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51.
According to a multiphase mixture theory, we have mathematically developed a multiphysical model with chemoelectromechanical coupling considerations, termed the multieffect‐coupling electric‐stimulus (MECe) model, to simulate the responsive behavior of electric‐sensitive hydrogels immersed in a bath solution under an externally applied electric field. For solutions of the MECe model consisting of coupled nonlinear partial differential governing equations, a meshless Hermite–Cloud method with a hierarchical iteration technique has been used for a one‐dimensional steady‐state analysis of a hydrogel strip. The computed results are compared with the experimental data, and there is very good agreement. Simulations within the domains of both hydrogels and surrounding solutions also present distributions of the ionic concentrations and electric potential as well as the hydrogel displacement. The effects of various physical parameters on the response behavior of electric‐stimulus responsive hydrogels are discussed in detail. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1514–1531, 2004 相似文献
52.
Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products. 相似文献
53.
Ming Zhao WANG Guan Liang CAI Ling XIA Jun Jian YAO Hong Yan CHEN Zhao Xing MENG Bo Li LIUDepartment of Chemistry Beijing Normal University Beijing Chemical Defense Institute PLA Beijing 《中国化学快报》2004,15(4):495-497
The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents. 相似文献
54.
Jensen and Toft 8 conjectured that every 2‐edge‐connected graph without a K5‐minor has a nowhere zero 4‐flow. Walton and Welsh 19 proved that if a coloopless regular matroid M does not have a minor in {M(K3,3), M*(K5)}, then M admits a nowhere zero 4‐flow. In this note, we prove that if a coloopless regular matroid M does not have a minor in {M(K5), M*(K5)}, then M admits a nowhere zero 4‐flow. Our result implies the Jensen and Toft conjecture. © 2005 Wiley Periodicals, Inc. J Graph Theory 相似文献
55.
多级制造系统是现代制造业的主要加工方式,系统的每一级的加工速度和加工周期是系统设计的主要决策变量,正确确定这两个变量是系统得到优化的主要目标。本文导出了系统优化的基本模型,它包括系统各级的生产时间、等待时间、生产速度、生产成本以及系统的循环时间、总成本、产品利润和利润率等,并给出了一个应用实例。 相似文献
56.
57.
Double-diffusive convection due to a cylindrical source submerged in a salt-stratified solution is numerically investigated
in this study. For proper simulation of the vortex generated around the cylinder, a computational domain with irregular shape
is employed. Flow conditions depend strongly on the thermal Rayleigh number, Ra
T
, and the buoyancy ratio, R
ρ. There are two types of onset of instability existing in the flow field. Both types are due to either the interaction of
the upward temperature gradient and downward salinity gradient or the interaction of the lateral temperature gradient and
downward salinity gradient. The onset of layer instability due to plume convection is due to the former, whereas, the onset
of layer instability of layers around the cylinder is due to the latter. Both types can be found in the flow field. The transport
mechanism of layers at the top of the basic plume belongs to former while that due to basic plume and layer around the cylinder
are the latter. The increase in Ra
T
reinforces the plume convection and reduces the layer numbers generated around the cylinder for the same buoyancy ratio.
For the same Ra
T
, the increase of R
ρ suppresses the plume convection but reinforces the layers generated around the cylinder. The profiles of local Nusselt number
reflects the heat transfer characteristics of plume convection and layered structure. The profiles of averaged Nusselt number
are between the pure conduction and natural convection modes and the variation is due to the evolution of layers.
Received on 13 September 1996 相似文献
58.
59.
M.-K. Chen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,21(1):13-18
We examine the influence of relativistic and QED effects on the existence of the 1,3P
o
H- resonances between n
= 2 and 3 hydrogen thresholds, the relativistic and QED corrections and the coupling effects between the high singlet and triplet
states are considered as first-order perturbations. We firstly obtain accurate non-relativistic resonant energies and widths
of fifteen 1P
o
resonances, and fifteen 3P
o
resonances. The fifteen 1P
o
resonances are classified to be
3
(2, 0)
-
n
( 4 ?
n
? 12) and
3
(1, 1)
+
n
( 3 ?
n
? 8). The fifteen 3P
o
resonances are classified to be
3
(2, 0)
+
n
( 3 ?
n
? 12) and
3
(1, 1)
-
n
( 4 ?
n
? 8). We found there exist six Feshbach resonances for
3
(2, 0)
-
n
(1P
o
) series, four Feshbach resonances for
3
(1, 1)
+
n
(1P
o
) series, seven Feshbach resonances for
3
(2, 0)
+
n
(3P
o
) series, and three Feshbach resonances for
3
(1, 1)
-
n
(1P
o
) series.
Received 22 February 2002 Published online 24 September 2002 相似文献
60.