纳米纤维结构对石墨/纳米碳纤维复合材料电化学性能的影响

为了实现石墨/纳米碳纤维复合材料用作锂离子电池负极材料的商业化应用,本实验采用了化学气相沉积在石墨颗粒表面原位生长纳米碳纤维包覆的方法制备了石墨/纳米碳纤维复合材料,利用拉曼、扫描电镜以及高分辨透射电镜等手段对纳米碳纤维包覆层中纤维的形貌与微观结构进行研究.研究结果表明:550℃下生长的板式结构的纤维嵌锂容量要高于600℃生长的无序结构和650℃生长的管状结构纤维;纳米碳纤维优良的导电性能能够复合材料的倍率性能;此外,复合材料中纤维比例在5;左右时,循环稳定性好,首次循环库伦效率也较高.     

非线性变形节理中纵波传播特性的理论研究

基于波前动量守恒理论和位移不连续方法所提出的时域分析新方法,引入岩石非线性法向本构关系,对弹性纵波在岩石非线性节理中的传播特性进行了理论分析。采用节理变形的双曲线模型(BB模型),获得纵波P波斜入射非线性节理的传播波动方程,并通过参数研究分析了在岩石节理中节理非线性系数、节理初始刚度、应力波入射角和入射波幅值等因素对纵波传播规律的影响。结果表明:所推导的应力波传播方程在考虑多种非线性问题时,通过迭代计算即可方便求出透射波和反射波的数值解,避免了复杂的数学运算;当波斜入射节理面时,产生了波型转换,节理变形的非线性对透射波和反射波有较大影响,透射系数和反射系数并非随着非线性参数的变化而单调变化。时域内所推导的波传播方程更有益于波斜入射时非线性参数的广泛研究,为开展该方面的理论研究工作提供了借鉴。     

纳米TiO2/蛋白土复合材料的制备与表征

为了解决纳米TiO2在使用过程中分散性差、难以回收等缺点,将纳米TiO2负载在酸浸蛋白土表面,提高光催化效率.以酸浸蛋白土为载体,TiCl4为前驱体,采用水解沉淀法制备了纳米TiO2/蛋白土复合材料.采用XRD、TEM等方法对复合材料性能进行了表征,并进行了复合材料的光催化降解甲醛实验研究.结果表明负载在蛋白土表面的Ti02晶型为锐钛型,晶粒粒度为5～20 nm.对甲醛降解实验研究结果表明,所制备的蛋白土负载纳米TiO2复合材料具有良好的光催化降解性能,其24h对甲醛的降解去除率可以达到90;以上.     

Nonlinear dynamic analysis of a rub-impact rotor supported by oil film bearings

A general model of a rub-impact rotor system is set up and supported by oil film journal bearings. The Jacobian matrix of the system response is used to calculate the Floquet multipliers, and the stability of periodic response is determined via the Floquet theory. The nonlinear dynamic characteristics of the system are investigated when the rotating speed and damping ratio is used as control parameter. The analysis methods are inclusive of bifurcation diagrams, Poincaré maps, phase plane portraits, power spectrums, and vibration responses of the rotor center and bearing center. The analysis reveals a complex dynamic behavior comprising periodic, multi-periodic, chaotic, and quasi-periodic response. The modeling results thus obtained by using the proposed method will contribute to understanding and controlling of the nonlinear dynamic behaviors of the rotor-bearing system.     

维吾尔语焦点的韵律实现及感知

通过严格控制的语音实验,研究了维吾尔语陈述句中焦点对音高和时长的调节作用。实验设计了两个目标句,请发音人根据上下文自然地强调句中相应的词,随后还考察了焦点的感知问题。结果表明:(1)以句末焦点为基线,维吾尔语焦点的韵律编码方式类似于北京话和英语中的"三区段"调节模式,表现为焦点词音高升高、音域扩大和焦点后音高骤降(音域变窄),而焦点前音高变化不大;(2)焦点词和焦点前的词时长都有延长,而焦点后的词没有明显变化;(3)对焦点感知的正确率平均可达90%左右,表明焦点的韵律编码方式是有效的感知线索;(4)感知实验及语调分析还显示,维吾尔语"中性焦点"语调特征与英语和汉语不同,它接近句首焦点而不是句末焦点。另外,论文特别讨论了"焦点后音高骤降"在中国语言中的分布及来源问题。      

无锡钢电镀溶液中氟离子电化学行为的研究

采用交流伏安法、电化学阻抗谱(EIS)和Mott-Schottky 分析技术研究了无锡钢电镀液中氟离子电化学行为. 结果表明, 在氧化还原过程中氟离子抑制铬离子化学状态转变, 降低铅合金和铅氧化物阳极的氧化电流密度, 改变铅合金和铅氧化物阳极的氧化还原历程. EIS 结果表明电场作用下溶液中铬氧离子团发生聚合, 在铅合金阳极表面形成感抗现象. 含氟溶液中铬氧离子团在阳极表面的感抗现象消失, 溶液导电性提高. Mott-Schottky 曲线显示氟离子提高阳极材料的载流子密度, 铅合金阳极和铅氧化物阳极均为n 型半导体.     

交替三线性分解算法结合区域变量选择同时分辨和定量测定二甲基苯酚异构体复杂体系

研究同分异构体复杂体系的同时分辨和定量测定,选取二甲基苯酚(DMP)5种同分异构体：2,3-二甲基苯酚、2,4-二甲基苯酚、2,5-二甲基苯酚、2,6-二甲基苯酚和3,4-二甲基苯酚,对该色谱和光谱严重重叠的复杂体系,经高效液相色谱．光二极管阵列检测联用仪(HPLC-DAD)检测后,结合选取较佳保留时间及较佳光谱波长范围的办法,利用化学计量学中的交替三线性分解算法进行分辨解析和定量测定,获得较满意结果。     

血清中硫脂质的提纯及其结构分析

应用离子交换及硅胶柱色谱法分离提纯血清中酸性脂质,并采用薄层色谱法(TLC)、TLC免疫染色法、质谱法及溶化分解等方法分析血清中硫脂质的种类及结构。实验确定了样品的提纯体系,证实胆固醇硫酸及脑硫脂是血清中的主要硫脂质。     

Optical properties of zinc barium silicate glasses

A serial of glasses samples with the higher ZnO concentration from 30 mol% to 45 mol% were prepared and their optical absorption and photoluminescence properties were investigated. It is shown that the composition of glass strongly affects the position of the absorption edge and emission band where a fairly big red-shift was observed with increasing of ZnO concentration. It is most likely attributed to the reduced quantum confinement effect due to increased aggregation degree of ZnO in the glass matrix. The introduction of F^? into zinc barium silicate glasses leads to a notable red-shift of the absorption spectra, as well as the enhanced UV emission and distinctive visible emissions.     

Sovolthermal Synthesis and Crystal Structure of Two CdII Coordination Polymers of Benzenedicarboxylic

Abstract  Two cadmium coordination polymers of benzenedicarboxylic: [C₈H₆CdO₅]_n (1) and [C₈H₁₀CdO₇]_n·4H₂O (2), have been synthesized by sovolthermal method and characterized by single-crystal X-ray diffraction. Our experimental results suggest that complex 1 crystallizes in orthorhombic space group Pbcm with a = 6.4978(8) ?, b = 6.9475(9) ?, c = 18.319(2) ?, and Z = 4. Structural analysis reveals that complex 1 features a three-dimensional framework structure formed by strong coordination bond and weak hydrogen bond force. Complex 2 crystallizes in orthorhombic space group Pcca with a = 7.293(2), b = 9.980(3), c = 19.889(6), and Z = 4. Complex 2 exhibits a layered framework structure formed by extensive inter-chain hydrogen bond interaction. Index Abstract  Two cadmium coordination polymers of benzenedicarboxylic: [C₈H₆CdO₅]_n (1) and [C₈H₁₀CdO₇]_n·4H₂O (2), have been synthesized by sovolthermal method and characterized by single-crystal X-ray diffraction