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21.
22.
Sergio Català‐Clariana Fernando Benavente Estela Giménez José Barbosa Victoria Sanz‐Nebot 《Electrophoresis》2013,34(13):1886-1894
Biologically active peptides derived from complex bovine milk protein hydrolysates are of particular interest in food science and nutrition because they have been shown to play different physiological roles, providing benefits in human health. In this study, we used CE‐TOF‐MS for separation and identification of bioactive peptides in three hypoallergenic infant milk formulas. An appropriate sample cleanup using a citrate buffer with DTT and urea followed by SPE with Sep‐Pack® C18 and StrataXTM cartridges allowed the detection of a large number of low molecular mass bioactive peptides. This preliminary identification was solely based on the measured experimental monoisotopic molecular mass values (Mexp). Later, we evaluated the classical semiempirical relationships between electrophoretic mobility and charge‐to‐mass ratio (me vs. q/Mα, α = 1/2 for the classical polymer model) to describe their migration behavior. The assistance of migration prediction proved to be useful to improve reliability of the identification, avoiding misinterpretations and solving some identity conflicts. After revision, the identity of 24, 30, and 38 bioactive peptides was confirmed in each of the three infant milk formulas. A significant number of these peptides were reported as inhibitors of angiotensin‐converting enzyme, however, the presence of sequences with other biological activities such as antihypertensive, antithrombotic, hypocholesterolemic, immunomodulation, cytotoxicity, antioxidant, antimicrobial, antigenic, or opioid was also confirmed. 相似文献
23.
Giménez-Romero D Agrisuelas J García-Jareño JJ Gregori J Gabrielli C Perrot H Vicente F 《Journal of the American Chemical Society》2007,129(22):7121-7126
This paper demonstrates the importance of the structural changeover in controlling the physical-chemical properties of hexacyanometalate-like materials (Prussian Blue). A meticulous in situ study of compositional variations using electroacoustic impedance techniques associated to electrogravimetric techniques in hexacyanoferrates containing K+ alkali metals reveals the existence of a nanostructural changeover coupled to a change of the magnetic properties of these electromagnetic materials. In the same way, the electroacoustic impedance techniques can be useful both in the understanding and in the in situ monitoring of the structural changeovers and the magnetic behavior of all kinds of materials. 相似文献
24.
E. Giménez-Martín M. López-Andrade A. Ontiveros-Ortega M. Espinosa-Jiménez 《Cellulose (London, England)》2009,16(3):467-479
Comparative investigations of adsorption properties of chlorhexidine (CHX) on two cellulose fibers, bleached cotton and viscose,
were studied in order to obtain dry gauzes covered with known amount of this antiseptic. Adsorption isotherm results carried
out at 293 and 323 K can be described by Langmuir isotherm model, nevertheless, at high concentration correlation is better
to Freundlich isotherm. Electrokinetic potential evolution with CHX concentration, shows that initial negative zeta potential
of cotton and viscose diminish its absolute value as the concentration of the treatment increases; both fibers present an
isoelectric point at high concentration of CHX that is 0.3 mM for viscose and 0.8 mM for cotton. Electrostatic interactions
between cationic groups of CHX and carboxylic acid groups of the fibers could explain adsorption at low concentration, but
when it is higher than these values, possible hydrogen bonding between the amine groups of CHX and hydroxyl groups of cellulose
could explain increasing adsorption when it is hindered by electrostatic repulsion as it is predicted by Freundlich model,
that describes heterogeneous surface and multilayer adsorption. Adsorption kinetics isotherms reveal that the process is quick
with t
1/2 values of 5.4 min for cotton and 2.8 min for viscose. Differences in adsorption behaviour between the two fibers could be
attributed to structural differences as we have observed from estimation of CI index based on FTIR spectra. Values obtained
1.6 for viscose and 2.2 for cotton could explain that the amount of CHX adsorbed on viscose is higher than it is on cotton.
Finally desorption experiments performed with 0.01 M of NaCl solution at room temperature and pH 6 reveals the possibility
of therapeutical application of these fibers although further investigations must be done to optimize the process. 相似文献
25.
Cationic polyallylamine (PAH), was adsorbed onto lignocellulosic fibres, and a fluorescent label on the polyelectrolyte enabled
its location to be shown by confocal fluorescence microscopy. The adsorption time and ionic strength were varied to study
their effect on the localisation of the adsorbed PAH. The microscopy showed that a long adsorption time, 24 h, and a high
ionic strength, 10−1 M NaCl + 5 × 10−3 M NaHCO3 or higher, resulted in the adsorption of polyallylamine throughout the fibre walls. Shorter adsorption times and/or lower
ionic strength resulted in adsorption only to the fibre exterior. By preparing sheets from fibres with polyelectrolyte adsorbed
either to the exterior parts or into the fibre cell wall and testing their mechanical behaviour, a link was established between
the localisation of adsorbed polyelectrolyte and the mechanical properties. Adsorption to the fibre exterior led to an increase
in tensile strength and strain at break. The creep deformation at 90%RH was also slightly reduced by the adsorption of low
molecular weight PAH (15 kDa). When polyallylamine was adsorbed throughout the wall of the lignocellulosic fibres, the mechanical
properties were not however improved and the creep deformation at 90%RH actually increased somewhat. 相似文献
26.
Summary Apparent ionic diffusion coefficients across polycarbonate membranes bathed by two electrolyte solutions have been studied
from Nernst-Planck equation using the assumption of constant electric field. From these diffusion coefficients we have also
determined the cation transport numbers across the membranes. Six different membranes and two electrolytes (LiCl and MgCl2) have been considered, at the temperature of 20°C and for concentrations in the range (10−4÷10−1) mol l−1.
Riassunto Sono stati studiati coefficienti apparenti di diffusione ionica attraverso membrane di policarbonato magnate da due soluzioni di elettroliti a partire dall’equazione di Nernst-Planck usando l’assunto di campo elettrico costante. Da questi coefficienti di diffusione abbiamo anche determinato il numero di trasporto di cationi attraverso le membrane. Si sono considerate sei diverse membrane e due elettroliti (LiCl e MgCl2), alla temperatura di 20°C e per concentrazioni nell’intervallo (10−3÷10+1) mol l−1.
Резюме Используя предположения о постоянном электрическом поле, на основе уравнения Нернста-Планка исследуются ионные коэффициенты диффузии через поликарбанатные мембраны, омываемые двумя электролитическими растворами. Из этих коэффициентов диффузии мы также определяем транспорт катионов через эти мембраны. Были рассмотрены шесть различных мембран и два электролита (LiCl и MgCl2) при температуре 20°C и для концентраций в области (10−4÷ ÷10−1) моль·л−1.相似文献
27.
Campos Giménez E Trisconi MJ Kilinc T Andrieux P 《Journal of AOAC International》2010,93(5):1494-1502
A fast and simple chromatographic method to determine biotin in foods is presented. Biotin is extracted using papain (60 degrees C, 1 h). After pH adjustment and filtration, biotin is determined by LC with fluorescence detection using postcolumn reagent avidin-FITC (avidin labeled with fluorescein isothiocyanate). The method has been validated in a large range of products: milk- and soy-based infant formulas, cereals, cocoa-malt beverages, and clinical nutrition products. The method showed recovery rates of 98.1 +/- 5.7% (average +/- SD) in a large range of concentrations. Biotin concentrations determined in infant formula standard reference materials 1846 and 1849 were in agreement with reference values. RSD of repeatability (RSDr) varied from 2.0 to 4.5%, and intermediate reproducibility (RSD(iR)) from 5.8 to 9.4%. LOD and LOQ were 3.0 and 5.0 microg/100 g, respectively. The proposed method is suitable for routine analysis of biotin in fortified foods (infant formulas, infant cereals, cocoa-malt beverages, and clinical nutrition products). It can be used as a faster, more selective, and precise alternative to the classical microbiological determination, and is easily transferable among laboratories. 相似文献
28.
This study uses data envelopment analysis to analyse the efficiency of educational systems in 31 countries. This type of evaluation is of interest both when formulating a model for analysis and when applying such a model empirically. The efficiency of an educational system must take into account the students' economic and social background, as this is an environmental factor that decisively influences their performance. This is a highly important aspect and so we propose a specific evaluative process for it. Secondly, we evaluate the efficiency of educational systems in different countries, an analysis that has few forerunners since the majority of previous research has focused on analysing a single country. The results suggest that, in general, the most efficient management of educational systems can be found in those countries with a Communist past. They also suggest that there is a series of developed countries, which, judging by the results obtained, could increase their students' performance with even fewer resources than those currently allocated to their educational systems. 相似文献
29.
Sanjurjo Emilio Naya Miguel Ángel Blanco-Claraco José Luis Torres-Moreno José Luis Giménez-Fernández Antonio 《Nonlinear dynamics》2017,88(3):1935-1951
Nonlinear Dynamics - Multibody simulations are already used in many industries to speed up the development of new products. However, improvements in multibody formulations and the continuous... 相似文献
30.
Fernando Giménez 《Israel Journal of Mathematics》1990,71(2):239-255
LetM be a Kaehler manifold of real dimension 2n with holomorphic sectional curvatureK
H≥4λ and antiholomorphic Ricci curvatureρ
A≥(2n−2)λ, andP is a complex hypersurface. We give a bound for the quotient (volume ofP)/(volume ofM) and prove that this bound is attained if and only ifP=C
P
n−1(λ) andM=C
P
n(λ). Moreover, we give some results on the volume of of tubes aboutP inM.
Work partially supported by a DGICYT Grant No. PS87-0115-CO3-01. 相似文献