扇贝微量元素的测定

以高压硝化罐消化样品,利用电感耦合等离子体原子发射光谱(ICP-AES)法和火焰原子吸收(AAS)法分别测定了扇贝中的Zn,Co,Fe,Mn,Mg,Ca,Cu,K共八种微量元素的含量, 并对两种分析方法进行了分析比较b 结果表明,ICP-AES法和AAS法测定的微量元素无显著性差异, ICP-AES稍优。方法回收率在93.3%～102.8%之间,相对标准偏差均小于1.60%。扇贝含有丰富对人体有益微量元素,不但味道鲜美,而且可以补充人体所必需的微量元素。     

A cell functional minimization scheme for parabolic problem

We are interested in a robust and accurate finite volume scheme for 2-D parabolic problems derived from the cell functional minimization approach. The scheme has a local stencil, is locally conservative, treats discontinuity rigorously and leads to a symmetric positive definite linear system. Since the scheme has both cell centered unknowns and cell edge unknowns, the computational cost is an issue and a parallel algorithm is then suggested based on nonoverlapping domain decomposition approach. The interface condition is of the Dirichlet–Robin type and has a parameter λ. By choosing this parameter properly, the convergence of the iteration process could be sped up. Numerical results for linear and nonlinear problems demonstrate the good performance of the cell functional minimization scheme and its parallel version on distorted meshes.     

Expression and Characterization of an Active Chimeric Protein of Human Extracellular Superoxide Dismutase and hCuZnSOD in Pichiapastoris

Mammalian cells express two isoforms of Cu-and Zn-containing superoxide dismutases(SODs),CuZnSOD and extracellular SOD(EC-SOD),involved in the defense system against reactive oxygen species(ROS).The two SODs have structurally homologous centre domain with distinct N-and C-terminuses,resulting in the different characteristics of the structure and function of the two molecules.We generated a hybrid SOD molecule(namely hySOD) via replacing the N-and C-terminuses of hCuZnSOD with the counterparts of hEC-SOD.The...     

Influence of Excitation Pulse Width on the Second-Order Correlation Functions of the Exciton-Biexciton Emissions

We investigate theoretically the population dynamics and the second-order correlation functions of photon emissions from the biexciton-exciton system of a single quantum dot with excitation from pulses to continuous wave. The dynamic equations of the correlation functions are deduced by applying quantum regression theorem to optical Bloch equations. The influences of excitation pulse width on the correlation function have been discussed in detail.     

Synthesis of single crystal BaWO4 nanowires in catanionic reverse micelles

High aspect-ratio, single crystal BaWO4 nanowires with diameters as small as 3.5 nm and lengths up to more than 50 microns were synthesized in catanionic reverse micelles formed by an equimolar mixture of two surfactants: undecylic acid and decylamine.     

水溶性高聚物聚丙烯酰胺的稀溶液性质(Ⅰ)

本工作利用光散射和粘度方法,使用辐射聚合聚丙烯酰胺(PAAM)的级分样品,研究了在较宽分子量范围(10~4-10~7)内PAAM的特性粘数,分子尺寸及第二维利系数对重均分子量的依赖性.从实验上得到了PAAM在0.2mol/lNaCl水溶液中的均方旋转半径与均方末端距之间的关系及高分子-溶剂相互作用参数.     

研究强迫非线性振子中倍周期分岔和“混乱”现象的分频采样方法

采用分频采样方法对于在周期外力作用下的非线性振子进行数值研究,达到可与离散映象相比拟的高分辨力。首次为常微分方程组描述的系统确定了高达8192分频的倍周期分岔序列和相应的“混乱”带的序列,并证实存在着嵌在混乱带中的二阶和三阶分岔序列。讨论了分频采样方法的优点和局限性,以及使用这一方法时应注意的问题。 关键词：     

Polymer-directed synthesis of penniform BaWO4 nanostructures in reverse micelles

Novel penniform superstructures of BaWO4 nanowires have been successfully synthesized in catanionic reverse micelles by using a double-hydrophilic block copolymer as the directing agent. This synthetic method is very simple, mild, and controllable, and it provides a novel method for direct solution-growth of hierarchical nanostructures based on inorganic nanowires.     

重离子辐射提高腺病毒介导小鼠黑色素瘤细胞转染率的研究

探讨12C6+ 离子束辐射对用带有绿色荧光蛋白基因的缺陷性腺病毒（AdCMV GFP）转染小鼠黑色素瘤细胞(B16细胞系)的影响。 采用不同剂量的12C6+ 重离子束辐射经AdCMV GFP 转染的B16细胞， 利用流式细胞仪检测腺病毒的转染率。 结果表明， 12C6＋重离子束辐射能提高腺病毒对B16细胞的转染率， 且具有量效关系。 此外， 先转染后辐射法比起先辐射后转染法能更显著地提高转染率。The effect of 12C6+ beam irradiation on AdCMV GFP (a replication deficient recombinant adenoviral vector containing CMV promoter and green fluorescent protein) gene transfection efficiency for murine melanoma cell B16 has been investigated. B16 cells infected with AdCMV GFP were irradiated by different doses of 12C6+ beam. The transfection efficiency was assessed by flow cytometry (FCM). Results show that 12C6+ beam irradiation can improve tansfection efficiency of AdCMV GFP on murine melanoma cell B16 in a dose dependent manner. In addition， the tansfection efficiency in pre tranfection plus irradiation group is higher than that in pre irradiation plus tranfection group at the same dose irradiation dose.     

氧分子和苯酚自由基反应机理的理论研究

用密度泛函理论B3LYP方法对氧分子和苯酚自由基反应机理进行了研究.在B3LYP/6-31G(d,p)水平上优化得到了反应路径上的反应物、中间体、过渡态和产物的几何构型和谐振频率;并在B3LYP/6-311 G(2df,2pd)水平上进行了单点能计算.计算结果表明,苯酚是O2同苯酚自由基Ⅰ反应的主要产物,苯酚过氧自由基Ⅴ和Ⅵ是此反应的次要产物.苯酚过氧自由基Ⅴ的主要后继反应中,环化形成[3.2.1]双环氧桥自由基Ⅶ是主要的反应路径,Ⅶ可以进一步开环反应,形成环裂解产物1,2和1,4二醛.