Two new kaempferol glycosides from the seeds of Camellia semiserrata Chi

Two new acetylated kaempferol glycosides were isolated from the seeds of Camellia semiserrata Chi,their structures were elucidated as kaempferol-3-O-[(3-O-acetyl)-α-L-rhamnopyranosyl(1→3)(4-O-acetyl)-α-L-rhamnopyranosyl(1→6)-β-D-glucopyranoside] (1) and kaempferol-3-O-[(2-O-acetyl)-α-L-rhamnopyranosyl(1→3)(4-O-acetyl)-α-L-rhamnopyranosyl(1→6)-β-D-gluco -pyranoside](2) by spectral experiments(including ESI-MS,1D- and 2D-NMR).     

Copper and amine free Sonogashira cross-coupling reaction catalyzed by efficient diphosphane-palladium catalyst

The commercially available diphosphane ligand MeO-BIPHEP was first investigated in the palladium-catalyzed Sonogashira reaction in the absence of copper and amine.The coupling of various aryl bromides and aryl chlorides with phenylacetylene gave moderate to excellent yields.     

STEREOREGULAR POLY(CYCLOHEXENE CARBONATE)S:UNIQUE CRYSTALLIZATION BEHAVIOR

<正>An example of crystalline CO_2-based polymer from the asymmetric alternating copolymerization of CO_2 and cyclohexene oxide is reported.Isotacticity of poly(cyclohexene carbonate)(PCHC)has the critical influence on the crystallinity,and only copolymers with a isotacticity of more than 90%are crystallizable.The stereoregular PCHC is a typical semi-crystalline thermoplastic,and possesses a high melting point(T_m)of 215-230℃and a decomposition temperature of ca.310℃.The spherulitic morphology of(R)-PCHC grows in a clockwise spiral from a center,and that of (S)-PCHC is a counterclockwise spiral,while the stereocomplex of(S)-PCHC/(R)-PCHC(1/1 mass ratio)presents lath-like dendritic crystal.The novel crystalline CO_2-based polycarbonate represents a rare example of optically active polymers with unique crystallization behavior.Our findings reflect the critical influence of stereoregularity on the crystallization for this kind of polymeric materials,and may lead to developments of thermal-resistance CO_2 copolymers for application in engineering thermoplastics.     

多级反射镜阵列MonteCarlo法误差合成与统计分析

本文研究的傅里叶变换红外光谱仪利用两面多级反射镜阵列替代时间调制型傅里叶变换光谱仪中的平面反射镜,以多级反射镜阵列对干涉图数据进行二维采样,从而减小系统的体积并增加系统的稳定性．由于多级反射镜阵列在其制作过程中加工精度的限制,各子反射镜之间会存在厚度偏差ε与角度偏差θ,这将影响到采样干涉图的光强分布与复原光谱的质量．本文将各子反射镜的￡与臼作为随机变量,利用MonteCarlo方法对傅里叶变换光谱仪中所有子反射镜的误差项进行合成,并通过对误差合成后光谱误差因子Q的统计分析来评价子反射镜的各误差项对复原光谱的影响．统计结果表明,Q的统计均值随着σε与σθ的增加表现为一单调递增的曲面,且与两个偏差之间具有准线性关系．依据对Q的统计分析,可以确定多级反射镜阵列各子反射镜ε与θ的容限．     

薄层色谱与红外光谱联用中新型固定相氟化钡的制备及应用

采用氟化钠与氯化钡反应制备了满足薄层色谱-红外光谱联用要求的氟化钡颗粒. 该方法虽然可以避免产生干扰红外光谱分析的碳酸钡杂质, 但氟化钡的产率偏低. 通过电感耦合等离子体(ICP)和X射线粉末衍射(XRD)分析证实, 氟化钠与氯化钡反应同时会生成氟氯化钡, 在沉淀洗涤过程中, 氟氯化钡的溶解会造成钡离子的流失和氟化钡产率的下降. 本文采用氟化钠溶液洗涤沉淀制备氟化钡, 可使氟氯化钡转化为氟化钡, 使氟化钡产率得到明显提高. 扫描电子显微镜和纳米粒度仪分析结果表明, 制备的氟化钡颗粒的粒径约为100 nm. 利用沉降挥发法制备了以氟化钡颗粒为固定相的薄层色谱板, 实验结果表明用该薄层色谱板可成功分离罗丹明B和孔雀石绿, 分离所得样品可被红外光谱检测且不受固定相的干扰.     

Coupled mixed-mode cohesive zone modeling of interfacial debonding in simply supported plated beams

The development of predictive models for plate end debonding failures in beams strengthened with thin soffit plates is a topic of great practical relevance. After the early stress-based formulations, fracture mechanics approaches have become increasingly established. More recently, the cohesive zone (CZ) model has been successfully adopted as a bridge between the stress- and fracture mechanics-based treatments. However, the few studies of this nature propose complex formulations which can only be implemented numerically. To date, the only available analytical solution based on CZ modeling for the prediction of interfacial stresses/debonding in plated beams is limited to the determination of interfacial shear stresses and thus neglects the mixed-mode effects generated by the presence of interfacial normal stresses at the plate end. This paper presents a new analytical formulation based on the CZ modeling approach for the prediction of plate end debonding in plated beams. A key enhancement with respect to the previous solution is the use of a coupled mixed-mode CZ model, which enables a full account of mixed-mode effects at the plate end. The model describes the evolution of the interface after the end of the elastic regime, and predicts the value of the load at incipient debonding. The achievement of a closed-form solution for this quite complex case entails the introduction of a crucial simplifying assumption, as well as the ad hoc modeling of an effective cohesive interfacial response. The paper presents the analytical theory and compares its predictions with numerical and experimental results.     

Electrochemical performance of sulfur composite cathode materials for rechargeable lithium batteries

The structure and characteristic of carbon materials have a direct influence on the electrochemical performance of sulfur-carbon composite electrode materials for lithium-sulfur battery.In this paper,sulfur composite has been synthesized by heating a mixture of elemental sulfur and activated carbon,which is characterized as high specific surface area and microporous structure.The composite,contained 70%sulfur,as cathode in a lithium cell based on organic liquid electrolyte was tested at room temperature....     

微型曲面发光二极管阵列照度一致性研究

为提高微型曲面发光二极管(LED)阵列在显示及照明使用方面的舒适度,针对微型曲面LED阵列照度分布的均匀性问题进行研究.采用TracePro光线追迹法分别计算了柱面显示阵列及球面照明阵列的照度分布.计算结果表明,曲面弯曲半径R和光源辐射参数m是影响柱面阵列照度分布的主要因素.通过合理排布阵列像素单元位置,可以增强器件显示均匀度,提高能量利用效率.10×10柱面LED阵列最大平坦化照度均匀度为90.5%.对球面环形阵列照度分布计算结果表明,单环形LED阵列照度均匀性与像素数量无关.影响球面多环LED阵列照度分布的参数主要包括环线分布系数K、环法线与第一环阵列光源法线夹角(?)_0及各环线像素光通量之比φ.以双环LED阵列为模型进行计算,获得最大平坦化照度均匀度为94.8%.调整球面多环阵列位置参数可实现不同照度分布模式.实验对比了微型LED像素单元夹角θ分别为13°,15°和17°时的照度分布,实验结果与理论计算较为一致.本文取得的理论与实验结果可以为微型曲面LED显示及多模式智能照明设计提供参考.     

MW级超临界二氧化碳向心涡轮设计及分析

本文以某MW级超临界二氧化碳(S-CO2)向心涡轮为研究对象,对S-CO2向心涡轮的设计体系展开进一步探索,并利用一维分析方法和三维数值模拟方法对其进行气动分析.文中先介绍了本课题组已经开发完成的针对向心涡轮喷嘴和转子叶轮的一维气动优化设计方法,然后补充向心涡轮进气蜗壳的设计方法,最后利用三维CFD方法对设计方案的进气...     

空间采样傅里叶变换光谱仪光谱反演研究

根据相似性准则,对采集到的干涉图像进行干涉图元的拆分,通过寻址定位,得到与离散光程差序列相匹配的采样干涉图序列。采用过零采样方式,对大单边干涉图序列与小双边干涉图序列利用不同的窗函数进行切趾。为了校正相位误差,结合所研究采样干涉图的特点,对频域光谱乘积校正和空域干涉图卷积校正进行了研究和改进,获得了比较理想的光谱线形,其中空域干涉图卷积校正后的光谱偏差仅为0.012088,具有最好的校正效果。