纳米WO3的制备及其光解水析氧性能研究

用溶胶凝胶法,灼烧法合成了纳米级WO3,采用X-射线衍射、紫外可见漫反射光谱对WO3进行表征.在Fe3 为电子受体、溶液酸度pH为2.0情况下,研究了纳米级WO3在365nm紫外辐射下光解水析氧的光催化活性,并讨论了不同方法制备的催化剂活性差异的原因.结果表明,结晶程度越高、尺寸越小、比表面积越大的纳米级WO3具有更高的光分解水析氧活性,电子受体的浓度、溶液的酸度对析氧活性有明显的影响.     

Graphitic nanofillers in PMMA nanocomposites—An investigation of particle size and dispersion and their influence on nanocomposite properties

Mechanical, thermal, and electrical properties of graphite/PMMA composites have been evaluated as functions of particle size and dispersion of the graphitic nanofiller components via the use of three different graphitic nanofillers: “as received graphite” (ARG), “expanded graphite,” (EG) and “graphite nanoplatelets” (GNPs) EG, a graphitic materials with much lower density than ARG, was prepared from ARG flakes via an acid intercalation and thermal expansion. Subsequent sonication of EG in a liquid yielded GNPs as thin stacks of graphitic platelets with thicknesses of ～10 nm. Solution‐based processing was used to prepare PMMA composites with these three fillers. Dynamic mechanical analysis, thermal analysis, and electrical impedance measurements were carried out on the resulting composites, demonstrating that reduced particle size, high surface area, and increased surface roughness can significantly alter the graphite/polymer interface and enhance the mechanical, thermal, and electrical properties of the polymer matrix. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2097–2112, 2007     

Investigation on crosslinking behaviors of NBR/PVC filled with anhydrous copper sulfate particles by dynamic mechanical analysis

Crosslinking behaviors of acrylonitrile butadiene rubber (NBR)/poly (vinyl chloride) (PVC) alloy, filled with anhydrous copper sulfate (CuSO₄) particles, were investigated for the first time by dynamic mechanical analysis (DMA) under hetero and isothermal modes, respectively. In the heterothermal testing, (NBR/PVC)/CuSO₄ compound showed two marked increases in the storage modulus (E′), corresponding to coordination crosslinking of NBR-CuSO₄ and self-crosslinking of NBR and PVC respectively. During the isothermal testing, a dramatic increase in E′ was found at the initial stage while that of original NBR/PVC alloy was not detected. The marked increase in E′ of (NBR/PVC)/CuSO₄ compound was mainly due to the crosslinking induced by coordination between  CN and Cu²⁺. The increasing extent of E′ increased with the rise of CuSO₄ content, suggesting the formation of a greater number of crosslinks. Moreover, the activation energy (E_a) of crosslinking process was about 139 kJ/mol. In this work, fourier transform infrared spectrum (FT-IR) and equilibrium swelling method were also performed for the characterization of the compound. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 41–51, 2007     

Protection of iron corrosion by stearic acid and stearic imidazoline self-assembled monolayers

A type of stearic imidazoline (IM) inhibitor was prepared using stearic acid (SA) and diethylenetriamine (DETA) as raw materials. The monolayers of IM and SA were assembled on the iron surface. The electrochemical characterization of stearic acid (SA) and stearic imidazoline (IM) on an oxide free iron surface had been studied. The monolayers of IM inhibitor were characterized by electrochemical impedance spectroscopy (EIS), electrochemical polarization curves, double layer capacitance, X-ray photoelectron spectroscopy (XPS) and molecular simulation. The results of electrochemical studies had illustrated that the inhibition efficiency of IM was higher than SA. XPS showed that the IM molecules adsorbed on the iron surface. The molecular simulation calculations showed that the IM molecules were tilted at an angle on the iron surface.     

Fission Barrier for ^240Pu in the Quadrupole Constrained Relativistic Mean Field Approach

The fission barrier for ^240pu is investigated beyond the second saddle point in the potentiM energy surface by the constrained relativistic mean field method with the newly proposed parameter set PK1. The microscopic correction for the centre-of-mass motion is essentiM to provide the correct potential energy surface. The shell effects that stabilize the nuclei against the fission is also investigated by the Strutinsky method. The shapes for the ground state, fission isomer and saddle-points, etc, are studied in detail.     

On the uniqueness of the foliation of spheres of constant mean curvature in asymptotically flat 3-manifolds

In this note we study constant mean curvature surfaces in asymptotically flat 3-manifolds. We prove that, outside a given compact subset in an asymptotically flat 3-manifold with positive mass, stable spheres of given constant mean curvature are unique. Therefore we are able to conclude that the foliation of stable spheres of constant mean curvature in an asymptotically flat 3-manifold with positive mass outside a given compact subset is unique.

     

Eu3+离子在微晶玻璃研究中的探针作用

制备出单掺Eu3+离子的氟氧化物玻璃陶瓷系列样品,利用Eu3+离子作为荧光探针,通过热处理前后Eu3+离子发射光谱中电偶极子跃迁与磁偶极子跃迁强度比值的变化表征在玻璃材料中微晶是否形成,分析了Eu3+离子荧光发射谱中电偶极子跃迁与晶体场对称性的关系,进一步表征了稀土离子所处微晶晶格场的变化.     

The Generalized West Decomposition of Operators and Other Compact Perturbation Problems

This paper introduces the concept of the generalized Riesz operators and the concept of the generalized West decomposition of a general operator which generalizes the definition of the West decomposition of Riesz operators, and proves that the following three statements are equivalent on a general Banach space： （a） Every generalized Riesz operator has the generalized West decomposition; （b） Every operator makes strong Stampfli theorem true; Every operator has Apostol＇s compact correction.     

图像的自动采集分析和实现

文章针对焊件检测过程中需大量采集和分析实时图像的要求 ,利用小波分析的特点 ,相关跟踪识别视频图像运动状态 ,实现自动采集、分析处理和储存一并完成 ,解决了视频图像连续捕获不能得到高像质的问题。