全文获取类型
收费全文 | 7369篇 |
免费 | 1153篇 |
国内免费 | 741篇 |
专业分类
化学 | 4859篇 |
晶体学 | 74篇 |
力学 | 434篇 |
综合类 | 42篇 |
数学 | 697篇 |
物理学 | 3157篇 |
出版年
2024年 | 26篇 |
2023年 | 155篇 |
2022年 | 209篇 |
2021年 | 211篇 |
2020年 | 275篇 |
2019年 | 231篇 |
2018年 | 215篇 |
2017年 | 192篇 |
2016年 | 315篇 |
2015年 | 311篇 |
2014年 | 380篇 |
2013年 | 526篇 |
2012年 | 564篇 |
2011年 | 605篇 |
2010年 | 413篇 |
2009年 | 417篇 |
2008年 | 442篇 |
2007年 | 378篇 |
2006年 | 377篇 |
2005年 | 341篇 |
2004年 | 288篇 |
2003年 | 207篇 |
2002年 | 235篇 |
2001年 | 181篇 |
2000年 | 174篇 |
1999年 | 187篇 |
1998年 | 137篇 |
1997年 | 139篇 |
1996年 | 163篇 |
1995年 | 121篇 |
1994年 | 123篇 |
1993年 | 114篇 |
1992年 | 106篇 |
1991年 | 85篇 |
1990年 | 64篇 |
1989年 | 74篇 |
1988年 | 52篇 |
1987年 | 47篇 |
1986年 | 39篇 |
1985年 | 35篇 |
1984年 | 20篇 |
1983年 | 18篇 |
1982年 | 14篇 |
1981年 | 13篇 |
1980年 | 9篇 |
1979年 | 6篇 |
1976年 | 4篇 |
1973年 | 3篇 |
1970年 | 3篇 |
1957年 | 3篇 |
排序方式: 共有9263条查询结果,搜索用时 0 毫秒
991.
Shen Shuifa Fang Keming Gu Jiahui Liu Qingcheng Xu Furong 《The European Physical Journal A - Hadrons and Nuclei》2007,32(2):149-158
The decay of 95Ru has been investigated by means of γ-ray spectroscopy. The 95Ru nuclei were produced by the reaction 92Mo( α, n) 95Ru at a beam energy of 17MeV. High-purity Ge detectors have been used singly and in coincidence to study γ-rays in the decay of 95Ru to 95Tc. 132 γ-rays are reported, among them, energies and intensities for 127 transitions have been determined. A decay scheme of 95Ru with 31 levels is proposed which accommodates 127 of these transitions. Spins and parities for three new levels are proposed
from calculated log ft values, measured γ-ray branching ratios, and in-beam experiment results of the daughter nucleus 95Tc. Combining with the high-spin states observed by in-beam γ-ray spectroscopy of previous decay works, the structure of the excited states of 95Tc is discussed in the framework of the projected shell model. 相似文献
992.
Xiaodong Jin Suping Cui Shibing Sun Yingliang Tian Feng Lv Xiaoyu Gu Hongfei Li Jun Sun Sheng Zhang Serge Bourbigot 《先进技术聚合物》2019,30(7):1605-1615
In this work, a novel sulfur‐based flame retardant (SA‐M) was synthesized by the self‐assembly of melamine and sulfamic acid. The chemical structure of SA‐M was fully characterized. SA‐M, in company with Al2O3, was then introduced into polyamide 11 (PA 11) by melt compounding in order to improve the fire resistance of the polymer substrate. The observation by scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) indicated the well dispersion of SA‐M in PA 11 matrix. The fire performance of PA 11 composites was evaluated by limiting oxygen index (LOI), vertical burning (UL‐94), and cone calorimeter tests, respectively. The results showed that the presence of 17.5% SA‐M and 2.5% Al2O3 increased the LOI value from 22.4% to 30.9%, upgraded the UL‐94 rating from no rating to V‐0, significantly eliminated the melt dripping, and decreased the peak heat release rate from 1024 to 603 kW/m2. The thermal behaviors were investigated by thermogravimeric analysis (TGA) and TGA‐Fourier transform infrared spectroscopy (FTIR). It was suggested that SA‐M took effects mainly in gas phase by diluting the combustible fuel, leading to the improvement of the fire resistance of PA 11. 相似文献
993.
Qingxia Xue Quan Wu Yuan Yao Xinjian Li Jun Sun Xiaoyu Gu Weiguo Song Fang Yan Sheng Zhang 《先进技术聚合物》2021,32(1):368-378
An efficient bio‐safe cyclophosphazene flame retardant, 1,5,9,13,16,20‐Hexaoxa‐7,14,21‐triaza‐6λ4,8λ4,5λ4‐triphosphatrispiro[5.1.5.1.5.1]heneicosa‐6,8(14),15(21)‐triene (HCPO), was synthesized, and then was incorporated into polylactic acid (PLA) to improve the fire safety. The chemical structure of HCPO was confirmed by Fourier‐transformed infrared spectroscopy, mass spectrometry, and nuclear magnetic resonance spectroscopy. The thermal stability of the compound was characterized by thermogravimetric (TG) analyzer. The cytotoxic effects of HCPO to cells were evaluated. Fire behavior and thermal stability of PLA composites were investigated by vertical burning, limiting oxygen index (LOI), TG analysis, and cone calorimeter. The morphology of residual charring was observed by scanning electron microscope. The results showed HCPO was bio‐safe, and highly effective to enhance the flame retardancy of PLA composites. The LOI value was increased from 18.4 to 27.5 and UL‐94 grade achieved V‐0 for the PLA composite containing only 2% HCPO and 2% pentaerythrotol. It was demonstrated that intermolecular cross‐linking reaction between pentaerythrotol and HCPO in high temperature range could accelerate the formation of compact char layers. 相似文献
994.
We demonstrated the interaction of a gold cone target with a femto second(fs) laser pulse above the relativistic intensity of 1.37×10 18 μm 2 W/cm 2.Relativistic electrons with energy above 2 MeV were observed.A 25%-40% increase of the electron temperature is achieved compared to the case when a plane gold target is used.The electron temperature increase results from the guiding of the laser beam at the tip and the intense quasistatic magnetic field in the cone geometry.The behavior of the relativistic electrons is verified in our 2D-PIC simulations. 相似文献
995.
A force field is developed for zeolitic imidazolate framework-8 (ZIF-8) with structural flexibility by combining quantum chemical calculations and classical Amber force field. The predicted crystalline properties of ZIF-8 (lattice constants, bond lengths, angles, dihedrals, and x-ray diffraction patterns) agree well with experimental results. A structural transition from crystalline to amorphous as found in experiment is observed. The mechanical properties of ZIF-8 are also described fairly well by the force field, particularly the Young's modulus predicted matches perfectly with measured value. Furthermore, the heat capacity of ZIF-8 as a typical thermophysical property is predicted and close to experimental data available for other metal-organic frameworks. It is revealed the structural flexibility of ZIF-8 exerts a significant effect on gas diffusion. In rigid ZIF-8, no diffusive behavior is observed for CH(4) within the simulation time scale of current study. With the structural flexibility, however, the predicted diffusivities of CH(4) and CO(2) are close to reported data in the literature. The density distributions and free energy profiles of CH(4) and CO(2) in the pore of ZIF-8 are estimated to analyze the mechanism of gas diffusion. 相似文献
996.
997.
998.
999.
Jia‐Jian Wang Hua‐Ming Zeng Zhi‐Gang She Cheng‐Du Miao Kui Hong Yu‐Cheng Gu Lan Liu Yong‐Cheng Lin 《Helvetica chimica acta》2011,94(10):1875-1880
Two new meroterpenes, ‘acetoxydehydroaustin B’ ( 1 ) and ‘1,2‐dihydro‐acetoxydehydroaustin B’ ( 2 ) were isolated in the form of a mixed crystal from the mangrove endophytic fungus Aspergillus sp. 085241B. Their structures and absolute configurations were determined by extensive analysis of their spectra and X‐ray diffraction data. In a preliminary bioassay, the mixed crystal did not exhibit activities against cancer cell lines of MDA‐MB‐435, SKBR3, HepG2, HEP3B, PC‐3, and A549, as well as against α‐glucosidase and tyrosinase. 相似文献
1000.
Jian Feng Gu Miroslav Grmela Mosto Bousmina 《ournal of non Newtonian Fluid Mechanics》2010,165(3-4):75-83
Doi–Ohta rheological model of immiscible blends is extended by replacing the fluid interface with an elastic membrane. A symmetric tensor characterizing the in-membrane deformations joins the surface area and the orientation tensor (used in the Doi–Ohta theory) to provide morphological state variables. The governing equations of the model are solved numerically and the morphological and rheological predictions are presented. As an illustration, we regard the model as a first step in mesoscopic rheological modeling of suspensions of red blood cells. The material properties of the membrane enclosing the red blood cells, that are inferred from rheology, are indeed found to be close to the ones seen in direct experimental measurements. A more realistic model of human blood has to include additional morphological state variables describing larger structures (in particular whole red blood cells). 相似文献