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991.
The vapor‐phase reaction of citronellal (CTN) at 220 °C and atmospheric pressure has been studied using mesoporous molecular sieves and zeolites in a fixed‐bed reactor. The primary products included isopulegol (IPG), menthone, and pulegol with subsequent reactions to form cyclic hydrocarbons. The CTN conversion and the product selectivity depend on the acidity and the textural property of catalysts. Lewis and/or Brönsted acid sites are essential for catalyzing this reaction. An increase of SiO2/Al2O3 mol ratio diminishes the acid amount of all catalysts and enhances both the surface area and the structural order of MCM‐41. The catalytic activity follows the order of MCM‐41 > HZSM‐5 > Hβ > USY, in accordance with the relative total acid amount except that of MCM‐41. Despite its low acidity, Si‐MCM‐41 exhibits the best catalytic performance due to its uniform mesopores, large surface area and good stability; the CTN conversion and the IPG yield attain 91.9% and 58.6%, respectively, after at least 25 h time‐on‐stream. 相似文献
992.
合成了新型手性Salen配体(H3L)及新型手性Salen双核锌配合物(主体).通过研究主体对咪唑类客体及氨基酸酯类客体的分子识别行为,测定了这些配位反应的缔合常数.主体对咪唑类客体分子识别的缔合常数顺序为:K(Im) >K(2-MeIm) >K(2-Et-4-MeIm).主体对氨基酸酯类客体分子识别的缔合常数顺序为:K(LeuOCH3) >K(ValOCH3) >K(AlaOCH3) >K(SerOCH3),配位数均为2.主体与D、 L型氨基酸酯分子识别反应在不同温度下的缔合常数结果表明,随着温度的升高,对映选择性下降.实验发现反应体系中存在焓熵补偿关系. CD光谱的研究结果也反映了主体对不同客体识别能力的差异. 相似文献
993.
鹿角短指软珊瑚Sinularia Cervicornis Tix-Dur 中的一个新糖甙-Cervicoside 总被引:1,自引:0,他引:1
珊瑚属腔肠动物门 ( Clelenterata) ,海鸡冠目 ( Alcyonacea) ,是一种热带与亚热带海洋中广泛分布Scheme 1 Structure of cervicoside(1 )的低等海洋生物 .软珊瑚的次生代谢物中含有萜类和甾体类等各类生理活性物质[1~ 5] .我们在对鹿角短指软珊瑚的次生代谢产物研究中 ,分离到一个新三糖甙 ,命名为 Cervicoside( 1 ) ,结构见 Scheme 1 .该化合物具有较强的体外抗癌活性 .1 实验部分1 .1 样品 鹿角短指软珊瑚采自海南岛三亚海域 .样品储藏于中山大学化学与化学工程学院天然有机化学研究室 ,编号为 98- SY- 3.种属由中国科学院南海… 相似文献
994.
After a series of optimization for the reaction conditions (reagents, reaction temperature, etc.), treatment of the sulfonates 4, 8, 13 and 15 with 8% NaOH (room temperature, 24 h) via a semipinacol rearrangement afforded the corresponding C-nor compounds 5, 9, 12 and 16, as the major of a pair of epimer at C-16, to an excellent extent, in 95%, 92%, 100% and 90% yield, respectively. The 12,13-seco compounds 21 and 22 (23) were obtained in 20% and 60% yield, respectively, by treating 5 with Br(2)-glacial HOAc (room temperature, 24 h). Treatment of the C-nor compounds 5 or 6, 16 or 17, and 28 from 10 with SOCl(2)-anhydrous benzene (room temperature, overnight) afforded the 12,13-seco compounds 24, 26 and 30 in 70% or 100%, 40% and 66% yield, respectively. When treatment of the C-nor compound 29 from 9 under same conditions gave the 12,13-seco products 30, 31 and 32 in 33%, 26% and 20% yield. When treating 21 or 24, and 26 with 5% KOH in EtOH afforded the 12,13-seco compounds 25 and 27 quantitatively, respectively. The compound 31 converted to 30 quantitatively by treatment with Na(2)CO(3) in MeOH. All of the new compounds were isolated and fully characterized. 相似文献
995.
996.
A uniform poly[2-methoxy-5-(2′-ethylhexyloxy)-p-phenylenevinylene] (MEH-PPV)/titania hybrid film was successfully prepared by an in situ sol-gel reaction of titanium isopropoxide (TIP) in the presence of MEH-PPV/2-chlorophenol solution. The annealing treatment increased the conversion of TIP to titania as determined from evidence of the formation of Ti-O-Ti bonds in the Fourier transform infrared (FTIR) spectrum. Scanning electronic microscope (SEM) photographs showed that the morphology and distribution of titania in the hybrid film were strongly related to the amount of water in the in situ sol-gel reaction. The thermal stability of MEH-PPV/titania hybrids was enhanced by the annealing treatment. Small angle X-ray scattering (SAXS) and X-ray diffraction (XRD) analyses indicated that annealing treatment promoted the ordered aggregation of the MEH-PPV chains and crystallization of titania to a certain extent. The blue shift in Ultraviolet-visible (UV-vis) absorption of pure MEH-PPV after annealing was ascribed to the small extent of decomposition and coil conformation which occurred at high temperature. A more-obvious blue shift for the hybrids was observed, which resulted from irregular aggregation and coil conformation of the MEH-PPV chains induced by heterogeneous point, TIP (titania). The red shift in the photoluminescent (PL) emission for pure MEH-PPV resulted from a certain extent of ordered aggregation after annealing. However, only a slight red shift in the PL emission peak for the hybrids was found due to the hindrance of ordered aggregation of MEH-PPV chains in the presence of TIP (titania). 相似文献
997.
Cerium-doped terbium aluminum garnet phosphors, Tb3Al5O12:Ce3+ (TAG:Ce3+), were prepared with different methods: co-precipitation (CP), half dry-half wet (HDHW), sol-combustion (SC) and Pechini method plus conventional solid state reaction (SS) method. Comparative study on the phase-formation, particle size, morphologies and luminescent characteristics of the phosphors synthesized with different methods was carried out by means of XRD, FE-SEM and photoluminescence (PL) analysis and SC method was confirmed by the comparison of the results to be an easy and an effective process for preparing efficient and nano-sized Tb3Al5O12:Ce3+ phosphors. Various factors influencing particle size, morphology and PL of the phosphors, such as precursor preparation, reaction temperature and heating time, were also investigated. Light-emitting diodes (LEDs) were fabricated with each phosphor and a ∼460 nm emitting InGaN chip. The LEDs from SS, HDHW and CP exhibit strong white emission while those from SC and Pechini emit yellow, revealing that the emission characteristics of LEDs are influenced not only by the morphology and the particle size of the phosphors, but also by the preparing process of the phosphors. 相似文献
998.
Three divalent transiton‐metal complexes of 2,3‐pyridinedicarboxylate (2,3‐pda2), [Mn(2,3‐pda)‐(H2O)3]∞ ( 7 ), [Ni(2,3‐pda)(H2O)3]∞ ( 8 ), and [Cd2(2,3‐pda)2(H2O)]∞ ( 9 ) have been hydrothermally synthesized and structurally characterized. X‐ray diffraction analyses reveal that compounds 7 and 8 are zigzag‐ and linear‐type one‐dimension (1D) coordination polymers, respectively, whereas compound 9 is a three‐dimension (3D) coordination polymer. A simple comparison of the coordination geometries with the available neutral analogues {Mx(2,3‐pda)x(H2O)y}∞ containing one or two divalent transition‐metal atoms and equal ligands in the presence or absence of coordinated water molecules is also presented. 相似文献
999.
Haes AJ Zhao J Zou S Own CS Marks LD Schatz GC Van Duyne RP 《The journal of physical chemistry. B》2005,109(22):11158-11162
A novel method to produce solution-phase triangular silver nanoparticles is presented. Ag nanoparticles are prepared by nanosphere lithography and are subsequently released into solution. The resulting nanoparticles are asymmetrically functionalized to produce either single isolated nanoparticles or dimer pairs. The structural and optical properties of Ag nanoparticles have been characterized. Mie theory and the Discrete Dipole Approximation method (DDA) have been used to model and interpret the optical properties of the released Ag nanoparticles. 相似文献
1000.
Tian-Fu LiuHua-Kuan Lin Shou-Rong ZhuZhong-Ming Wang Hong-gen WangHong-Wei Sun Xue-Bing LengYun-Ti Chen 《Journal of Molecular Structure》2002,605(1):117-122
The Mn(II) and Zn(II) complexes of N,N′-diisopropyl-1,10-phenanthroline-2,9-dimethanamine have been synthesised, and the structure of the two complexes have been studied by X-ray crystallography. 相似文献