全文获取类型
收费全文 | 1890篇 |
免费 | 124篇 |
国内免费 | 10篇 |
专业分类
化学 | 1458篇 |
晶体学 | 28篇 |
力学 | 52篇 |
数学 | 95篇 |
物理学 | 391篇 |
出版年
2024年 | 6篇 |
2023年 | 17篇 |
2022年 | 46篇 |
2021年 | 52篇 |
2020年 | 47篇 |
2019年 | 54篇 |
2018年 | 31篇 |
2017年 | 36篇 |
2016年 | 77篇 |
2015年 | 62篇 |
2014年 | 94篇 |
2013年 | 153篇 |
2012年 | 161篇 |
2011年 | 176篇 |
2010年 | 104篇 |
2009年 | 84篇 |
2008年 | 125篇 |
2007年 | 106篇 |
2006年 | 98篇 |
2005年 | 76篇 |
2004年 | 92篇 |
2003年 | 62篇 |
2002年 | 58篇 |
2001年 | 39篇 |
2000年 | 35篇 |
1999年 | 15篇 |
1998年 | 10篇 |
1997年 | 6篇 |
1996年 | 16篇 |
1995年 | 9篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
排序方式: 共有2024条查询结果,搜索用时 15 毫秒
61.
62.
Park Hye Min Kim Jeong Ho Kim Young Seok Kang Sung Won Oh Dae Min Lee Un Jang Kim Do Hyung Joo Koan Sik 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(2):1051-1057
Journal of Radioanalytical and Nuclear Chemistry - An in situ detector for radiological assessments of strontium-90 (90Sr) in river and lake water is developed, based on a CaF2(Eu) scintillator,... 相似文献
63.
64.
65.
66.
Jang Ho Kim Woo Chang Kim Frank J. Fabozzi 《Journal of Optimization Theory and Applications》2014,161(1):103-121
Robust models have a major role in portfolio optimization for resolving the sensitivity issue of the classical mean–variance model. In this paper, we survey developments of worst-case optimization while focusing on approaches for constructing robust portfolios. In addition to the robust formulations for the Markowitz model, we review work on deriving robust counterparts for value-at-risk and conditional value-at-risk problems as well as methods for combining uncertainty in factor models. Recent findings on properties of robust portfolios are introduced, and we conclude by presenting our thoughts on future research directions. 相似文献
67.
Bijesh Sekaran Youngwoo Jang Prof. Dr. Rajneesh Misra Prof. Dr. Francis D'Souza 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(56):12991-13001
A new set of free-base and zinc(II)-metallated, β-pyrrole-functionalized unsymmetrical push–pull porphyrins were designed and synthesized via β-mono- and dibrominated tetraphenylporphyrins using Sonogashira cross-coupling reactions. The ability of donors and acceptors on the push–pull porphyrins to produce high-potential charge separated states was investigated. The porphyrins were functionalized at the opposite β,β′-pyrrole positions of porphyrin ring bearing triphenylamine push groups and naphthalimide pull groups. Systematic studies involving optical absorption, steady-state and time-resolved emission revealed existence of intramolecular type interactions both in the ground and excited states. The push–pull nature of the molecular systems was supported by frontier orbitals generated on optimized structures, wherein delocalization of HOMO over the push group and LUMO over the pull group connecting the porphyrin π-system was witnessed. Electrochemical studies were performed to visualize the effect of push and pull groups on the overall redox potentials of the porphyrins. Spectroelectrochemical studies combined with frontier orbitals helped in characterizing the one-electron oxidized and reduced porphyrins. Finally, by performing transient absorption studies in polar benzonitrile, the ability of push–pull porphyrins to produce charge-separated states upon photoexcitation was confirmed and the measured rates were in the range of 109 s−1. The lifetime of the final charge separated state was around 5 ns. This study ascertains the importance of push–pull porphyrins in solar energy conversion and diverse optoelectronic applications, for which high-potential charge-separated states are warranted. 相似文献
68.
Iseul Jeong Chae Bin Kim Dong‐Gue Kang Kwang‐Un Jeong Se Gyu Jang Nam‐Ho You Seokhoon Ahn Dai‐Soo Lee Munju Goh 《Journal of polymer science. Part A, Polymer chemistry》2019,57(6):708-715
To address tremendous needs for developing efficiently heat dissipating materials with lightweights, a series of liquid crystalline epoxy resins (LCEs) are designed and synthesized as thermally conductive matrix. All prepared LCEs possess epoxies at the molecular side positions and cyanobiphenyl mesogenic end groups. Based on several experimental results such as differential scanning calorimetry, polarized optical microscopy, and X‐ray diffraction, it is found that the LCEs exhibited liquid crystalline mesophases. When LCE is cured with a diamine crosslinker, the cured LCE maintains the oriented LC domain formed in the uncured state, ascribing to a presence of dipole–diploe and π–π interactions between cyanobiphenyl mesogenic end groups. Due to the anisotropic molecular orientation, the cured LCE exhibits a high thermal conductivity of 0.46 W m?1 K?1, which is higher than those of commercially available crystalline or amorphous epoxy resins. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 708–715 相似文献
69.
Lee Chang Hwa Kim Tack-Jin Yoon Dalsung Jang Junhyuk Kim Gha-Young Lee Sung-Jai 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(2):331-336
Journal of Radioanalytical and Nuclear Chemistry - U chlorination is demonstrated using electrochemical and chemical reactions with ZnCl2 in LiCl–KCl molten salts. Voltammetric studies... 相似文献
70.
Chang Hyeong Lee Kyung Duk Park Bongsoo Jang 《Journal of mathematical chemistry》2013,51(7):1945-1960
In this paper, we present the multistage homotopy perturbation method for finding the solution of the chemical kinetics with nonlinear reactions. We develop a general scheme for finding the analytic solution of chemical reaction networks and apply it to motivating chemical examples such as the enzyme kinetics model and the Brusselator model. We illustrate the numerical result for the models and show the accuracy of the method. 相似文献