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991.
N-Acylalkylation of neutral and anionic N-nucleophiles with α-halocarbonyl compounds was investigated by quantum chemical methods
in terms of the density functional theory and by experimental methods for 2,3-dihydroimidazo[2,1-b]quinazolin-1(10)H-5-one, its N-anion, and simpler model structures. High reactivity of these reagents is determined primarily by stabilization
of transition states (TS) by bridge bonds involving halogen or nitrogen atoms rather than by conjugation, as has been commonly
accepted. Bridged TS are formed by both the substitution mechanism S
N
2 and the addition-elimination mechanism. α-Haloalkyl-substituted zwitterions, which are potential intermediates of stepwise
N-acylalkylation of neutral N-nucleophiles, do not exist in the isolated state, but they are rather efficiently stabilized
upon solvation. These zwitterions, as well as analogous O-anions generated from anionic N-nucleophiles, can serve as intermediates
of N-acylalkylation, as was demonstrated by localization of the corresponding TS.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1150–1164, June, 2007. 相似文献
992.
G. N. Kichigin 《Doklady Physics》2003,48(10):565-567
993.
Electron paramagnetic resonance and optical absorption spectra of Cr ions in cadmium phosphate glass
R.V.S.S.N. Ravikumar Ryuichi KomatsuKo. Ikeda A.V. ChandrasekharB.J. Reddy Y.P. ReddyP.S. Rao 《Solid State Communications》2003,126(5):251-253
EPR and optical absorption investigations of chromium doped cadmium phosphate glass are carried out. Crystal field, spin-Hamiltonian and bonding parameters are evaluated. From the results and analyses of the EPR and optical studies, the site symmetry of Cr3+ ion in the glass is ascribed to a distorted octahedron. The bonding parameters suggest the ionic nature of Cr3+ ion with the ligands. 相似文献
994.
C. Bréchignac Ph. Cahuzac F. Carlier C. Colliex M. de Frutos N. Kébaïli J. Le Roux A. Masson B. Yoon 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):265-268
We studied shape relaxation of nano-fractal islands,
during annealing, after their growth from antimony cluster
deposition on graphite surface. Annealing at
180°C shows evidence of an increase
of the fractal branch width with time followed by branch
fragmentation, without changing the fractal dimension. The time
evolution of the width of the arm suggests the surface
self-diffusion mechanism as the main relaxation process. With
Monte Carlo simulations, we confirmed the observed behavior.
Comparison is done with our previous results on fragmentation of
nano-fractal silver islands when impurity added to the incident
cluster promotes rapid fragmentation by surface self-diffusion
enhancement [1]. 相似文献
995.
A. I. Artem’ev D. N. Klochkov K. Oganesyan Yu. V. Rostovtsev M. V. Fedorov 《Laser Physics》2007,17(10):1213-1216
The spatial amplification of a wave in a magnetostatic undulator with noncollinear electron and laser beams is studied in the framework of the dispersion relation for single-frequency and collective regimes. The dependence of the gain on the electron beam width is estimated with regard to the spatial boundedness of the beams. The laser power threshold at which the selection with respect to the transverse velocity is possible is obtained for a free-electron laser without inversion. 相似文献
996.
V. F. Shkar’ V. P. Denisenkov A. M. Grishin A. A. Yalali S. I. Khartsev E. I. Nikolaev V. N. Sayapin 《Physics of the Solid State》2003,45(12):2334-2337
Bismuth iron garnet films prepared through electron-beam and laser-induced evaporation on (001)-oriented substrates of scandium gallium gadolinium garnet are investigated using ferromagnetic resonance. It is assumed that the additional minima observed in the angular dependence of the resonance field can be associated with the magnetic moment of bismuth ions. 相似文献
997.
998.
Numerical solution of the Slonczewski equations were used to study the motion of an individual domain wall in a two-layer uniaxial film in which the damping parameter and the gyromagnetic ratio depend on the specific layer. 相似文献
999.
N. A. Pisarenko 《Algebra and Logic》1995,33(6):386-397
Let A be a semisimple alternative superalgebra over a field of characteristic not 2, 3 which contains no sub-superalgebras of type (M1(F), M1(F)) in its decomposition into prime ideals. Then each superbimodule of A is merely an alternative A-bimodule. The case where A = (M1(F),M1(F)) produces, however, a series of indecomposable A-superbimodules. In the present article, we describe such superbimodules over an algebraically closed field.Translated fromAlgebra i Logika, Vol. 33, No. 6, pp. 689–707, November–December, 1994.Partially supported by the International Science Foundation (ISF), grant No. RB 6000. 相似文献
1000.
J. S. Yang Z. G. Chen Y. T. Hu S. N. Jiang S. H. Guo 《Archive of Applied Mechanics (Ingenieur Archiv)》2007,77(10):689-696
We study thickness-twist vibrations and waves in an unbounded, multi-sectioned piezoelectric plate of crystals with 6 mm symmetry
or polarized ceramics. An exact solution from the three-dimensional equations of piezoelectricity is obtained. Basic vibration
and wave propagation characteristics are calculated based on the solution. The results are useful in the understanding and
design of plate resonators, filters and acoustic wave sensors of ZnO, AlN and polarized ceramics. 相似文献