Asymmetric Mesoporous Carbon Microparticles by 3D-Confined Self-Assembly of Block Copolymer/Homopolymer Blends and Selective Carbonization

Shape control of mesoporous carbon microparticles(MCMPs) is of critical importance; in particular, asymmetric shapes that can yield unique properties have attracted significant attention. However, the tailored synthesis of asymmetric MCMPs with ordered structures remains challenging. Herein, we report a facile route to prepare asymmetric MCMPs by dynamic neutral interface-guided 3D-confined self-assembly(3D-CSA) of block copolymer/homopolymer(BCP/hP) blends, followed by a self-templated selectiv...