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81.

Boron carbide (B4C) is one of the main products from the primary combustion of boron (B)-based propellants and has a significant influence on the secondary combustion of B. To systematically evaluate its effects on the secondary combustion of B, mixtures of B4C and B in different mass ratios were prepared. To study the ignition temperatures and combustion flames of the samples, a xenon lamp ignition experimental system and a flame shape test system were designed, respectively. A thermogravimetry–differential scanning calorimetry–Fourier transform infrared spectroscopy combined thermal analysis system was used to study the thermal oxidation characteristics and analyze the gaseous products of the samples. The results indicate that B4C reduces the heat absorption at the beginning of the ignition, but subsequently prevents the rapid rise of sample temperature. During the stable combustion stage, the maximum flame length under optical density 10−4 (OD4) filter was 20.4 mm, and the maximum flame length under 580 nm + OD4 filters (represents the combustion of B element) was 16.7 mm. The samples contained a small amount of HBO2 and H3BO3, which led to slight mass loss during the low temperature section of the thermal oxidation process. During the high temperature section, the oxidation of B and B4C caused considerable mass gain. The gaseous products of the thermal oxidation process include CO2, CO, and H2O. In general, the B content of 60% was the most beneficial to decrease the oxidation temperature, increase the combustion intensity, and improve the heat-releasing ability of the samples.

  相似文献   
82.
将周培源给出的平面湍尾流的一级近似解作为已知量,代入湍流脉动速度方程中,在微尺度范围内,采用谱方法对该方程进行数值求解,得到了和实验结果符合的二阶、三阶、四阶脉动速度关联函数的计算结果。  相似文献   
83.
郑建中 《力学学报》2007,15(2):253-257
富溪双连拱隧道出口高边坡岩体风化、卸荷严重,在施工开挖前边坡中上部已经发生较为明显的倾倒变形,整个变形体处于极限平衡状态。本文在现场调查和岩体结构分析基础上,建立了边坡变形破坏机理的概念模型,利用FLAC3D模拟研究了开挖后坡体变形特征。在变形分析基础上,提出了对倾倒变形体采用锚管注浆处理的边坡治理措施,支护效果模拟计算表明,注浆后边坡稳定性较好,同时监测资料也显示支护措施实施后,边坡的稳定性较好,可以保障公路的施工和长期营运的安全。  相似文献   
84.
针对一类机器人操作手,提出了一种设计机器人操作手迭代学习控制的新方法,与其它现有的迭代学习控制方法相比较,当折合到机器人操作手关节轴上的驱动装置惯量足够大时,可以用驱动装置的动力学特性参数确定学习增益,克服了传统迭代学习控制方法由多次尝试选取学习增益的缺点,增强了实用性。在实际机器人操作手上的实验结果充分表明了新提出方法可获得较高学习速度和控制精度的优越性。  相似文献   
85.
The Raman spectroscopic data in the range 500-1800 cm−1 for a series of 15 rare earth double-deckers with tervalent rare earths MIII[Pc(MeOPhO)8]2 (M = Y, La, …, Lu, except Ce, Pr and Pm), reduced state HPr[Pc(MeOPhO)8]2 and intermediate-valent cerium Ce[Pc(MeOPhO)8]2 have been collected using laser excitation source emitting at 632.8 nm. With excitation at 632.8 nm, which is in close resonance with the main Q absorption band of the phthalocyanine ligand, typical Raman marker bands of the monoanion radical [Pc(MeOPhO)8] were observed at 1500-1528 cm−1 as very strong bands resulting from the coupling of pyrrole CC and aza CN stretchings. For Ce[Pc(MeOPhO)8]2 and HPr[Pc(MeOPhO)8]2, a very strong band at 1499 cm−1 with contributions from both pyrrole CC and aza CN stretchings and also isoindole stretching was the marker Raman band of [Pc(MeOPhO)8]2−. In addition, the influence of ionic radius of the rare earth metal and substituent species on the Raman scatting characteristics of sandwich-type compounds has also been tentatively studied.  相似文献   
86.
In a recent work [Gao et al., Appl. Phys. Lett. 134, 113902 (2007)], we reported a novel DNA separation method by tethering DNA chains to a solid surface and then stretching the DNA chains with an electric field. The anchor is such designed that the critical force to detach a DNA chain is independent of its length. Because the stretching force is proportional to the DNA net charge, a gradual increase of the electric field leads to size-based removal of the DNA strands from the surface and thus DNA separation. Originally proposed for separation of long double-stranded DNA chains (>10 000 bps), this method has been proven useful also for short single-stranded DNA fragments (<100 bases) for which the fluctuation force induced by the solvent becomes significant. Here we show that the fluctuation force can be approximately represented by a gaussian model for tethered DNA chains. Analytical expressions have been derived to account for the dependence of the fluctuation force on the surface confinement, the polymer chain length, and the DNA tethering potential. The theoretical predictions are found to coincide with experiment.  相似文献   
87.
Peng Q  Cao Z  Lau C  Kai M  Lu J 《The Analyst》2011,136(1):140-147
We report on a highly sensitive aptameric assay system for the determination of IgE, where a special chemiluminescence (CL) reagent, 3,4,5-trimethoxylphenylglyoxal (TMPG), acts as the signaling molecule and polystyrene beads as the amplification platform. Briefly, a "sandwich-type" detection strategy is employed in our design, where magnetic beads functionalized with a capture antibody were reacted with the target protein IgE, and then sandwiched with the aptamer-barcodes which were prepared by assembling polystyrene beads with IgE aptamer. The target immunoreaction event could be sensitively detected via an instantaneous derivatization reaction between TMPG and the guanine (G) nucleotides within the aptamer-barcodes to form an unstable CL intermediate for the generation of light. Further signal amplification is achieved by extending the G nucleotide-rich domain on the aptamer backbone for second amplification. Such simple amplified CL transduction allows the detection of IgE down to the 4.6 pM level, which is better than most previous aptameric methods for IgE detection. This new protocol also provides a good capability in discriminating IgE from nontarget proteins such as IgG, IgA, IgM, interferon and thrombin. The practical application of the proposed aptamer-barcode based immunoassay was successfully carried out for the determination of IgE in 20 human serum samples. It is straightforward to adapt this strategy to detect a spectrum of other proteins by using different aptamers, thus this method may offer a new direction in designing high-performance CL aptasensors for early diagnoses of diseases.  相似文献   
88.
The object of this research aims at the hydraulic generator unit rotor system. According to fault problems of the generator rotor local rubbing caused by the parallel misalignment and mass eccentricity, a dynamic model for the rotor system coupled with misalignment and rub-impact is established. The dynamic behaviors of this system are investigated using numerical integral method, as the parallel misalignment, mass eccentricity and bearing stiffness vary. The nonlinear dynamic responses of the generator rotor and turbine rotor with coupling faults are analyzed by means of bifurcation diagrams, Poincaré maps, axis orbits, time histories and amplitude spectrum diagrams. Various nonlinear phenomena in the system, such as periodic, three-periodic and quasi-periodic motions, are studied with the change of the parallel misalignment. The results reveal that vibration characteristics of the rotor system with coupling faults are extremely complex and there are some low frequencies with large amplitude in the 0.3–0.4× components. As the increase in mass eccentricity, the interval of nonperiodic motions will be continuously moved forward. It suggests that the reduction in mass eccentricity or increase in bearing stiffness could preclude nonlinear vibration. These might provide some important theory references for safety operating and exact identification of the faults in rotating machinery.  相似文献   
89.
采用数值模拟方法研究了波音737-200座舱模型内的气流场以及污染物传播过程,并通过实验数据加以验证;分析了天花板加侧壁送风(混合送风)、侧壁送风以及天花板送风三种送风方式下座舱内的速度场、涡量场、污染物浓度场和空气龄,并且解释了舱内流场结构对污染物传播过程的影响。研究结果表明:不同送风方式下飞机座舱内污染物的传播过程差异明显,这是由流场结构特征的差异造成的,特别是在小尺度范围内,涡结构十分复杂,严重影响污染物的传播规律;在聚集过程中,污染物更容易在漩涡范围内聚集,而变形主导的气流运动会阻碍污染物向更大范围传播;在排除过程中,天花板送风形式下污染物的排除效率最快,混合送风次之,侧壁送风最慢。这对于防控新冠肺炎是有参考价值的。  相似文献   
90.
Methods of nonnegative tensor factorization (NTF), such as NTF1, NTF2, etc., are extension of nonnegative matrix factorization (NMF) for multi-way data analysis. As an existing NTF method, nonnegative Tucker3 decomposition (NTD) is researched for three-way decomposition in this paper. Firstly, an approach utilizing matrix exponentials built on Tikhonov-type regularization to enforce sparseness is proposed to extract image features instead of exclusively using Tucker tensor decomposition. Meanwhile, updating algorithms, derived from updating rules of NMF, are allowed to efficiently implement updating of mode matrices and core tensors alternatively for accuracy. Then, experimental cases of alternating least squares (ALS) and conjugate nonnegative constraints, called nonnegative alternating least squares (NALS), are studied to remedy data overfitting in computing procedures. Lastly, the proposed method exhibits more advantageous results than other algorithms of Tucker3 for feature extraction, thanks to computer simulations performed in the context of data analysis.  相似文献   
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