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261.
262.
唐瑞平 《高等学校化学学报》1991,12(4):532-536
通过测定平带电位,澄清了OH~-离子在CdSe电极上的吸附情况,发现在S、S~(2-)、OH~-溶液中S~(2-)离子优先吸附,结合旋转环盘电极测量,证明n-CdSe电极在多硫溶液界面上的电荷转移过程。 相似文献
263.
Effects of Processing Parameters on Microstructure and Properties of Nanoscale ZrC/ZrB2 Multilayered Coatings 下载免费PDF全文
ZrC/ZrB2 multilayered coatings with bilayer periods of 3.5-40nm are synthesized by rf magnetron sputtering. Analyses of x-ray diffraction, scanning electron microscopy and nanoindentation indicate that multilayered coatings possess much higher hardness and greater fracture resistance than monolithic ZrC and ZrB2 coatings. A maximum hardness (41.TCPa) and a critical fracture load (73.7mN) are observed in the multilayer with A = 32 nm deposited at the substrate bias -40 V. Higher residual stress built in the ZrC layer can be released by periodic insertion of ZrB2 into the ZrC layer. A clear multilayered structure with mixed ZrB2(001), ZrB2 (002) and ZrC (111) orientations should be responsible for the enhanced mechanical properties. 相似文献
264.
Optical properties and microstructure of Ag film on glass substrate with Cr intermediate layer were studied by using spectrophotometer and XRD. The spectra results showed that introducing Cr intermediate layer reduced the surface roughness and promoted the reflectivity of Ag film. The XRD analysis showed that the crystalline grains increased and the stress decreased. The adhesion was also improved by using the tape test method. 相似文献
265.
Films of polytetrafluoroethylene (PTFE) were exposed to sodium naphthalenide (Na/naphtha) etchant so as to defluorinate the surface for obtaining hydroxyl functionality. Surface-initiators were immobilized on the PTFE films by esterification of 4,4′-azobis(4-cyanopentanoic acid) (ACP) and the hydroxyl groups covalently linked to the surface. Grafting of polymer brushes on the PTFE films was carried out by the surface-initiated free radical polymerization. Homopolymers brushes of methyl methacrylate (MMA) were prepared by free radical polymerization from the azo-functionalized PTFE surface. The chemical composition and topography of the graft-functionalized PTFE surfaces were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance (ATR) FT-IR spectroscopy and atomic force microscopy (AFM). Water contact angles on PTFE films were reduced by surface grafting of MMA. 相似文献
266.
We consider in this paper the Lagrangian dual method for solving general integer programming. New properties of Lagrangian
duality are derived by a means of perturbation analysis. In particular, a necessary and sufficient condition for a primal
optimal solution to be generated by the Lagrangian relaxation is obtained. The solution properties of Lagrangian relaxation
problem are studied systematically. To overcome the difficulties caused by duality gap between the primal problem and the
dual problem, we introduce an equivalent reformulation for the primal problem via applying a pth power to the constraints. We prove that this reformulation possesses an asymptotic strong duality property. Primal feasibility
and primal optimality of the Lagrangian relaxation problems can be achieved in this reformulation when the parameter p is larger than a threshold value, thus ensuring the existence of an optimal primal-dual pair. We further show that duality
gap for this partial pth power reformulation is a strictly decreasing function of p in the case of a single constraint.
Dedicated to Professor Alex Rubinov on the occasion of his 65th birthday. Research supported by the Research Grants Council
of Hong Kong under Grant CUHK 4214/01E, and the National Natural Science Foundation of China under Grants 79970107 and 10571116. 相似文献
267.
The constitutive behavior of porous materials (including the yield loci, the void growth rate, the macro stress-strain relation
and the strain to localization instability) is examined based on the lower bound approach proposed by the present authors.
These results are then compared with the experimental and the finite element results as well as those predicted by Gurson's
equations. Emphasis is placed on approaching the real behavior from the upper and the lower bound analysis. Calculation is
also made on the influence of void nucleation on the critical strain to instability and a modified strain-controlled nucleation
criterion is proposed. Finally the instability and fracture of AISI4340 steel in plane strain tension is examined and comparison
is made between theoretical and experimental results. 相似文献
268.
CrystalandMolecularStructureofOMPCTFWangRui-Yao;JinZhong-Sheng(LaboratoryofRareEarthChemistryandPhysics,ChangchunInstituteofA... 相似文献
269.
教学研究:介绍量子力学几个基本概念——兼答《关于量子几何相位的评注》中的几个主要问题 总被引:4,自引:4,他引:0
介绍了量子绝热定理的物理含义及成立的条件,认为有关主要献(Aharonov-Anandan,Bohm,孙昌璞等)的表述是正确的,而《关于量子几何相位的评注》^[1](以下简称《评注》)相应的表述不完全正确。在此基础上,认为这些献和教材(R.Shankar)得出的涉及Berry绝热相位的一些论述(不含Berry绝热相因子的瞬时能量本征态不满足含时Schroedinger方程等)也是正确的,而《评注》的论述与此相反。《评注》认为只有γn(C)才是Berry相位。本作则倾向于把γn(t)叫做Berry绝热相位,而把γn(C)=γn(T)-γn(0)叫做几何相位(geometric phase)^[2]。 相似文献
270.