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941.
G. Ya. Gerasimov 《High Energy Chemistry》2002,36(6):370-373
The behavior of a hydrogen–air mixture under the action of ionizing radiation was studied. A kinetic model for radiation-chemical processes in the H2–O2–N2 system was constructed, and the effects of the main parameters of radiolysis on shifting its flammability limits were analyzed. It was found that, under normal conditions (p = 0.1 MPa, T
0 = 300 K), the ignition of the stoichiometric mixture began at a radiation intensity of about 0.1 kGy/s. The induction period of the chain H2 oxidation reaction shortened with increasing radiation dose rate and pressure. 相似文献
942.
943.
F. T. Pozharskii V. Ts. Bukhaeva A. M. Simonov L. Ya. Bakhmet O. M. Aleksan'yan 《Chemistry of Heterocyclic Compounds》1969,5(2):246-247
2-[-(5-halogenofur-2-yl)vinyl]benzimidazoles (I) have been synthesized by the condensation of o-phenylenediamine with 5-halogeno-fur-2-ylacroleins or of 2-methylbenzimidazole with 5-halogenofurfurals. The methiodides of the 1-methyl-substituted derivatives ofI readily react with secondary amines (piperidine, dimethylamine)giving methiodides of 2-[-(5-dialkylaminofur-2-yl)vinyl]-1-methylbenzimidazoles. 相似文献
944.
Ya. F. Oshis A. A. Anderson M. V. Shimanskaya 《Chemistry of Heterocyclic Compounds》1982,18(7):740-745
The transformations of 1,3-diaminopropane and 3-amino-1-propanol under pulse conditions over tungsten trioxide in an inert atmosphere at 300–500 °C were investigated. The transformation of 1,3-diaminopropane leads to the formation of saturated pyrimidine bases; the maximum selectivity of the formation of hexahydropyrimidine bases at 300 °C is 60%, while the selectivity of the formation of tetrahydropyrimidine bases is 20% (400 °C). In the case of 3-amino-1-propanol the overall yield of heterocyclic bases was less than 5%, and piperazine and pyrazine derivatives were observed as the cyclic products; the formation of pyrimidine bases was not observed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 967–973, July, 1982. 相似文献
945.
The Hulthen, Kohn and Schwinger-type variational principles for the phase of true three particle scattering is formulated using the method of the hyperspherical basis. The optical theorem for such processes is proved. 相似文献
946.
Conclusions The effect of the asymmetry of the loading cycle on the fatigue strength of HDPE subjected to biaxial tension has been studied. An increase in the acuteness of the cycle leads to an increase in the durability of the material. Under conditions of cyclic loading, the material became embrittled as the duration of the experiment was extended. The effect of various different ratios between the principal stresses on the fatigue strength of HDPE has been investigated. It has been shown that the form of the isochronous boundary curves depends on the duration of the experiment. It was established that the mechanism of HDPE fracture changes depended on the duration of the loading. The accumulation of defects, when an experiment was of average or longer duration, built up at a greater rate than would have been predicted by a linear rule for summation.M. I. Kalinin Leningrad Polytechnic Institute. The "Plastpolimer" Okhtinsk Scientific Manufacturing Association, Leningrad. Translated from Mekhanika Polimerov, No. 1, pp. 35–40, January–February, 1977. 相似文献
947.
Conclusions 1. Experiments have been performed on biaxial stretching of HDPE over a wide range in ratios of the principal stress components, strain rates, and temperature. The character of change in the limiting characteristics of HDPE are different in different temperature regions.2. The limiting resistance of HDPE in the flat stressed state for T=const and vi=const is described satisfactorily by the Malmeister and Gol'denblat-Kopnov criteria.3. Prediction of the limiting resistance of HDPE should be carried out within limited temperature ranges, in which similarity of strain diagrams, a similar character of structural changes in the material (accumulation of damage), and identical character of change in its limiting characteristics are observed.Okhtinsk "Plastpolimer" Scientific and Production Union, Leningrad. Translated from Mekhanika Polimerov, No. 2, pp. 247–254, March–April, 1977, 相似文献
948.
Scalar scattering of light on the 3p and 3s subshells of the argon atom (Stokes scattering) and anti-Stokes scattering on the excited 4p and 4s states of argon are examined in the Hartree-Fock approximation. The calculation is made in a velocity form and in a length form. It is shown that the value in the r form is 1.5–2 times greater than in the form.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 36–42, January, 1977. 相似文献
949.
Xing‐Yun Chai Zheng‐Ren Xu Hong‐Yan Ren Hai‐Ming Shi Ya‐Nan Lu Fei‐Fei Li Peng‐Fei Tu 《Helvetica chimica acta》2007,90(11):2176-2185
Eight new benzoylated gentisyl alcohol (=2‐(hydroxymethyl)benzene‐1,4‐diol) glucosides, itosides A–H ( 1 – 8 ), together with the new pyrocatechol (=benzene‐1,2‐diol) glycoside itoside I ( 9 ) were isolated from the bark and twigs of Itoa orientalis (Flacourtiaceae). In itosides B–D ( 2 – 4 ), the gentisyl alcohol moiety was esterified by 1‐hydroxy‐6‐oxocyclohex‐2‐ene‐1‐carboxylic acid, while itosides E–H ( 5 – 8 ) contained instead an additional 2‐hydroxybenzoic acid moiety. The compounds were accompanied by the known derivatives 4‐hydroxytremulacin ( 10 ), poliothyrsoside ( 11 ), poliothyrsin ( 12 ), homaloside D ( 13 ), tremulacin, and pyrocatechol β‐D ‐glucopyranoside. The structures of the new compounds were elucidated by spectral and chemical methods. 相似文献
950.
自从1963年爆炸法合成纳米金刚石[1]以来,纳米金刚石已在科研和工业领域得以广泛应用.但是工业合成的纳米金刚石粉由于其工艺的限制存在一些杂质,其中主要包括纳米石墨、非晶碳和爆炸过程中产生的金属离子.因此,在实际科研工作前对纳米金刚石粉进行纯化处理就显得十分重要,以往的研究表明不同的处理方法各有利弊[2].在以下的研究中,我们采用盐酸消解的方法对商业购买的纳米金刚石粉进行纯化处理,通过对比纯化处理前后的IR、Raman以及ICP表征,分析讨论了酸处理方法的纯化效果. 相似文献