空气中电晕放电高能电子密度沿反应器分布的光谱研究(英)

利用目前在等离子体特性诊断方面较为先进实用的发射光谱法,在常温常压下测量了正脉冲电晕放电空气中的Ｎ２（Ｃ３ Πｕ →Ｂ３ Πｇ） 发射光谱相对强度沿线－ 筒式反应器的径向分布,由此得到了正脉冲电晕放电等离子体中高能电子（ ≥１１ ．０３ｅＶ） 的电子密度沿线－ 筒式反应器的径向分布．随径向距离增大高能电子密度呈非线性递减,对于不同放电电压这种递减规律相同．     

冠醚硒菁染料的合成

合成了对称和非对称两个新的冠醚硒菁染料2,2'-二乙基-45,4'5'-双并-(15-冠-5)硒碳菁碘化季铵盐和2,2'-二乙基-4,5-并-(15-冠-5)硒碳菁碘化季铵盐以用三种新的中间体2,2'-二硝基-4,5,4',5'-双并-(15-冠-5)二苯基二硒化物, 2-甲基-5,6-并-(15-冠-5)苯并硒唑和2-甲基-3-乙基-5,6-并-(15-冠-5)苯并硒碘化季铵盐。报道了它们的红外、紫外、核磁共振、质谱数据。     

丙烷脱氢制丙烯研究进展

介绍了丙烷脱氢制丙烯的研究现状。包括丙烷催化脱氢的热力学、脱氢技术丙烷在膜反应器中脱氢及以氧气和二氧化碳作氧化剂的丙烷氧化脱氢。     

原子吸收法测定中药脑心通中微量和宏量元素的含量

采用原子吸收分光光度法测定了脑心通胶囊中钠、钾、钙、镁、铁、铬、锰、镍、镉、铜、锌11种元素的含量。结果表明，脑心通胶囊中含有较丰富的微量元素，为探讨中药脑心通中微量元素与治疗心脑血管疾病的关系提供了有用的数据。     

Ni,Pd／Al2O3对丙酮加氢一步合成甲基异丁基酮性能比较

研究了Ａｌ２Ｏ３负载Ｎｉ、Ｐｄ催化剂上丙酮加氢一步合成甲基异丁基酮的反应活性。考察了不同Ｎｉ含量和不同Ｐｄ含量对活性的影响。结果表明，在载体Ａｌ２Ｏ３中加入不同含量的ＳｉＯ２后，会改善载体的性能，Ｎｉ／Ａｌ２Ｏ３催化剂中添加稀土元素Ｌａ或Ｃｅ后可改善催化剂的稳定性。     

ABO_3，A_2BO_4型复合氧化物催化剂用于CO，CH_4，NH_3完全氧

本文探讨了ＣＯ，ＣＨ＿４和ＮＨ＿３在ＬａＮｉＯ＿３，Ｌａ＿２ＮｉＯ＿４和ＬａＳｒＮｉＯ＿４三个催化剂上的氧化行为，并得出结论：对于ＣＯ氧化，关键步骤在于ＣＯ在催化剂表面上的络合活化。Ｎｉ￣（３＋）含量越高，越利于ＣＯ的络合活化。对于氨氧化，催化反应遵循氧化－还原机理。Ｎｉ￣（３＋）是主要的活性离子，晶格氧是主要活性氧种。对于ＣＨ＿４氧化，催化机理较复杂，只是发现Ａ＿２ＢＯ＿４型氧化物（Ｌａ＿２ＮｉＯ＿４，ＬａＳｒＮｉＯ＿４）比ＡＢＯ＿３型氧化物（ＬａＮｉＯ＿３）较利于ＣＨ＿４的氧化。     

聚乙二醇对纳米二氧化钛性质和应用的影响

二氧化钛纳米晶光催化材料是近年来发展起来的新型环境友好材料,国内外研究者在利用二氧化钛纳米晶光催化降解苯酚、氯酚、甲醛等污染物方面做了大量的研究工作。研究表明TiO2的3种晶型,锐钛矿型、金红石型和板钛矿型中,有光催化作用的主要是锐钛型和金红石型,其晶型和晶粒大小     

Effect of Transition Metals (Cu, Co and Fe) on the Autothermal Reforming of Methane over Ni/Ce0.2Zr0.1Al0.7Oδ Catalyst

The transition metals (Cu, Co, and Fe) were applied to modify Ni/Ce0.2Zr0.1Al0.7Oδ catalyst.The effects of transition metals on the catalytic properties of Ni/Ce0.2Zr0.1Al0.7Oδ autothermal reforming of methane were investigated. The Ni-supported catalysts were characterized by XRD, TPR and XPS.Tests in autothermal reforming of methane to hydrogen showed that the addition of transition metals (Cu and Co) significantly increased the activity of catalyst under the conditions of lower reaction temperature,and Ni/Cu0.05Ce0.2Zr0.1Al0.65Oδ was found to have the highest conversion of CH4 among all catalysts in the operation temperatures ranging from 923 K to 1023 K. TPR, XRD and XPS measurements indicated that the cubic phases of CexZr1-xO2 solid solution were formed in the preparation process of catalysts.Strong interaction was found to exist between NiO and CexZr1-xO2 solid solution. The addition of Cu improved the dispersion of NiO, inhibited the formation of NiAl2O4, and thus significantly promoted the activity of the catalyst Ni/Cu0.05Ce0.2Zr0.1Al0.65Oδ.     

Sol-gel polycondensation of methyltrimethoxysilane in ethanol studied by <Superscript>29</Superscript>Si NMR spectroscopy using a two-step acid/base procedure

Sol-gel polymerization of methyltrimethoxysilane (MTMS) in ethanol using a two-step acid/base catalyzed procedure (B2) is followed by ²⁹Si NMR spectroscopy. Analysis of the structural evolution of the B2 system shows that esterification of monomeric and end silicon species is rate-limited while that of linear and cyclic species is able to reach pseudoequilibrium in the second basic step. Condensation reactivity is reduced with increasing network connectivity, however, to a much less degree under B2 conditions than MTMS polymerization under acidic conditions. Steric effects as well as many other factors are attributed to this trend. The concentration of cyclic and polycyclic species of the B2 system is nearly 3 times lower compared to the acid-catalyzed system. The empirical degree of condensation at the gel point is determined to be 0.88. The effects of cyclization and phase separation on MTMS gelation are discussed for both B2 and acid-catalyzed systems. Based on these results it is believed that MTMS-based gels form for B2 and not acid-catalyzed conditions due to reduced cyclization, rapid hydrolysis and condensation, effective use of functional groups, and effective contribution of branched and polycyclic species as crosslinking points to connect polymeric chains in the B2 system.     

SYNTHESIS OF AN AMPHIPHILIC PPESK-g-P(PEGMA) GRAFT COPOLYMER VIA ATRP AND ITS USE IN BLEND MODIFICATION OF PPESK MEMBRANES

Preparation of an amphiphilic graft copolymer having poly(phthalazinone ether sulfone ketone)(PPESK) as main chains was carried out by atom transfer radical polymerization(ATRP).The precursor,chloromethylated PPESK (CMPPESK),was prepared by using chioromethylether as chloromethylation agent.Then,poly(ethylene glycol) methyl ether methacrylate(PEGMA) was used as monomer to synthesize PPESK-g-P(PEGMA) by ATRP method under the catalysis of a cuprous chloride/2,2'-bipyridyl system.PPESK/PPESK-g-P(PEGMA) blen...