全文获取类型
收费全文 | 2560篇 |
免费 | 499篇 |
国内免费 | 280篇 |
专业分类
化学 | 1789篇 |
晶体学 | 29篇 |
力学 | 199篇 |
综合类 | 7篇 |
数学 | 240篇 |
物理学 | 1075篇 |
出版年
2024年 | 9篇 |
2023年 | 64篇 |
2022年 | 112篇 |
2021年 | 115篇 |
2020年 | 113篇 |
2019年 | 110篇 |
2018年 | 109篇 |
2017年 | 93篇 |
2016年 | 145篇 |
2015年 | 131篇 |
2014年 | 142篇 |
2013年 | 175篇 |
2012年 | 274篇 |
2011年 | 287篇 |
2010年 | 177篇 |
2009年 | 130篇 |
2008年 | 143篇 |
2007年 | 148篇 |
2006年 | 130篇 |
2005年 | 87篇 |
2004年 | 76篇 |
2003年 | 78篇 |
2002年 | 48篇 |
2001年 | 38篇 |
2000年 | 38篇 |
1999年 | 37篇 |
1998年 | 38篇 |
1997年 | 47篇 |
1996年 | 36篇 |
1995年 | 22篇 |
1994年 | 23篇 |
1993年 | 29篇 |
1992年 | 26篇 |
1991年 | 22篇 |
1990年 | 18篇 |
1989年 | 11篇 |
1988年 | 12篇 |
1987年 | 5篇 |
1986年 | 16篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1973年 | 1篇 |
1970年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有3339条查询结果,搜索用时 15 毫秒
31.
臧宏亮 叶沿林 李智焕 王建松 楼建玲 李奇特 葛愉成 杨晓菲 李晶 蒋伟 冯俊 刘强 杨彪 陈志强 刘洋 吴鸿毅 牛晨阳 李晨光 王春光 王翔 刘威 高见 余翰舟 马军兵 马朋 白真 杨彦云 金仕纶 卢飞 《中国物理C(英文版)》2018,42(7):074003-074003
An experiment for p(~(14)C,~(14)C~*→~(10)Be+α)p inelastic excitation and decay was performed in inverse kinematics at a beam energy of 25.3 Me V/u.A series of~(14)C excited states,including a new one at 18.3(1)Me V,were observed which decay to various states of the final nucleus of~(10)Be.A specially designed telescope system,installed around zero degrees,played an essential role in detecting the resonant states near theα-separation threshold.A state at 14.1(1)Me V is clearly identified,being consistent with the predicted band-head of the molecular rotational band characterized by theπ-bond linear chain configuration.Further clarification of the properties of this exotic state is suggested by using appropriate reaction tools. 相似文献
32.
Ag-mediated charge transfer from electron-doped SrTiO3 to molecules CO and NO has been studied through the first-principles calculations based on density functional theory (DFT). Evaluation of Fukui functions indicates that Ag atom on SrTiO3 (001) surface is presented as an active reduction and oxidation site. It shows that Ag prefers to mediate the charge transfer from electronically excited SrTiO3 to target species. It illustrates that electron initially transfers from electron-doped SrTiO3 to Ag, i.e., Ag is negatively charged. Interfacial charge transfer induces dipole moment and changes the surface work function. SrO-termination of SrTiO3 (001) surface has weak activity to CO and NO while CO and NO can be strongly adsorbed on the negatively charged Ag atom. Negatively charged Ag donates its charge to the molecules. Charge occupies the molecule π2p* orbital, which is responsible for the activation of the molecular bonds. Evidence that deposited metals on photocatalyst surface can efficiently separate the photogenerated electron-hole pairs has been addressed in this study. 相似文献
33.
从NEA GaAs光电阴极的激活光电流曲线发现,当系统真空度不很高时,在首次Cs激活阶段,表面掺杂浓度较低的阴极材料,其光电流产生需要的时间也较长.同时,随着系统真空度的提高,这种时间上的差异又变得不再明显.该现象表明,Cs原子在阴极表面的吸附效率同表面层掺杂浓度以及系统真空度之间有直接的联系.为定量分析这种关系,本文根据实验数据建立了Cs在阴极表面吸附效率的数学模型,利用该模型仿真的结果同实验现象非常符合.该研究对进一步开展变掺杂阴极结构设计和制备工艺研究具有重要的价值和意义.
关键词:
GaAs光电阴极
吸附效率
真空度
表面掺杂浓度 相似文献
34.
Hui Yao Peng-Bin Niu Chao Zhang Wei-Ping Xu Zhi-Jian Li Yi-Hang Nie 《The European Physical Journal B - Condensed Matter and Complex Systems》2018,91(3):57
We theoretically study the thermoelectric transport properties in a quantum dot system with two ferromagnetic leads, the spin-flip scattering and the external magnetic field. The results show that the spin polarization of the leads strongly influences thermoelectric coefficients of the device. For the parallel configuration the peak of figure of merit increases with the increase of polarization strength and non-collinear configuration trends to destroy the improvement of figure of merit induced by lead polarization. While the modulation of the spin-flip scattering on the figure of merit is effective only in the absence of external magnetic field or small magnetic field. In terms of improving the thermoelectric efficiency, the external magnetic field plays a more important role than spin-flip scattering. The thermoelectric efficiency can be significantly enhanced by the magnetic field for a given spin-flip scattering strength. 相似文献
35.
Chao‐Zhi Zhang Ting Li Yang Yuan Cheng‐Yue Gu Meng‐Xiao Niu Hui Cao 《Journal of Physical Organic Chemistry》2017,30(5)
Substituents significantly affect optical properties of organic compounds. In this study, a series of organic compounds were synthesized. Ultraviolet‐visible and cyclic voltammetry spectra were determined. The relationships between the number of π electron in an aryl ring and the redshift (and molecular orbital energy levels) were studied. To investigate mechanisms of the bromine substituent effects, theoretical calculations were carried out. Ultraviolet‐visible spectra of bromine‐containing compounds exhibit obvious redshifts (0.04‐0.17 eV) of the maximal absorption wavelengths and enhanced absorbance (11%‐57%) compared with corresponding reference compounds. The lowest unoccupied and highest occupied molecular orbital energy levels of compounds containing bromine substituents are 0.05 to 0.60 and 0.02 to 0.40 eV lower than that of corresponding reference compounds. On the whole, the redshifts and the reduced molecular orbital energy levels caused by bromine substituent decrease with the increase in the number of π electron in an aryl ring. The effects would be attributed to strong p‐π conjugation between p electron in the bromine substituent and π electrons in aryl rings. Therefore, this paper suggests a useful way for tuning optical absorption and molecular orbital energy levels of aryl compounds. 相似文献
36.
37.
The carbon nitride (CNx) coating with its novel properties will be excellent candidate for biomedical applications. CNx coatings were prepared on the surface of Ti–6Al–4V by ion-beam-assisted deposition (IBAD) with different NHn+ beam bombarding energies at low substrate temperature. The coatings were characterized by Scanning electron microscopy (SEM), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and Fourier-transform infrared (FTIR) spectroscopy. The result showed that the wear-resistance of CNx coatings was better at higher beam bombarding energy. The cell attachment tests also gave interesting results that CNx coatings exhibited low macrophage attachment and provide desirable surface for the normal cellular growth and morphology of the fibroblasts. Structural analysis showed that NHn+ beam bombardment at the energies of 300–400 eV could result in more nitrogen concentration and fraction of sp3CN bonds in the structure of CNx coatings, which may be responsible for the improvement in the wear-resistance and the cell attachment. 相似文献
38.
利用SHS等离子喷涂技术,将经过机械团聚法制备的Fe2O3-Al复合粉体送入等离子焰流,沉积出厚度约为400 μm的复合涂层.利用XRD,SEM 和TEM等检测手段对涂层的成分和组织进行了分析,测定了涂层的显微硬度、断裂韧性以及耐磨性.结果表明涂层为具有纳米结构的FeAl2O4-Al2O3-Fe纳米复合组织;涂层的显微硬度为HV100g870;断裂韧性是普通Al2O3涂层的2倍;无润滑磨损的耐磨性是普通Al2O3涂层的2.5倍. 相似文献
39.
40.
Monte Carlo simulation of the dynamic evolution ofbinary lamellar eutectic in directional solidification 总被引:1,自引:0,他引:1 下载免费PDF全文
The dynamic evolution of the lamellar eutectic of binary alloys in directional solidification is studied in detail using the Monte Carlo technique. The simulated results can be summarized into two aspects: ({1}) the lamellar spacing λ is found to be inversely proportional to the chemical potential difference Δμ, predicting a linear relationship between the kinetic supercooling ΔT_k and total supercooling at the solid/liquid (S/L) interface; (2) as the solidifying velocity R is low, the dynamic product λ^{2}R shows a considerable dependence on temperature gradient G_T in the liquid in front of the S/L interface, although this dependence becomes much weaker at a high R. 相似文献