全文获取类型
收费全文 | 887篇 |
免费 | 113篇 |
国内免费 | 113篇 |
专业分类
化学 | 586篇 |
晶体学 | 11篇 |
力学 | 63篇 |
综合类 | 1篇 |
数学 | 130篇 |
物理学 | 322篇 |
出版年
2024年 | 3篇 |
2023年 | 19篇 |
2022年 | 40篇 |
2021年 | 34篇 |
2020年 | 38篇 |
2019年 | 37篇 |
2018年 | 25篇 |
2017年 | 24篇 |
2016年 | 40篇 |
2015年 | 46篇 |
2014年 | 45篇 |
2013年 | 51篇 |
2012年 | 91篇 |
2011年 | 92篇 |
2010年 | 60篇 |
2009年 | 60篇 |
2008年 | 60篇 |
2007年 | 39篇 |
2006年 | 62篇 |
2005年 | 42篇 |
2004年 | 39篇 |
2003年 | 24篇 |
2002年 | 16篇 |
2001年 | 17篇 |
2000年 | 13篇 |
1999年 | 14篇 |
1998年 | 4篇 |
1997年 | 14篇 |
1996年 | 3篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 9篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1113条查询结果,搜索用时 15 毫秒
101.
A laser collimator is necessary for testing and verification of the pointing, acquisition and tracking (PAT) performance of inter-satellite laser communication terminals on the ground. The laser collimator must have a large clear aperture to fit the PAT performance testing system. The PAT subsystem has a large field of view for the acquisition and a high angular accuracy for the fine tracking. To resolve the conflict between large field of view and fine angular resolution, a large-aperture double-focus laser collimator is proposed and its optical design and mechanical structure are described. The collimator mainly consists of a primary lens, a reflector, a beam-splitting plate, a secondary lens, two compensating lenses, two imaging sensors and a laser. The primary lens directly forms the long focal length arm of the collimator. The combination of the primary lens and the secondary lens form the short focal length arm of the collimator. The collimator has an angular resolution <0.75 μrad and a 10 mrad field of view. For the collimator, the incident beam is focused on the two imaging sensors by its two arms, and the beam emitted from the laser is collimated and transmitted. The collimator is combined with an optical scanner and a fine beam deflector to test and verify the PAT performance of the inter-satellite laser communication terminal in a full physical manner. 相似文献
102.
In this paper the authors use a modified Wirtinger presentation to give a lower bound on the unknotting number of a knot in S3. 相似文献
103.
Application of chromatography technology in the separation of active alkaloids from Hypecoum leptocarpum and their inhibitory effect on fatty acid synthase
下载免费PDF全文
![点击此处可从《Journal of separation science》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Qiulong Zhang Guangxiang Luan Tao Ma Na Hu Yourui Suo Xiaoyan Wang Xiaofeng Ma Chenxu Ding 《Journal of separation science》2015,38(23):4063-4070
A method that involved the combination of pH‐zone‐refining counter‐current chromatography and semipreparative reversed‐phase liquid chromatography has been established for the preparative separation of alkaloids from Hypecoum leptocarpum. From 1.2 g of crude sample, 31 mg N‐feruloyltyramine, 27 mg oxohydrastinine, 47 mg hydroprotopine, 25 mg leptopidine, and 18 mg hypecocarpine have been obtained. The structure of the new compound, hypecocarpine, is confirmed based on the analysis of spectroscopic data, including NMR, UV, and IR spectroscopy and positive electrospray ionization mass spectrometry. The known chemical structures were characterized on the basis of 1H and 13C NMR spectroscopy. The purities of the five alkaloids are all over 92.7% as determined by high‐performance liquid chromatography. The alkaloids’ cytotoxicity in breast cancer cells is assessed by using a Cell Counting Kit assay and their inhibitory effect on fatty acid synthase expression is assessed by a Western blot assay. These results suggest that leptopidine could suppress growth and induce cytotoxicity in breast cancer cells and that the cytotoxicity of leptopidine may be related to its inhibitory effect on fatty acid synthase expression. 相似文献
104.
首先采用溶液共混法制备出石墨烯-碳纳米管(G-CNT)/聚氨酯(TPU)复合材料,然后通过拉伸实验及扫描电子显微镜(SEM)表征来考察该材料的拉伸强度和微波自修复特性,并从力学及材料与微波之间的相互作用等角度对其拉伸强度增强和微波修复机理进行研究.结果表明:在拉伸强度方面,与单一的石墨烯或CNT增强TPU相比,G-CNT之间形成的协同效应使TPU拉伸强度得到进一步提高,当石墨烯和CNT的质量比为3∶1时,G-CNT/TPU抗拉强度较纯TPU提高了67%,较G/TPU提高了18%,较CNT/TPU提高了25%;在材料裂纹的微波修复方面,石墨烯和CNT之间的协同效应使TPU材料自修复效果得到有效提高,当石墨烯和CNT的质量比为3∶1时,G-CNT/TPU修复效果达到最高值117%. 相似文献
105.
Wang Jiajia Yin Haixia Chen Jingshuai Niu Helin Mao Changjie Song Jiming Jin Baokang Tian Yupeng Zhang Shengyi 《Journal of Solid State Electrochemistry》2017,21(8):2381-2391
Journal of Solid State Electrochemistry - A hydrophilic polypyrrole/tellurium (PPy/Te) nanocomposite was synthesized by a facile approach in which H2TeO3 was used as the oxidizing agent of pyrrole... 相似文献
106.
In this paper,it is shown that for a 3-dimensional small cover M over a polytope P,there are only 2-torsions in H1(M;Z).Moreover,the mod 2 Betti number growth of finite covers of M is studied. 相似文献
107.
In this paper, we propose a novel algorithm for solving the classical P-median problem. The essential aim is to identify the optimal extended Lagrangian multipliers corresponding to the optimal solution of the underlying problem. For this, we first explore the structure of the data matrix in P-median problem to recast it as another equivalent global optimization problem over the space of the extended Lagrangian multipliers. Then we present a stochastic search algorithm to find the extended Lagrangian multipliers corresponding to the optimal solution of the original P-median problem. Numerical experiments illustrate that the proposed algorithm can effectively find a global optimal or very good suboptimal solution to the underlying P-median problem, especially for the computationally challenging subclass of P-median problems with a large gap between the optimal solution of the original problem and that of its Lagrangian relaxation. 相似文献
108.
中心逼近式灰色GM(1,1)模型在滑坡变形预测中的应用 总被引:2,自引:0,他引:2
黄龙西村滑坡位于甘肃天水,属黄土高势能滑坡,滑体体积3.9×105m3,基底为花岗闪长岩。为了提高滑坡灰色GM(1,1)模型的预测精度,采用一种改变背景值的方法--中心逼近式灰色GM(1,1)模型。通过黄龙西村滑坡实例验证分析,结果表明中心逼近式灰色GM(1,1)模型的预测值与该滑坡实际监测值十分接近,且其残差平方和及平均误差百分比明显比传统灰色GM(1,1)模型的残差平方和及平均误差百分比小,具有较高的预测精度。同时,可通过调整模型中参数m的取值,使中心逼近式灰色GM(1,1)模型具有更高的预测精度。经计算,当m=6时,中心逼近式灰色GM(1,1)模型的预测精度比传统灰色GM(1,1)模型提高了5.34%。 相似文献
109.
110.