Reactivities of tetraalkyltin complexes toward Pt/HY zeolite

Tetraalkyltin complexes, SnR₄ (R = Me, Et, Pr, Bu) could react with Pt/HY at 193, 243, 273 and 333 K, respectively. The reactions occurred on the surface of the zeolite and the organotin grafted zeolites were characterized in detail. The framework and the microporous structure of the grafted Pt/HY zeolites were retained. However, the modified zeolites showed better size selectivity in the absorption of hydrocarbons.     

磁性钴纳米晶的二维自组装

在两种表面活性剂存在下，采用高温醇还原，合成出单分散、平均颗粒尺寸为14±19nm，直径标准偏差小(～18%)的磁性金属Co纳米晶.利用x射线衍射、紫外吸收光谱、x射线光电子能谱及透射电子显微镜对其结构和表面价态进行了分析.并将磁性金属Co纳米晶自组织形成有序的二维(2D)六方紧密堆积结构. 关键词： Co纳米晶 单分散 自组装     

光照下meso-四(4-磺基苯基)卟啉(H_2TPPS)形成锌配合物的光-极谱研究

在氨性溶液中,光照射对ZnTPPS的形成影响很大。光-极谱试验表明:光电流(i_p)与浓度(c)间有以下的关系:对Zn(NH_3)_4~(2+),i_p∝C_((Zn)(NH_3)_4)~(2+)_~(1/2),对H_2TPPS,i_p∝C_(H_2TPPS),ZnTPPS络合物还原波的i_p不明显。本文对其差异性和光电流产生的原因做了初步探讨。     

Fundamental reactions in TiO2 nanocrystallite aqueous solutions studied by pulse radiolysis

Reactions of the hydrated electron, H atoms, 2-propanol, and methanol radicals with the TiO₂ nano-particles have been studied either directly or by competition kinetics. The radicals were produced by radiolysis of 2-propanol, t-butanol, or methanol aqueous solutions in acid pH's. The reactions involve electron injection to the conduction band. As expected, the t-butanol radical is inert towards TiO₂ under our conditions, while the other reducing radicals react with TiO₂. The reactivity decreases in the order: e_aq⁻>H>CH₃COHCH₃>CH₂OH. Two TiO₂ nanocrystallite sizes, with average diameters of 1.0 and 4.7 nm were compared. For equal concentrations (in terms of TiO₂ molecules), the rate of electron injection shows relatively little dependency on particle size. The rates of interfacial electron transfer and transfer coefficient are also reported.     

系综分布和它的小涨落近似

由“从正则分布出发，在小涨落近似下得出的能量涨落分布公式”求得的能量涨落的二次矩与直接由正则分布求得的二次矩完全相同，但分别由二求得的高次矩并不完全相同。     

Synthesis of single crystalline layered lithium manganese oxide nanorods

Single-crystalline layered lithium manganese oxide nanorods were prepared via a low-temperature molten salt synthesis method. The material was investigated by a variety of techniques, including X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectrum (XPS).     

A New Pathway to Synthesize Cyclomercurated Ferrocenylimines Containing Heterocyclic Ring

The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine.This procedure provides an efficient method for the synthesis of cyclomerucurated ferrocenylimines containing heterocyclic ring which are difficultly synthesized by the conventional method.The reaction mechanism is proposed.     

托卡马克能量约束及自举电流效应的初步考虑

基于Lee等人的离子温度梯度模导致的反常热能输运系数,本文研究了辅助加热托卡马克等离子体的能量约束行为,并对自举电流的效应作了初步考虑。结果表明,计算得到的能量约束时间随等离子体电流I_p和托卡马克大半径R增大而增长,随注入功率P_t、环向场B_t以及等离子体小半径α的增大而缩短。这些结果与Kaye-Goldston的经验约束定标具有相同的趋势。自举电流的存在总是导致能量约束时间的增加,当自举电流与总电流的比值γ较小时,能量约束时间的增加率约为γ/2。此外,自举电流将造成锯齿反转半径的减小。     

析氢反应动力学的交流阻抗法研究

利用交流阻抗法测定析氢电化学动力学参数，得到与极化曲线法一致的结果，为确定复杂析氢过程速率的决定步骤提供了判据。