La-Ce-TiO2纳米光催化剂的溶胶-微波法合成、谱学表征及其活性研究

以钛酸四丁酯为原料,采用溶胶-微波法(Sol-Microwave Method)合成了镧和铈共掺型纳米TiO2粉体(La-Ce-TiO2),借助XRD、XPS和UV-Vis等测试手段对其进行了表征,并以甲基橙为模型污染物考察了掺杂量对样品光催化活性的影响规律.XRD分析表明,所得粉体均为锐钛矿相纳米TiO2,且稀土元素镧和铈掺杂后纳米TiO2特征衍射峰宽化,强度降低;XPS分析表明,镧和铈掺杂后样品表面存在大量的氧缺位;UV-Vis吸收光谱表明,所得粉体在400 nm以下均有连续宽化的吸收带,且La和Ce掺杂后样品对光的吸收显著增强,这足由于La(Ⅲ)-O荷移跃迁以及Ce(Ⅳ)f→d跃迁和Ce(Ⅳ)-O荷移跃迁所致;光催化实验表明,La和Ce共掺杂能显著提高纳米TiO2的光催化活性,其中当La(Ⅲ)和Ce(Ⅳ)掺杂量分别为2%和0.04%时,纳米TiO2光催化剂具有较高的催化活性,自然光照射下光催化氧化处理卷烟厂蒸叶车间废水,效果较好,废水COD去除率达到86.11%.     

532-nm picosecond pulse generated in a passively mode-locked Nd:YVO_4 laser

A diode-pumped continuous-wave （CW） mode-locked Nd：YVO4/KTP green laser with semiconductor saturable absorber mirror （SESAM） is demonstrated. The maximum output power of CW mode-locked green laser is obtained to be 552 mW at the incident pump power of 7.25 W, corresponding to an opticai-optical conversion efficiency of about 7.6%. The 532-nm CW mode-locked pulse duration is estimated to be about 8.4 ps with the repetition rate of 87 MHz.     

High-spin states in neutron-rich 102Mo nucleus

High-spin states in neutron-rich 102Mo nucleus have been studied by measuring the prompt γ-rays in the spontaneous fission of 252Cf. The previous level scheme has been updated and some new levels and transitions are identified. The one-phonon γ-band is expanded and a band head level of the two-phonon γ-band is proposed. The systematic characteristics of yrast bands, one-phonon γ-bands, two-phonon γ-bands and quasi-particle bands in 102Mo, 104Mo and 106Mo are discussed.     

Bulk-sensitive spectroscopic studies on noncentrosymmetric superconducting system of Mg–Ir–B

We present the data from ultrahigh-resolution laser-excited photoemission spectroscopy on a newly discovered noncentrosymmetric superconductor Mg₁₀Ir₁₉B₁₆. We observed the evidences for the opening of superconducting gap where numerical fittings show that isotropic s-wave model can satisfactorily explain the behavior of spectra near the Fermi level. We also present the valence band photoemission spectrum and B K fluorescence spectrum to discuss the basic electronic structure of Mg₁₀Ir₁₉B₁₆.     

6.17-W continuous wave operation of a 2132-nm c-cut Tm,Ho:YAP pumped by a laser diode of 794.3 nm

Continuous wave (CW) operation of a c-cut Tm (5 at %), Ho (0.3 at %):YAP laser at 2132 nm wavelength were reported in this paper. In the temperature of 77 K, the Tm,Ho:YAP crystal was double end-pumped by a 21.4 W fiber-coupled laser diode (LD) at the center wavelength of 794.3 nm. Different resonator lengths and output couplers for the total pump power were tried. The resonator length was 205 mm, and the maximum CW output power of 6.17 W was acquired, corresponding to an optical-optical conversion efficiency of 28.8% and a slope efficiency of 35.6%.     

Facile method for CLSM imaging unfunctionalized Au nanoparticles through fluorescent channels

The microscopic visualization of metal nanoparticles has become a useful tool for the investigation of their applications in cell labeling and the study of their bio-effects. In the current study, we have developed a facile method with confocal laser scanning microscope (CLSM) to observe unfunctionalized Au nanoparticles through fluorescent channels. The sharp reflected signal and photostable property of the metal nanoparticles makes the present method very ideal for fluorescent co-localization, real-time imaging, and further quantitative analysis. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users. Lan Yuan and Wei Wei contributed equally to this study.     

土壤源热泵在合肥某工程中的应用

介绍了土壤源热泵的工作原理,探讨了土壤源热泵空调应用于中央空调系统的设计方法,以及其主要部件地热换热器的埋管方式、结构、管材、运行等特点。选取几种常用的冷热源系统与土壤源热泵系统进行比较分析,参考合肥地区的能源价格,计算各方案的运行成本,用动态费用年值法对各方案的经济性进行了评价。     

利用近红外光谱检测多层组织血氧饱和度的研究

利用近红外光谱无创检测生物组织血氧饱和状态,是一种极富研究和应用前景的检测技术,在临床检测中被广泛应用.但常规临床检测应用于指端仅反映局部血氧饱和度信息,在使用中具有局限性,信号的可信度也存在质疑.该文提出了一种采用反射式脉搏血氧饱和度检测技术检测生物多层组织氧合状况的新方法,该方法通过调节入射光强以适应解剖学中生物组织多层结构的检测.应用该方法针对手指结构的实验结果表明,随着入射光强的改变,反映血氧饱和状态的光电脉搏波信号有显著变化.结合手指解剖学分析表明,光电脉搏波信号的变化与手指的多层面组织结构相对应,反映不同层面血氧饱和状态.这一特点表明,通过此法可以针对生物组织的多层结构进行测量.     

Image registration based on matrix perturbation analysis using spectral graph

We present a novel perspective on characterizing the spectral correspondence between nodes of the weighted graph with application to image registration. It is based on matrix perturbation analysis on the spectral graph. The contribution may be divided into three parts. Firstly, the perturbation matrix is obtained by perturbing the matrix of graph model. Secondly, an orthogonal matrix is obtained based on an optimal parameter, which can better capture correspondence features. Thirdly, the optimal matching matrix is proposed by adjusting signs of orthogonal matrix for image registration. Experiments on both synthetic images and real-world images demonstrate the effectiveness and accuracy of the proposed method.     

Performance of dispersed Rayleigh interferometer on the active cophasing and alignment testbed

We report the laboratory experiment on a segmented mirror testbed that shows the use of a dispersed Rayleigh interferometer to phase segmented mirrors.Segment alignment of tip-tilt is fulfilled by overlapping diffraction pattern centroids of the three individual segments on the focal plane.A spherical interferometer is introduced to evaluate the performance of piston, tip-tilt sensing, and control closed-loop, and finally a total residual root-mean-square (RMS) surface error of about 45 nm is achieved, in which a typical error of about 20 nm is contributed by piston.These results demonstrate that the dispersed Rayleigh interferometer can successfully sense the piston of segmented mirrors and be used in phasing segmented telescopes under extensive studies.