, L(OEt) = [(Cp)Co(P(O)(OEt)(2))(3)], Cp = cyclopentadiene), [(Tp)(2)Cr(2)(CN)(6)Mn(2)(L(OEt))(2)]·4H(2)O (3), and [(Tp)(2)Cr(2)(CN)(6)Mn(2)(phen)(4)](ClO(4))(2) (4, phen = phenanthroline), and a one-dimensional (1D) chain polymer [(Tp)(2)Cr(2)(CN)(6)Mn(bpy)](n) (5, bpy = 2,2'-bipyridine) have been synthesized and structurally characterized. Complex 1 shows a trigonal bipyramidal geometry in which [(Tp)Cr(CN)(3)](-) units occupy the apical positions and are linked through cyanide to [Cu(Me(3)tacn)](2+) units situated in the equatorial plane. Complexes 2-4 show similar square structures, where Cr(III) and M(II) (M = Cu(II) or Mn(II)) ions are alternatively located on the rectangle corners. Complex 5 consists of a 4,2-ribbon-like bimetallic chain. Ferromagnetic interactions between Cr(III) and Cu(II) ions bridged by cyanides are observed in complexes 1 and 2. Antiferromagnetic interactions are presented between Cr(III) and Mn(II) ions bridged by cyanides in complexes 3-5. Complex 5 shows metamagnetic behavior with a critical field of about 22.5 kOe at 1.8 K. 相似文献
Phytohemical investigation on the heartwood of Dalbergia odorifera resulted in the isolation of nine flavonoids. Their structures were elucidated as sativanone (1), (3R)-vestitone (2), (3R)-2',3',7-trihydroxy-4'-methoxyisoflavanone (3), (3R)-4'-methoxy-2',3,7-trihydroxyisoflavanone (4), carthamidin (5), liquiritigenin (6), isoliquiritigenin (7), (3R)-vestitol (8), and sulfuretin (9) based on their spectral data. All compounds were evaluated for their inhibitory activity against Ralstonia solanacearum. This is the first report about anti-R. solanacearum activity of the compounds from D. odorifera. 相似文献
A [70]fullerene-benzodifuranone acceptor dyad synthesized by a Ag?-mediated coupling reaction was used to construct a thin-film organic solar cell. The fullerene and the benzodifuranone dye in the dyad have close-lying LUMO levels in the range of 3.7-3.9 eV, so that energy transfer from the dye to the fullerene can take place. A p-n heterojunction photovoltaic device consisting of a tetrabenzoporphyrin and a [70]fullerene-benzodifuranone dyad showed a weak but discernible contribution from light absorption of the dyad to the photocurrent under both a positive and a negative effective bias. These results indicate that the benzodifuranone moiety attached to the acceptor contributes to light-harvesting by energy transfer. 相似文献
Gatifloxacin (GAFX), P-aminomethylbezoic acid (PAMBA), cefazolin (CFZL) and cefminox (CMNX) can be combined and administered perorally or intravenously, and are excreted mainly into the urine. A novel capillary zone electrophoresis (CZE) method was developed, for the first time, for an effective separation and simultaneous determination of the said four drugs in human urine. The electrophoresis conditions were investigated and optimized. A 25 mM borate buffer (pH 9.2) was used and the peak area was determined with UV detection. Under optimal conditions, the four drugs can be separated effectively. Good linearity was achieved with the correlation coefficients (r2) of > 0.999. The limit of detection (LOD) for PAMBA, GAFX, CFZL and CMNX was 5.8, 3.9, 7.8 and 15.0 ??g ml?1, respectively. Their average recovery in human urine was 93.2, 98.3, 108 and 92.7%, respectively, with the RSDs ranging from 1.0% to 3.5%. The proposed method is simple, rapid and accurate, and provides the sensitivity and linearity necessary for the selective and simultaneous analysis of the test drugs in human urine at clinically relevant concentrations. 相似文献
In this paper, we employ qualitative analysis and methods of bifurcation theory to study the maximum number of limit cycles for a polynomial system with center in global bifurcation. 相似文献
This paper deals with the global asymptotic stabilization and finite-time stabilization issues for variable-order fractional systems with partial a priori bounded disturbances by designing an appropriate adaptive controller. Via the inductive method and Arzela-Ascoli theorem, the existence and uniqueness of the solution for the considered system is firstly verified under the proposed control strategy. By applying Lyapunov stability theory, non-smooth analysis and inequality technique, sufficient stabilization criteria are established under the framework of variable-order fractional Filippov differential inclusion. Finally, two numerical simulations are given to demonstrate the validity of the proposed method.
In this work, Au-modified F-TiO2 is developed as a simple and efficient photocatalyst for H2O2 production under ultraviolet light. The Au/F-TiO2 photocatalyst avoids the necessity of adding fluoride into the reaction medium for enhancing H2O2 synthesis, as in a pure TiO2 reaction system. The F− modification inhibits the H2O2 decomposition through the formation of the ≡Ti–F complex. Au is an active cocatalyst for photocatalytic H2O2 production. We compared the activity of TiO2 with F− modification and without F− modification in the presence of Au, and found that the H2O2 production rate over Au/F-TiO2 reaches four times that of Au/TiO2. In situ electron spin resonance studies have shown that H2O2 is produced by stepwise single-electron oxygen reduction on the Au/F-TiO2 photocatalyst. 相似文献
This paper proposes a new method for eliminating impulse noise. Based on the space characteristic of object and noise, three kinds of basic noise patterns are introduced to describe noise and detect noise candidates. Correspondingly, noise removal operators are presented to remove the impulse noise. Extensive experiment results have shown that the proposed method is better than some of the state-of-the-art methods. 相似文献
In this paper, we propose a radial stereo imaging system for three-dimensional reconstruction of an object. This system uses a novel optical device which consists of a camera and two reflected mirrors. It can reconstruct three-dimensional model of an object by capturing one image. Depending on the reflection of the mirrors, each world point in the scene has a pair of points which sit in the inner and outer of the captured image, respectively. We firstly analyze the imaging constraint of the proposed system, and then derive the geometrical relationship between world point and image point pair to calculate the three-dimensional coordinate values of an arbitrary point on the object, which means that the three-dimensional model of the object can be recovered. Experiments are carried out to prove our design, and the results show that our radial stereo imaging system is convenient and effective for the three-dimensional reconstruction of an object. This system can be used in variety of applications, such as virtual reality and commodity show. 相似文献