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941.
Styrene was polymerized in the presence of benzoyl peroxide (BPO) and 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) to yield polystyrene-TEMPO (PS-TEMPO) macroinitiator. The PS-TEMPO macroinitiator with different molecular weight was reacted with 4-vinyl pyridine (4-VP) to synthesize polystyrene-block-poly(4-vinyl pyridine) (PS-b-PVP), which was then quaternized with n-octyl iodide. Antibacterial activity of the quaternized copolymers was assessed against a gram negative bacterium (Pseudomonas aeruginosa) and a gram positive one (Staphylococcus aureus) by using the shake flask test method, and the results were compared with those of poly(styrene-random-4-vinyl pyridine) (P(ST-r--VP)). The quaternized copolymers inhibited greatly the growth of the bacteria, and PS-b-PVP was more active than P(ST-r-VP), which was ascribed to the fact that the content of quaternized 4-VP units on the surface of the particles of the former copolymer was higher than that corresponding to the latter one. 相似文献
942.
A new kind of polysiloxane containing N,N'-bis(diphenylsilyl)tetraphenylcyclodisilazane was prepared by anionicnon-equilibrium polymerization with a "seed solution" as initiator. The monomer, N,N'-bis(hydroxydiphenylsilyl)-tetraphenyl-cyclodisilazane (BHPTPC), was synthesized via the hydrolysis of N,N'-bis(chlorodiphenylsilyl)tetraphenyl-cyclodisilazane (BCPTPC). A new method for the preparation of BCPTPC is also reported here with high yield and simplermanipulation. The synthesized polysiloxane containing N,N'-bis(diphenylsilyl)tetraphenylcyclodisilazane was characterized by ~1H-NMR, ~(29)Si-NMR, gel permeation chromatography (GPC) and intrinsic viscosity. 相似文献
943.
A piezoelectric nucleic acid sensor was constructed ofr detection of tumor necrosis factor gene.Two methods were employed for immobilization of nucleic acid probe on gold electrode of piezoelectric crystal.The results show that polyethyleneimine adbesion and glutaraldehyde cross-linking method has higher sensitivity,stability and selectivity than protein A method.The solid-phase nucleic acid hybridization of oligo unclecotides and tumor necrosis factor target gene sequence were monitorde using this sensor.Tumor necrosis factor gene sequence(580bp) was detected by this nucleic acid sensor for the first time. 相似文献
944.
Squalamine (1) was synthesized stereoselectively in 14 steps and 19% overall yield from 3-keto-5-chenodeoxycholanate (2) by using a modified Sharpless asymmetric dihydroxylation as the key step. 相似文献
945.
946.
本文提出了用分析型HPLC仪器制备β-大马酮标准品的方法及用HPLC测定β-大马酮含量的方法。制备色谱柱为Zorbax SIL 9.4 mmφ×25cm,流动相为石油醚(30~60℃)/乙醚98.5/1.5。分析用色谱柱为Shim CLC SIL 6 mmφ×15cm(岛津全多孔硅胶柱),流动相为石油醚(60—90℃)/无水乙醇99.88/0.12,检测器为紫外可见分光光度检测器。波长253nm或302nm,标准曲线的线性范围0~1.4mg/ml。峰高或峰面积均可用于测定,回收率100.7%。 相似文献
947.
948.
报道标题化合物La(PMBP)_3(H_2O)_2,Hpmbp=C_(17)H_(14)N_2O_2的合成及晶体结构,晶体属于单斜晶系,空间群C2/c,晶体学数据:a=24.744(5),b=16.325(6),c=25.871(5),β=105.44(3)°,V=10073(2)3,M_r=1006,Z=8,D_x=1.328g/cm~(-3),μ=9.042cm~(-1),F(000)=4094。最终偏离因子R=0.049,R_w=0.059。分子中La(Ⅲ)与8个氧原子配位形成三角十二面体构型,La-O平均键长为2.496(2)。 相似文献
949.
950.
A Pt microelectrode modified with nickel(II) polytetramethyldibenzo[b,i]tetraaza[14]annulene was prepared by electropolymerization of nickel(II) tetramethyldibenzo[b,i]tetraaza[14]annulene monomers and applied to determine sulfur dioxide in vitriol plant wastewater. For determination of SO2 with this electrochemically modified Pt microelectrode, the linear range was from 9.6 x 10(-6) to 2.4 x 10(-4) mol L-1, the sensitivity was 1.8 x 10(-4) A L mol-1, the detection limit was calculated to be 4.8 x 10(-6) mol L-1 (S/N = 3), the response time was less than 20 s and the relative standard deviation was found to be 2.1% on analyzing 4.8 x 10(-5) mol L-1 SO2 solution repeatedly (n = 7). These results demonstrated good accuracy compared with those obtained by the conventional iodimetric method. 相似文献