Sensitive monitoring of humic acid in various aquatic environments with acidic cerium chemiluminescence detection.

In this research, a simple, sensitive chemiluminescence (CL) method for the determination of humic acid (HA) in water samples was first developed based on the redox reaction between humic acid and cerium(IV) in the acidic condition. Different with the former redox CL reaction which occurred in alkaline solution, no enhancers were needed and neither precipitation nor a second contamination would occur in the present CL system. Comparing with other spectrometric methods, we find that the proposed analysis system had better applicability and accuracy. Under the optimal experiment conditions, the CL peak height was linear with the concentration of HA in the range of 0.03 to 10.0 microg mL(-1). The detection limit is 0.01 microg mL(-1) (S/N = 3), and the relative standard deviation was 2.3% for 0.5 microg mL(-1) HA solution with eleven repeated measurements. The present CL method was successfully applied to the determination of HA in tap water, spring water and river water samples with good recovery from 90.0 to 110.0%. A possible CL mechanism was proposed based on the results of UV and fluorescence spectrometry and the CL spectrum of HA. It was speculated that the semi-quinone radicals in the excited state were the emitters.     

CCD狭缝摄象

在过去的几十年中,各靶场已广泛应用狭缝摄影对种种飞行弹丸的多项重要技术参数进行测试,它在许多测试项目中应用的有效性、广泛性和经济性已被人们所肯定。据报道,在国外的一些靶场所进行的发射试验中,狭缝摄影机曾占全部测试设备中所使用的摄影仪器的百分之九十,这是因为狭缝摄影有其独特的、其它方法不可比拟的优点。     

逆序数的应用

本文通过“1 4-1 5”智力玩具和最优戴断切割问题两个实例 ,讨论了逆序数在解决实际问题中的应用     

Kähler hyperbolicity and the Euler number of a compact manifold with geodesic flow of Anosov type

 Let M be a 2m-dimensional compact Riemannian manifold with Anosov geodesic flow. We prove that every closed bounded k form, k≥2, on the universal covering of M is d(bounded). Further, if M is homotopy equivalent to a compact K?hler manifold, then its Euler number χ(M) satisfies (−1) ^m χ(M)>0. Received: 25 September 2001 / Published Online: 16 October 2002     

17N+197Au反应中碎片与中子的符合测量

在3?3?.4MeV/u ¹⁷N束轰击¹⁹⁷Au靶产生的反应中,利用放置于不同角度组合的17个中子探测器(4°—83°)和14个半导体望远镜(2.3°—9.0°)对反应产物碎片与中子进行了符合测量.经对所得实验角分布积分得到Z=3—6元素的同位素产额分布.在参加者-旁观者模型框架下,采用¹⁷N原子核内部的不同密度分布计算了同位素产额分布并与实验数据做比较.     

探讨Abel积分零点的一个定理

本文研究了具有中心环域的可积多项式系统,探讨此系统在用多项式进行微扰的情况下,其所对应的Abel积分的零点个数的计算方法,给出了一个较为实用的定理,并举出了若干个应用的例子．     

带W权Drazin逆的一种新算法

利用矩阵A的带W权Drazin逆的一个性质特征,对任意的矩阵A∈Cm×n,W∈Cn×m,建立了带W权的Drazin逆Ad,w的一种新的表示式,给出了具体的算法步骤,并且在文末给出了算例.     

河南省城市居民消费结构比较研究

本文主要应用聚类分析方法 ,对河南省 17个地市级城市居民的消费结构进行了比较统计分析 ,从而得到了各城市居民消费结构的一些特点和规律 ,并进一步探讨了其消费结构、可支配收入与总消费支出之间的关系     

Kinetic behaviour of aluminum naphthenate/benzene system in process of gelation and degradation

The kinetic behaviour of aluminum naphthenate/benzene system in the process of gelation and degradation was systematically studied. The results obtained from the kinetic experiments indicated that the gelation stage was in accordance with a kinetic model of an auto-catalytic first-order reaction, and the degradation stage was a simple first-order reaction. The rate constants in these two stages at various temperaturs were measured. And the determined apparent activation energies for the gelation stage and for the degradation stage are 27.5±2.0 and 37.7±2.3 kJ/mol, respectively.