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881.
Residual determination and risk assessment of buprofezin in plum (Prunus domestica) grown in open‐field conditions following the application of three different formulations
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Md. Humayun Kabir A.M. Abd El‐Aty Sung‐Woo Kim Han Sol Lee Md. Musfiqur Rahman Young‐Jun Lee Hyung Suk Chung Truong Lieu Jeong‐Heui Choi Ho‐Chul Shin Geon‐Jae Im Su Myeong Hong Jae‐Han Shim 《Biomedical chromatography : BMC》2016,30(11):1721-1727
This study was conducted to characterize the residual level and perform a risk assessment on buprofezin formulated as an emulsifiable concentrate, wettable powder, and suspension concentrate over various treatment schedules in plum (Prunus domestica). The samples were extracted with an AOAC quick, easy, cheap, effective, rugged, and safe, ‘QuEChERS’, method after major modifications. As intrinsic interferences were observed in blank plum samples following dispersive‐solid phase extraction (consisting of primary secondary amine and C18 sorbents), amino cartridges were used for solid‐phase extraction. Analysis was carried out using liquid chromatography with diode array detection and confirmed by liquid chromatography–tandem mass spectrometry. The method showed excellent linearity with determination coefficient (R2 = 1) and satisfactory recoveries (at two spiking levels, 0.5 and 2.5 mg/kg) between 90.98 and 94.74% with relative standard deviation (RSD) ≤8%. The limit of quantification (0.05 mg/kg) was considerably lower than the maximum residue limit (2 mg/kg) set by the Codex Alimentarius. Absolute residue levels for emulsifiable concentrates were highest, perhaps owing to the dilution rate and adjuvant. Notably, all formulation residues were lower than the maximum residue limit, and safety data proved that the fruits are safe for consumers. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
882.
Nonlinear Dynamics - This paper investigates the problem of stabilization for sampled-data neural-network-based systems under variable sampling. A novel Lyapunov–Krasovskii functional (LKF)... 相似文献
883.
Solution properties,unperturbed dimensions,and chain flexibility of poly(1‐adamantyl acrylate)
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Wei Lu Panchao Yin Masashi Osa Weiyu Wang Nam‐Goo Kang Kunlun Hong Jimmy W. Mays 《Journal of Polymer Science.Polymer Physics》2017,55(20):1526-1531
Poly(1‐adamantyl acrylate) (PAdA) exhibits much higher glass transition and degradation temperatures than other polyacrylates. However, the quantitative evaluation of the stiffness of this polymer chain has not been reported previously. In this study, the dilute solution properties and conformational characteristics of PAdA were evaluated using viscometry and scattering techniques. The unperturbed dimensions of this polymer were evaluated using the Burchard–Stockmayer–Fixman extrapolation and the touched‐bead wormlike chain model. The PAdA chain has a comparable persistence length, diameter per bead and characteristic ratio to poly(methyl methacrylate) and polystyrene. All these results indicate that PAdA is less flexible than common polyacrylates. In addition, the second virial coefficients (A2) of PAdA in different solvents obtained by static light scattering were compared. Among the solvents investigated, tetrahydrofuran is a moderate solvent. Radius of gyration of a polymer sample in the various solvents ranged from 16.8 to 30.3 nm. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1526–1531 相似文献
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885.
The design variable tolerance effects on the natural frequency variance of constrained multi-body systems in dynamic equilibrium are investigated in this study. Monte-Carlo simulation is often employed for such investigations, but it is known to have serious drawbacks. Excessive amount of computation time needs to be consumed since a large number of evaluations are usually required for the method. Furthermore, the solution accuracy cannot be always guaranteed in spite of the excessive amount of computation time. In order to overcome such drawbacks, a method employing eigenvalue sensitivity information is proposed to obtain the variance of natural frequency in this study. In order to verify the accuracy and the efficiency of the method, some numerical examples of multi-body systems in dynamic equilibrium are solved and the results are compared to those obtained by an analytical method and Monte-Carlo simulation. 相似文献
886.
887.
Yang?LiuEmail author Yanwei?Du Hong?Li Jinfeng?Wang 《Journal of Applied Mathematics and Computing》2015,47(1-2):103-117
In this article, an \(H^1\)-Galerkin mixed finite element (MFE) method for solving time fractional reaction–diffusion equation is presented. The optimal time convergence order \(O(\varDelta t^{2-\alpha })\) and the optimal spatial rate of convergence in \(H^1\) and \(L^2\)-norms for variable \(u\) and its gradient \(\sigma \) are derived. Moreover, some numerical results are shown to support our theoretical analysis. 相似文献
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890.
Hua Fang Weizhu Chen Bihong Hong Yufen Zhao Meijuan Fang 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2182-2193
This article describes the synthesis of α-hydroxyphosphonic acid esters using the Pudovik reaction. IR, 1H NMR, 13C NMR, 31P NMR, MS, and elemental analysis were employed to confirm their structures. X-ray structure analysis is reported for six compounds. The antibacterial activities of these compounds are also reported. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献