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121.
Jun Hua YU Xue Song WANG Bao Wen ZHANG* Yi CAO Technical Institute of Physics Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2002,13(10)
Porphyrin derivatives attract much more interest in photodynamic therapy (PDT). Their importance as therapeutic drugs and targeting agents has been widely recognized1, and many of the efforts have been put towards crafting new porphyrin-based molecular entities to achieve enhanced tumor localization, better tissue penetration and increased singlet oxygen quantum yield2. The states of porphyrins in tissue models such as micelles, lipid bilayers are extensively investigated focusing more or l… 相似文献
122.
Wei‐Ling Wang Jian‐Wei Xu Yee‐Hing Lai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4154-4164
Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and 1H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu2+, Co2+, Ni2+, Zn2+, Mn2+, and Ag+ ions. In contrast, only Cu2+, Co2+, and Ni2+ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu2+, Co2+, and Ni2+ ions toward P7 are of the order of 106 M?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006 相似文献
123.
为了科学构建原油价格波动与国民经济发展的关系,在借鉴国内外专家学者相关模型基础上,考虑不同国民经济指标对油价波动的时滞反馈等因素,构建油价波动对国民经济影响模型.利用原油价格波动对国民经济发展的动态模型,对模型的各部分关系系数进行确定,最后根据所得到的模型对国民经济影响进行实际分析与预测,并得出规避油价波动影响风险的措施. 相似文献
124.
利用不同能量的质子在大气环境中辐照拟南芥的含水种子,能量从1.1MeV到6.5MeV.根据模拟计算结果,相应能量的离子对种子的损伤区域分别为胚的浅层、胚的一半和整个胚.本实验中,具有较高能量的质子可以完全均匀地作用于拟南芥生长、发育及遗传密切相关的胚茎端分生组织,而能量较低的质子则不能直接作用于茎端分生组织.实验所用质子注量范围为4×109ions/cm2—1×1014ions/cm2.实验结果显示,虽然拟南芥种子的发芽率和幼苗存活率随离子注量增加都呈现下降的趋势,但对应于不同的胚损伤区域,即在不同的入射质子能量条件下,注量曲线具有各自的特征.实验结果显示,拟南芥种子中除了胚茎端分生组织作为对离子辐照敏感的辐射主靶外,茎端分生组织之外的胚区域可能作为离子辐射次靶,影响到最终的辐射生物学效应.
关键词:
离子辐照
拟南芥
胚区域
生物效应 相似文献
125.
126.
By introducing a four-layer step-index waveguide modeling, the characteristics of long-period fiber grating (LPFG) with an nm-thick film overlay, which has higher refractive index than that of fiber cladding are investigated in detail. The influence of both the overlay thickness and refractive index on the tuning ability of LPFG is analyzed. The numerical results demonstrate that spectral response of LPFG is divided into three distinct regions as the overlay deposition increases and the shift of resonant wavelength is drastic in some special thickness range. In conjunction with higher-order cladding mode coupling and fiber cladding etching, the sensitivity of LPFG to the overlay refractive index is enhanced significantly and over 120 nm resonant wavelength tunable range is achieved. 相似文献
127.
This paper discusses a kind of optimization problem with linear complementarity constraints, and presents a sequential quadratic
programming (SQP) algorithm for solving a stationary point of the problem. The algorithm is a modification of the SQP algorithm
proposed by Fukushima et al. [Computational Optimization and Applications, 10 (1998),
5-34], and is based on a reformulation of complementarity condition as a system of linear equations. At each iteration,
one quadratic programming and one system of equations needs to be solved, and a curve search is used to yield the step size.
Under some appropriate assumptions, including the lower-level strict complementarity, but without the upper-level strict
complementarity for the inequality constraints, the algorithm is proved to possess strong convergence and superlinear convergence.
Some preliminary numerical results are reported. 相似文献
128.
本文在M ogens B ladt和T ina H av iid R ydberg无市场假设,仅利用价格过程的实际概率的期权保险精算定价模型的基础上,得出了标的资产服从几何分数布朗运动的欧式期权定价公式,并说明了几何布朗运动是本文的一种特殊情况. 相似文献
129.
对二维平面系统的二维系统的中心焦点区分问题 ,I l'yashenko曾建议一个算法 ,本文给出此法的详细证明 .据此 ,我们讨论了区分问题在 Arnold意义下的代数可解性与不可解性 相似文献
130.