全文获取类型
收费全文 | 3731篇 |
免费 | 616篇 |
国内免费 | 531篇 |
专业分类
化学 | 2912篇 |
晶体学 | 70篇 |
力学 | 182篇 |
综合类 | 42篇 |
数学 | 458篇 |
物理学 | 1214篇 |
出版年
2024年 | 10篇 |
2023年 | 62篇 |
2022年 | 128篇 |
2021年 | 116篇 |
2020年 | 146篇 |
2019年 | 146篇 |
2018年 | 137篇 |
2017年 | 111篇 |
2016年 | 154篇 |
2015年 | 171篇 |
2014年 | 181篇 |
2013年 | 248篇 |
2012年 | 300篇 |
2011年 | 334篇 |
2010年 | 225篇 |
2009年 | 203篇 |
2008年 | 279篇 |
2007年 | 191篇 |
2006年 | 188篇 |
2005年 | 186篇 |
2004年 | 156篇 |
2003年 | 152篇 |
2002年 | 186篇 |
2001年 | 153篇 |
2000年 | 106篇 |
1999年 | 85篇 |
1998年 | 72篇 |
1997年 | 44篇 |
1996年 | 90篇 |
1995年 | 64篇 |
1994年 | 46篇 |
1993年 | 29篇 |
1992年 | 29篇 |
1991年 | 27篇 |
1990年 | 28篇 |
1989年 | 16篇 |
1988年 | 14篇 |
1987年 | 15篇 |
1986年 | 9篇 |
1985年 | 15篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1974年 | 1篇 |
1957年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有4878条查询结果,搜索用时 15 毫秒
991.
A proper k-edge coloring of a graph G is an assignment of one of k colors to each edge of G such that there are no two edges with the same color incident to a common vertex. Let f(v) denote the sum of colors of the edges incident to v. A k-neighbor sum distinguishing edge coloring of G is a proper k-edge coloring of G such that for each edge uv∈E(G), f(u)≠f(v). By χ'_∑(G), we denote the smallest value k in such a coloring of G. Let mad(G) denote the maximum average degree of a graph G. In this paper, we prove that every normal graph with mad(G) ■ and Δ(G) ≥ 8 admits a(Δ(G) + 2)-neighbor sum distinguishing edge coloring. Our approach is based on the Combinatorial Nullstellensatz and discharging method. 相似文献
992.
Miao‐Miao Li Qin Xiong Bao‐Le Qu Yu‐Qing Xiao Yu Lan Liang‐Qiu Lu Wen‐Jing Xiao 《Angewandte Chemie (International ed. in English)》2020,59(40):17429-17434
Vinylcyclopropanes (VCPs) are commonly used in transition‐metal‐catalyzed cycloadditions, and the utilization of their recently realized reactivities to construct new cyclic architectures is of great significance in modern synthetic chemistry. Herein, a palladium‐catalyzed, visible‐light‐driven, asymmetric [5+2] cycloaddition of VCPs with α‐diazoketones is accomplished by switching the reactivity of the Pd‐containing dipolar intermediate from an all‐carbon 1,3‐dipole to an oxo‐1,5‐dipole. Enantioenriched seven‐membered lactones were produced with good reaction efficiencies and selectivities (23 examples, 52–92 % yields with up to 99:1 er and 12.5:1 dr). In addition, computational investigations were performed to rationalize the observed high chemo‐ and periselectivities. 相似文献
993.
Teng Bao Jie Jin Mekdimu Mezemir Damtie Ke Wu Zhi Ming Yu Lie Wang Jun Chen Yong Zhang Ray L. Frost 《Journal of Saudi Chemical Society》2019,23(7):864-878
A zero-valent iron/rectorite nanocomposite (NZVI/rectorite) was developed as a heterogeneous H2O2 catalyst for P-chlorophenol degradation. The physicochemical properties of NZVI/rectorite were characterized by various techniques including X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive spectrometry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller analysis. Results showed that NZVI sphere nanoparticles were successfully loaded on the rectorite surface with less aggregation and good dispersion. Moreover, compared with acid-leached rectorite (30.91 m2/g), the NZVI/rectorite appeared to have larger surface area (50.75 m2/g). In addition, the effects of pH, reaction time, initial P-chlorophenol concentration, catalyst amount, and H2O2 dosage on the P-chlorophenol degradation were systematically investigated. Results showed that NZVI/rectorite presents better properties for the degradation and mineralization of P-chlorophenol compared with pristine NZVI due to the large surface area, low aggregation, and good dispersion of the former. The degradation mechanisms of P-chlorophenol by NZVI/rectorite were adsorption and reduction coupled with a Fenton-like reaction. Four successive runs of the stability and regeneration study also showed that the NZVI/rectorite were unchanged even after 100% of P-chlorophenol degradation ratio. This study has extended the application of NZVI/rectorite as environment function material for the removal of P-chlorophenol from the environment. 相似文献
994.
Houfu Lv Tianfu Liu Xiaomin Zhang Yuefeng Song Hiroaki Matsumoto Na Ta Chaobin Zeng Guoxiong Wang Xinhe Bao 《Angewandte Chemie (International ed. in English)》2020,59(37):15968-15973
In situ exsolution of metal nanoparticles in perovskite under reducing atmosphere is employed to generate a highly active metal–oxide interface for CO2 electrolysis in a solid oxide electrolysis cell. Atomic‐scale insight is provided into the exsolution of CoFe alloy nanoparticles in La0.4Sr0.6Co0.2Fe0.7Mo0.1O3?δ (LSCFM) by in situ scanning transmission electron microscopy (STEM) with energy‐dispersive X‐ray spectroscopy and DFT calculations. The doped Mo atoms occupy B sites of LSCFM, which increases the segregation energy of Co and Fe ions at B sites and improves the structural stability of LSCFM under a reducing atmosphere. In situ STEM measurements visualized sequential exsolution of Co and Fe ions, formation of CoFe alloy nanoparticles, and reversible exsolution and dissolution of CoFe alloy nanoparticles in LSCFM. The metal–oxide interface improves CO2 adsorption and activation, showing a higher CO2 electrolysis performance than the LSCFM counterparts. 相似文献
995.
Yang Shujie Shi Bao Gai Mingjiu 《Annals of Differential Equations》2005,21(3):503-506
Some oscillation and non-oscillation criteria for second-order quasi-linear difference equations are given. The results in Zhang and Zhou [4] are improved. 相似文献
996.
997.
998.
本文讨论了广义Z4线性Calderbank-McGuire码的对偶的迹表示及2-adic表示, 同时给出了其最小Lee权估计. 相似文献
999.
本文介绍了一种大画幅纹影成像技本,应用该技术,显示了高超音速流场中锥体边界层转捩。将所得到的纹影图象在显微密度计图象处理系统中进行处理与测量,并结合纹影法原理进行了分析计算,得到了边界层诸截面相对密度变化曲线以及边界层转捩位置等实验结果,该结果与有关气动理论和实践结果进行了比较。 相似文献
1000.