Generation of DQPSK format and its performance against polarization mode dispersion

We propose a novel transmitter and receiver for differential quadrature phase-shift keying （DQPSK） format. The impact of the first-order polarization mode dispersion （PMD） on systems using DQPSK with 100- Gb/s non-return-to-zero （NRZ） or return-to-zero （RZ） format is investigated. Through computing the eye openings of DQPSK formats under different PMD conditions, it is found that NRZ DQPSK, as compared with RZ DQPSK, incurs smaller eye opening due to PMD. Carrier-suppressed return-to-zero （CSRZ） DQPSK format has better tolerance than RZ DQPSK format to PMD for a given bit rate.     

Determination of Lignin,Ash and Protein in Corn Fiber by Near Infrared Spectroscopy

研究一种基于近红外(NIR)光谱法的玉米皮渣组分中木质素、灰分及蛋白质的快速检测分析,采用偏最小二乘法(PLS)建立数学模型,比较了不同预处理方法对建立的木质素、灰分及蛋白质模型的影响,建立的校正模型所构建的木质素、灰分及蛋白质模型的定标集相关系数(Rc)分别为0.922887、0.902713和0.973160,验证集相关系数(Rv)分别为0.944109、0.916882和0.900532,定标集标准偏差(SEE)分别为0.304609、0.109288和0.697201,验证集标准偏差(SEP)分别为0.307115、0.0800459和0.96164.所建模型有较高的拟合和预测能力,可用于木质素、灰分及蛋白质含量的快速检测分析.     

离子液体[BDMIM]PF6修饰碳糊电极的制备及其电化学性能

以离子液体1,2-二甲基-3-丁基咪唑六氟磷酸盐（[BDMIM]PF6）代替传统液态石蜡为粘合剂与石墨粉相混合,制备了一种新型的离子液体修饰碳糊电极（IL/CPE）。采用扫描电子显微镜分别对其表面形貌和石蜡碳糊电极（CPE）表面形貌进行了表征。以亚铁氰化钾为电化学探针对IL/CPE的电化学行为进行了研究,并与CPE进行了比较。结果表明,[BDMIM]PF6由于具有较高的导电性,使IL/CPE比CPE具有更高的导电效率,铁氰化钾在电极上的可逆性变好,ΔEP值变小,峰电流响应增加10倍,电极过程由CPE上的吸附控制变为扩散控制,根据计时库仑法求解出铁氰化钾的扩散系数为5.52×10^-6cm2/s（25℃）。电化学交流阻抗图亦表明与不导电的液态石蜡油相比,离子液体的存在加快了电子传递。     

巧用Excel处理大学物理实验数据

以霍尔元件测量磁场为例,介绍了用Excel软件对实验数据进行分析处理的一般过程.结果表明利用Excel处理物理实验数据能大大减轻学生繁杂的数据计算及处理步骤,有效避免了手工处理所带来的误差,并且能满足一般的实验作图要求,适宜在大学物理实验数据处理方面推广应用.     

圆形射流湍流场的大涡模拟研究

使用发展的大涡模拟并行程序,数值模拟了圆形射流湍流场,与实验值进行详细比较,对大涡模拟程序进行检验,并分析网格尺度对计算结果的影响。结果表明,大涡模拟计算的平均速度场和雷诺应力场与实验值符合得非常好,验证了该大涡模拟计算程序的可靠性和精确度。同时发现一阶统计矩受网格尺度影响不大,二阶及高阶矩与网格尺度有较大的关系,因此使用大涡模拟方法计算湍流及湍流燃烧问题应对网格依赖性进行必要分析,至少保证二阶统计矩具有较好的精度。     

Dark pulse generation in a dispersion-managed fiber laser

We report an experimental observation of dark pulse generation in a dispersion-managed erbium-doped fiber laser with net anomalous cavity group-velocity dispersion. It is found that apart from the bright soliton pulses, dark pulses with spectral sidebands could be obtained in the laser under appropriate operating conditions. The generation of dark pulses may be attributed to soliton shaping in the cavity.     

Filter-free ultra-wideband doublet pulses generation based on wavelength conversion and fiber dispersion effect

Filter-free ultra-wideband (UWB) doublet pulse generation is experimentally demonstrated in the optical domain based on cross-gain modulation (XGM) in semiconductor optical amplifier (SOA) and UWB-over-fiber technology is implemented by exploiting dispersion-induced pulse broadening effect in single-mode fiber (SMF). In our proposed system, the SOA generates a polarity-inversed Gaussian pulse train with respect to the injected one through the XGM. After a piece of SMF, the bandwidth of polarity-reversed Gaussian pulse broadens due to the induced dispersion. After the combination of the two light waves with a suitable time delay between them, UWB pulse is obtained. The key parameters for UWB pulse, including central frequency, 10 dB bandwidth, as well as fractional bandwidth are experimentally obtained with 8 GHz, 9.9 GHz and 123% respectively. The generated UWB doublet pulse conforms with the UWB definition of Federal Communications Commission (FCC).     

Temperature dependence of the Raman spectra of Bi2Te3 and Bi0.5Sb1.5Te3 thermoelectric films

The temperature dependence of the Raman spectra of Bi₂Te₃ and Bi_0.5Sb_1.5Te₃ thermoelectric films was investigated. The temperature coefficients of the E_g(2) peak positions were determined as –0.0137 cm^–1/°C and –0.0156 cm^–1/°C, respectively. The thermal expansion of the crystal caused a linear shift of the Raman peak induced by the temperature change. Based on the linear relation, a reliable and noninvasive micro‐Raman scattering method was shown to measure the thermal conductivity of the thermoelectric films. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Unique geometric and electronic structure of CO adsorbed on Ge(100): A DFT study

CO adsorption on the Ge(100) surface has been investigated using a slab model with density functional theory implemented in SIESTA. CO was found to be exclusively adsorbed on the asymmetric dimer with C attaching on the lower Ge dimer atom. The adsorption process is barrierless. The calculated adsorption energy and vibration frequencies are comparable to previous experimental results. The crystal orbital Hamilton analysis showed that the bonding between Ge and CO is mainly attributable to the Ge 4p_z orbital overlapping with C 2 s, or with CO molecular orbitals 3σ and 4σ. The repulsive energy between adsorbed CO molecules is less than 1 kcal/mol. The diffusion barrier of CO on the Ge(100) surface is about 14 kcal/mol.     

ICP-MS测定血中镁、铜、铅浓度时的基体效应单一内标校正方法研究

ICP-MS测定模拟全血基体中不同质量段的Mg, Cu, Pb元素,考察基体效应对测定值的影响,分别采用传统内标法和单一内标CAIS方法(common analyte internal standardization)对其进行校正和比较。结果表明CAIS方法适用于不同浓度血液基体中多种元素的同时校正,且效果良好,其相对平均误差仅为3.05%,明显低于传统内标法的12.39%和校正前的23.91%;CAIS方法不受内标元素和被测元素质量数差异、测定强度差异以及电极电位差异的限制;使用全血和血清标准物质对CAIS方法可靠性进行验证,测定值全部落在标准值范围内。