全文获取类型
收费全文 | 22836篇 |
免费 | 2798篇 |
国内免费 | 2178篇 |
专业分类
化学 | 17628篇 |
晶体学 | 326篇 |
力学 | 1013篇 |
综合类 | 187篇 |
数学 | 2063篇 |
物理学 | 6595篇 |
出版年
2024年 | 26篇 |
2023年 | 274篇 |
2022年 | 475篇 |
2021年 | 582篇 |
2020年 | 669篇 |
2019年 | 710篇 |
2018年 | 524篇 |
2017年 | 530篇 |
2016年 | 889篇 |
2015年 | 849篇 |
2014年 | 1043篇 |
2013年 | 1540篇 |
2012年 | 1835篇 |
2011年 | 1980篇 |
2010年 | 1352篇 |
2009年 | 1228篇 |
2008年 | 1526篇 |
2007年 | 1337篇 |
2006年 | 1381篇 |
2005年 | 1279篇 |
2004年 | 1066篇 |
2003年 | 916篇 |
2002年 | 989篇 |
2001年 | 562篇 |
2000年 | 499篇 |
1999年 | 441篇 |
1998年 | 354篇 |
1997年 | 330篇 |
1996年 | 319篇 |
1995年 | 290篇 |
1994年 | 222篇 |
1993年 | 212篇 |
1992年 | 189篇 |
1991年 | 173篇 |
1990年 | 141篇 |
1989年 | 118篇 |
1988年 | 112篇 |
1987年 | 87篇 |
1986年 | 106篇 |
1985年 | 121篇 |
1984年 | 80篇 |
1983年 | 52篇 |
1982年 | 73篇 |
1981年 | 73篇 |
1980年 | 53篇 |
1979年 | 44篇 |
1978年 | 30篇 |
1977年 | 26篇 |
1976年 | 23篇 |
1973年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 140 毫秒
71.
In this paper, we exhibit a unified treatment of the mixed initial boundary value problem for second order (in time) parabolic linear differential equations in Banach spaces, whose boundary conditions are of a dynamical nature. Results regarding existence, uniqueness, continuous dependence (on initial data) and regularity of classical and strict solutions are established. Moreover, several examples are given as samples for possible applications.
72.
The rate coefficient for the reaction of CCl3 radicals with ozone has been measured at 303 ± 2 K. The CCl3 radicals were generated by the pulsed laser photolysis of carbon tetrachloride at 193 nm. The time profile of CCl3 concentration was monitored with a photoionization mass spectrometer. Addition of the O3–O2 mixture to this system caused a decay of the CCl3 concentration because of the reactions of CCl3 + O3 → products (5) and CCl3 + O2 → products (4). The decay of signals from the CCl3 radical was measured in the presence and absence of ozone. In the absence of ozone, the O3–O2 mixture was passed through a heated quartz tube to convert the ozone to molecular oxygen. Since the rate coefficient for the reaction of CCl3 + O2 could be determined separately, the absolute rate coefficient for reaction ( 5 ) was obtained from the competition among these reactions. The rate coefficient determined for reaction ( 5 ) was (8.6 ± 0.5) × 10?13 cm3 molecule?1 s?1 and was also found to be independent of the total pressure (253–880 Pa of N2). This result shows that the reaction of CCl3 with O3 cannot compete with its reaction with O2 in the ozone layer. © 2003 Wiley Periodicals, Inc. Int J Chem Kinet 35: 310–316, 2003 相似文献
73.
Frequency dependence of ac conductivity from 1 to 105 Hz and time series of the conductivity at 2 kHz were measured along c-axis of thulium nitrate crystal, Tm(NO3)36H2O at temperatures from 203.15 to 293.15 K. The meta-stability was observed. The frequency spectra of the conductivity were similar to those in disorder system. Aging effect was observed. Non-periodic instability (burst) was found. Non-linear dynamical property was characterized by 1/f noise spectrum, limit cycle in return map and dependence of correlation exponent on embedding dimension. 相似文献
74.
用密度泛函B3LYP/ 6 3 1G(d)方法 ,对质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)弱相互作用体系进行了全自由度能量梯度优化 ,得到了该系列团簇的稳定结构及其对应的体系能量 .通过对构型的分析得出了质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)的生长规律 .计算了中性丙酮分子团簇体系的质子亲合能并总结出其变化趋势 .分析讨论了质子化团簇的红外振动光谱 ,发现质子化团簇的振动光谱普遍较中性环型团簇的振动光谱复杂 ,最强的振动峰来源于质子在溶剂壳中两个氧原子之间的振动 ,而且随着团簇尺寸的增加羰基的伸缩振动峰的数目也随之增多 相似文献
75.
76.
Yong‐Jin Kim Jin‐Woong Kim Jung‐Eun Lee Jee‐Hyun Ryu Junoh Kim Ih‐Seop Chang Kyung‐Do Suh 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5627-5635
Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004 相似文献
77.
高阶线性微分方程的解及其解的导数的不动点 总被引:2,自引:0,他引:2
研究了复域齐次和非齐次线性微分方程的解及其解的导数的不动点与超级问题,得到了整函数系数的齐次和非齐次线性微分方程的解及其解的导数的不动点的两个结果,所得结果推广了一些相关结果. 相似文献
78.
Takashi Kishimoto 《Journal of Pure and Applied Algebra》2007,208(1):189-204
Let X?(T,D) be a compactification of an affine 3-fold X into a smooth projective 3-fold T such that the (reduced) boundary divisor D is SNC. In this paper, as an affine counterpart to the work due to S. Mori (cf. [S. Mori, Threefolds whose canonical bundles are not numerically effective, Ann. of Math. 116 (1982) 133-176]), we shall classify (K+D)-negative extremal rays on T. In particular, if such an extremal ray R=R+[C] intersects K non-negatively, we shall describe the log flips and divisorial contractions appearing explicitly. 相似文献
79.
Selective oxidation of an AlInAs layer was investigated for enhancement of magneto-optic effect in an optical isolator. Twelve times nonreciprocal phase shift enhancement was estimated from a measured AlInAs-oxide refractive index. 相似文献
80.
Endoscopic Observation of Tissue by Narrowband Illumination 总被引:6,自引:0,他引:6
Kazuhiro Gono Kenji Yamazaki Nobuyuki Doguchi Tetsuo Nonami Takashi Obi Masahiro Yamaguchi Nagaaki Ohyama Hirohisa Machida Yasushi Sano Shigeaki Yoshida Yasuo Hamamoto Takao Endo 《Optical Review》2003,10(4):211-215
We propose a new illumination method for a medical endoscope: narrow band imaging (NBI), in which the spectral bandwidth of the filtered light is narrowed. To confirm how the spectral specifications of the filtered light influence a reproduced image, an experiment was conducted observing the endoscopic images of the back mucosa of a human tongue. In addition, the effect of NBI on endoscopic images was investigated through preliminary clinical tests in colonoscopy and upper gastrointestinal endoscopy. It has been shown that NBI can enhance the capillary pattern and the crypt pattern on the mucosa. These patterns are useful features for diagnosing an early cancer. 相似文献