全文获取类型
收费全文 | 71490篇 |
免费 | 13875篇 |
国内免费 | 7562篇 |
专业分类
化学 | 66045篇 |
晶体学 | 981篇 |
力学 | 2715篇 |
综合类 | 487篇 |
数学 | 6249篇 |
物理学 | 16450篇 |
出版年
2024年 | 130篇 |
2023年 | 751篇 |
2022年 | 1424篇 |
2021年 | 1611篇 |
2020年 | 2609篇 |
2019年 | 3937篇 |
2018年 | 2303篇 |
2017年 | 1969篇 |
2016年 | 4940篇 |
2015年 | 5164篇 |
2014年 | 5495篇 |
2013年 | 6625篇 |
2012年 | 6058篇 |
2011年 | 5278篇 |
2010年 | 5175篇 |
2009年 | 5019篇 |
2008年 | 4704篇 |
2007年 | 3924篇 |
2006年 | 3552篇 |
2005年 | 3398篇 |
2004年 | 2887篇 |
2003年 | 2559篇 |
2002年 | 3397篇 |
2001年 | 2631篇 |
2000年 | 2169篇 |
1999年 | 1153篇 |
1998年 | 639篇 |
1997年 | 481篇 |
1996年 | 492篇 |
1995年 | 394篇 |
1994年 | 375篇 |
1993年 | 338篇 |
1992年 | 245篇 |
1991年 | 240篇 |
1990年 | 167篇 |
1989年 | 162篇 |
1988年 | 111篇 |
1987年 | 81篇 |
1986年 | 72篇 |
1985年 | 78篇 |
1984年 | 57篇 |
1983年 | 36篇 |
1982年 | 23篇 |
1981年 | 18篇 |
1980年 | 18篇 |
1979年 | 7篇 |
1977年 | 3篇 |
1959年 | 3篇 |
1957年 | 6篇 |
1936年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
针对无线传感器网络中节点因干扰过大导致重传能耗增加, 进而节点过早失效、网络生命期缩短的问题, 根据网络拓扑信息和路由信息设计节点的负载模型, 从而构建了节点的生命期模型. 然后利用博弈论将路径增益、交叉干扰和节点生命期等性能参数融入到效益函数中, 构建信道分配博弈模型. 理论分析证明该博弈模型存在纳什均衡. 进而运用最佳回应策略, 在所构建的信道分配博弈模型的基础上, 设计了一种优化网络生命期的抗干扰信道分配算法. 该算法使节点在选择信道时避免与网络中交叉干扰较大的节点和生命期较小的节点使用相同信道, 实现干扰小、能耗低且均衡的信道选择. 理论分析与仿真结果证明该算法最终能够快速地收敛到纳什均衡, 且具有较小的信息复杂度, 从而减小算法本身的通信能耗. 同时, 该算法具有良好的抗干扰性和信道均衡性, 能够有效地延长网络生命期. 相似文献
992.
针对矿山井下的特殊环境,提出了一种基于ZigBee技术的煤矿井下预警防爆监测系统,实现煤矿井下环境信息和人员位置的实时监测,以减少事故发生率;井下系统采用CC2530+CC2401芯片作为ZigBee节点的核心,井下主控制器通过CAN总线实现与井上上位机的通信;上位机使用Labview软件实现程序编程,实时显示煤矿井下采集到的CH4、CO、O2浓度、温湿度和人员坐标等参数并进行Web发布;该系统结合了基于模糊逻辑算法的预警技术、基于物理隔离的防爆技术,同时提出了一种融合LQI的RSSI加权质心算法;实验证明该系统运行稳定可靠,提高了人员定位的精度,具有良好的应用前景。 相似文献
993.
Xiaodong Xu Lifen Zhang Jian Zhou Jun Wang Jinghua Yin Jinliang Qiao 《Journal of Macromolecular Science: Physics》2015,54(1):32-44
The thermal behaviors of glycidyl methacrylate (GMA)-grafted polypropylene (PP) (PP-g-GMA) with two different grafting degrees, namely, GPP1 and GPP2, were investigated by differential scanning calorimetry (DSC), polarized optical microscopy (POM), wide-angle X-ray diffraction (WAXD), dynamic mechanical analysis (DMA), and thermogravimetrical analysis (TGA). DSC results suggested that the GMA grafted PP exhibited higher crystallization temperature Tc, higher melting temperature Tm, and higher crystallinity compared with the neat PP. The isothermal crystallization kinetics was analyzed with the Avrami equation and the total crystallization activation energy was calculated. It was concluded that the crystallization processes of PP and the grafted PP were controlled by nucleation and the values of the crystallization activation energy of PP and the grafted PP were almost identical. POM results suggested that the GMA grafted PP exhibited smaller spherulites size compared with the neat PP. WAXD patterns indicated that the neat PP encouraged the formation of γ phase, compared with the grafted PP, during the crystallization process. DMA results showed that melt grafting did not induce a clear effect on the γ-transition and β-transition of the amorphous phase but resulted in a decrease in mobility of the PP chains in the crystals. TGA curves suggested that the melt grafting slightly improved the thermal stability of PP. 相似文献
994.
Black phosphorus saturable absorber for ultrafast mode‐locked pulse laser via evanescent field interaction 下载免费PDF全文
Kichul Park Junsu Lee Young Tack Lee Won‐Kook Choi Ju Han Lee Yong‐Won Song 《Annalen der Physik》2015,527(11-12):770-776
Black phosphorus, or BP, has found a lot of applications in recent years including photonics. The most recent studies have shown that the material has an excellent optical nonlinearity useful in many areas, one of which is in saturable absorption for passive mode‐locking. A direct interaction scheme for mode‐locking, however, has a potential to optically cause permanent damage to the already delicate material. Evanescent field interaction scheme has already been proven to be a useful method to prevent such danger for other 2‐dimensional nanomaterials. In this report, we have utilized the evanescent field interaction to demonstrate that the optical nonlinear characteristics of BP is sufficiently strong to use in such an indirect interaction method. The successful demonstration of the passive mode‐locking operation has generated pulses with the pulse duration, repetition rate, and time bandwidth product of 2.18 ps, 15.59 MHz, and 0.336, respectively. 相似文献
995.
Calum Williams Yunuen Montelongo Jaime Oscar Tenorio‐Pearl Andrea Cabrero‐Vilatela Stephan Hofmann William I. Milne Timothy D. Wilkinson 《固体物理学:研究快报》2015,9(2):125-129
Digital holography requires arrays of small reconfigurable elements to achieve complex reconstruction of the hologram with common systems based on pixels utilizing liquid crystal on silicon (LCoS) technology. The backplane of a typical pixel element is potentially underutilized and thus relatively large physical areas exist in which information can be stored and exploited to give additional functionality to pixel elements. Polarisation and wavelength dependent optical properties can be achieved in small areas using the plasmonic effects of optical antennae. The integration of LCs with optical antennae‐based plasmonic holograms allows active modulation of the far field pattern. The work here demonstrates the concept that conventional LCoS pixel elements can be greatly enhanced with the integration of plasmonic holograms, composed of optical antennae patterned on the surface, giving rise to new levels of modulation capability for holographic pixel elements. Using LCs, polarisation dependent effects in plasmonic holograms can be switched. ‘Engineered pixels', with sub‐wavelength multiplexing over both polarisation and wavelength, can increase the channel capacity of a typical LC display device. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
996.
Yingyot Poo‐arporn Surachai Thachepan Rungtiva Palangsuntikul 《Journal of synchrotron radiation》2015,22(1):86-90
Evidence of internal sulfate attack in field exposure was demonstrated by the damaged interior wall of a three‐year‐old house situated in Nakhon Ratchasima Province, Thailand. Partial distension of the mortar was clearly observed together with an expansion of a black substance. Removal of the black substance revealed a dense black layer. This layer was only found in the vicinity of the damaged area, suggesting that this black material is possibly involved in the wall cracking. By employing synchrotron‐based X‐ray photoelectron spectroscopy (XPS) and X‐ray absorption near‐edge structure (XANES) techniques, the unknown sample was chemically identified. The S 2p and O 1s XPS results mutually indicated the existence of sulfate species in the materials collected from the damaged area. The XANES results indicated the presence of ferrous (II) sulfate, confirming sulfate‐induced expansion and cracking. The sulfate attack in the present case appeared to physically affect the structure whereas the chemical integrity at the molecular level of the calcium silicate hydrate phase was retained since there was a lack of spectroscopic evidence for calcium sulfate. It was speculated that internal sulfate probably originated from the contaminated aggregates used during the construction. The current findings would be beneficial for understanding the sulfate‐attack mechanism as well as for future prevention against sulfate attack during construction. 相似文献
997.
许多水域含有过量的硝酸根,会诱发许多问题。采用微机电系统工艺,制备出一种基于铂叉指微电极阵列的硝酸根离子(NO-3)检测微传感电极。通过电化学恒电位沉积法在铂叉指微电极阵列上修饰,得到多孔、簇状铜敏感膜。采用线性扫描伏安电化学检测方法,考察该微传感电极对NO-3的响应性能,在0~2mg/L浓度范围内,线性度为0.999,灵敏度为-3.15μA·L·mg-1。在相同沉积修饰条件下,叉指微电极比同等敏感面积(1mm2)的圆盘微电极表现出更强的催化活性和更高的灵敏度,分析其原因,认为主要是叉指微电极的结构和边缘效应造成的。 相似文献
998.
999.
研究了不同脉冲次数强流脉冲电子束表面改性对CuFe10合金组织及性能的影响。强流脉冲电子束处理CuFe10合金的重熔表面出现了火山坑和直径为100nm到1μm的富铁球,表明了强流脉冲电子束处理CuFe10合金表面发生了液相分离。强流脉冲电子束脉冲轰击30次后,CuFe10合金表面的显微硬度与耐蚀性能均得到显著改善,主要是由于强流脉冲电子束轰击处理CuFe10合金表层引发的快速熔凝过程中表面发生了液相分离及晶粒细化的缘故。 相似文献
1000.