界面态电荷对n沟6H-SiC MOSFET场效应迁移率的影响

针对界面态密度在禁带中的不均匀分布，分析了界面态电荷对n沟6H碳化硅MOSFET场效应迁移率的影响.分析结果显示，界面态电荷使n沟碳化硅器件的场效应迁移率明显降低.并给出了实验测定的场效应迁移率和反型层载流子迁移率的比值与界面态密度之间关系. 关键词： 碳化硅 界面态 反型层迁移率 场效应迁移率     

实现冷原子或冷分子囚禁的双层光阱列阵

提出了一种新颖的实现冷原子或冷分子囚禁的双层光阱方案,它由二元π相位板列阵和会聚透镜列阵所组成,用平面光波通过此光学系统时将在透镜焦平面两侧形成双层光阱.介绍了产生双层光阱的基本原理,分析了光阱光强分布、强度梯度等与光学系统参数间的关系,研究了双层光阱囚禁原子(或分子)的光学偶极势和自发散射速率(包括瑞利散射和拉曼散射)等.该方案不仅可用于多样品原子(或分子)的光学囚禁及全光型玻色一爱因斯坦凝聚(BEC),而且可用于制备新颖的双层2D光学晶格.     

准等熵压缩实验中金属铝的热力学耗散分析

为获取高压下材料的纯热力学压力-比容参考线和完全物态方程,减去应力-应变曲线中的其它信息,对准等熵压缩实验中由加载应变率引起的黏性耗散和热传导引起的热耗散做了分析讨论。基于反积分计算和流体动力学积分计算相结合的方法,根据激光加载(约108 s-1)和磁驱动准等熵压缩(约105 s-1)的实验数据,对材料声速、应力-应变曲线、温度和熵增等物理量进行计算,分析了不同应变率与该物理量的关系;还对热传导和SCG本构模型进行了计算,分析了热传导引起的温度变化对材料屈服强度、剪切模量和拉格朗日声速的影响。结果表明:激光加载实验中,应变率引起的温升差异约为180K,熵增差异约为250J/(kg·K),热传导导致温度下降40K;磁驱动准等熵压缩应变率较低,引起的熵增变化小于8J/(kg·K)。     

Temperature and metal composition dependence of lateral photovoltaic effect in Al-Alq3/SiO2/Si structures

A series of Al=-（Alq3）l-x granular films is prepared on Si wafer with native oxide layer using co-evaporation technique. Large lateral photovoltaic effect （LPE） is observed, with an optimal LPV sensitivity of 75 mV/mm in x=0.35 sample. The dependence of LPE on temperature and A1 composition is investigated, and the possible mechanism is discussed.     

Resolving overlapping peaks in ARXPS data: The effect of noise and fitting method

Peak-fitting of X-ray photoelectron spectroscopy (XPS) data can be very sensitive to noise when the difference on the binding energy among the peaks is smaller than the width of the peaks. This sensitivity depends on the fitting algorithm. Angle-resolved XPS (ARXPS) analysis offers the opportunity of employing the combined information contained in the data at the various angles to reduce the sensitivity to noise. The assumption of shared peak parameters (center and width) among the spectra for the different angles, and how it is introduced into the analysis, plays a basic role. Sequential fitting is the usual practice in ARXPS data peak-fitting. It consist on first estimating the center and width of the peaks from the data acquired at one of the angles, and then using those parameters as a starting approximation for fitting the data for each of the rest of the angles. An improvement of this method consists of averaging the centers and widths of the peaks obtained at the different angles, and then employing these values to assess the areas of the peaks for each angle. Another strategy for using the combined information is by assessing the peak parameters from the sum of the experimental data. The complete use of the combined information contained in the data-set is optimized by the simultaneous fitting method. It consists of the assessment of the center and width of the peaks by fitting the data at all the angles simultaneously. Computer-generated data was employed to compare the sensitivity with respect to noise between the sequential, averaged-sequential, sum, and simultaneous fitting methods. It is shown that the latter is significantly more robust and could provide reliable results even for noisy data and small peak separation. The fundamentals for the robustness of the simultaneous method are discussed, as well as the possibility of fitting many parameters at the same time. As an added feature of ARXPS, it was found that the estimation of the error intervals on the peak parameters is done remarkably more precisely by employing XPS data at various angles.     

Assembly of peptide–thiophene conjugates: the influence of peptide content and location

Biomolecule-directed self-assembly of π-conjugated oligomers has attracted great attention in the past decade. In this contribution, two conjugates composed of quaterthiophene and tetrapeptide (Gly-Val-Gly-Val) were synthesised, namely peptide–thiophene–peptide (PTP) and thiophene–peptide–thiophene (TPT), to investigate the influence of peptide content ratio and its location in the molecular structures on the nanostructures and properties of the assemblies. Both conjugates formed organogels consisting of left-handed twisted nanostructures; however, anti-parallel β-sheets were observed in PTP while parallel β-sheets were obtained for TPT, although in both cases oligothiophenes adopted an H-like stacking mode. Obvious solvent-induced supramolecular chirality inversion from the oligothiophene segment was observed for PTP while such phenomenon was not clear for TPT. PTP and TPT gels also showed different stabilities towards temperature increase, as evidenced by variable-temperature circular dichroism study. From the data, it is suggested that the rational design of the location and ratio of peptide plays a key role in constructing materials with determined properties based on peptide–thiophene conjugates.     

Biodegradable aromatic copolyesters made from bicyclic acetalized galactaric acid

Random poly(hexamethylene terephthalate‐co‐galactarate)s and poly(dodecamethylene terephthalate‐co‐galactarate)s copolyesters covering the whole range of compositions were obtained with weight‐average molecular weights of ～30,000–50,000 g mol^?1 by melt polycondensation. They were thermally stable above 300 °C, and displayed T_g in the +20 to ?20 °C range with values steadily decreasing with the content in galactarate units. All the copolyesters were semicrystalline with T_m between 50 and 150 °C and those made from dodecanediol were able to crystallize from the melt at a crystallization rate depending on composition. Copolyesters containing up to 50% of galactaric units retained the crystal structure of their respective polyterephthalate homopolyesters, whereas they adopted the structure of the respective polygalactarates when the content in Galx units reached 70%. Stress‐strain essays revealed decay in the mechanical parameters as the aromatic units were replaced by Galx. Incubation in aqueous buffer revealed that hydrolysis of the polyesters were largely enhanced by copolymerization and evidenced the capacity of the Galx unit for making aromatic polyesters susceptible to biodegradation. A detailed NMR analysis complemented by SEM observations indicated that hydrolysis took place by preferred splitting of galactarate ester bonds with releasing of alkanediol and Galx‐diacid. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

Multiple cation binding by bola-amphiphilic crown ethers: Assessment by fast atom bombardment mass spectrometry

Abstract

Bola-amphiphiles having two aza-18-crown-6 ether rings attached by a covalent spacer (O—O) and an analogous tris (macrocycle) (O—O—O) have been prepared and their cation complexation behavior has been assessed by fast atom bombardment and collisionally activated dissociation tandem mass spectrometry; the key finding is that two cations may simultaneously be complexed by a two- or three-crown system and that this complexation may also involve an anion.     

Low-Valent Titanium Induced Reductive Cyclization of 4,4-Dicyano-1,3-diaryl-1-butanone. Application to the Synthesis of 1-Amino-2-cyanocyclopentene Derivatives

Abstract: Titanium tetrachloride was reduced by zinc powder in THF to produce low-valent titanium which reacted with 4,4-dicyano-1,3-diaryl-1-buanone to give the derivatives of 1-amino-2-cyanocyclopentene.