Using broadband absorption spectroscopy to measure concentration of sulfur dioxide

A linear relationship between concentration of sulfur dioxide (SO₂) and optical parameter (OP) is established using the Beer–Lambert law. The SO₂ measuring system is set up to measure the concentration of sulfur dioxide in the wavelength range 275–315 nm. Experimental results indicate that the detection limit of the sulfur dioxide measuring system is below 0.2 ppm per meter of path length, and the measurement precision is better than ±1%. The proposed SO₂ measuring method features limited interference from other gases and dust, and high stability and short response time.     

Synergistic effect of silver seeds and organic modifiers on the morphology evolution mechanism of silver nanoparticles

Triangular, truncated triangular, quadrangular, hexagonal, and net-structured silver nanoplates as well as decahedral silver nanoparticles were manipulatively prepared starting from silver nitrate and silver seeds in the presence of poly(ethylene glycol) (PEG), poly(N-vinyl pyrrolidone) (PVP), and Tween 80 at room temperature, respectively. UV-vis spectroscopy, XRD, HRTEM, SAED, and FTIR were used to illustrate the crystal growth process and to characterize the resultant silver nanoparticles. It was found that the silver seeds and organic modifiers synergistically affected the morphology evolution of the silver nanoparticles. The co-presence of silver seeds and PEG was beneficial to the formation of triangular and truncated triangular silver nanoplates; the silver seeds and PVP favored the formation of polygonal silver nanoplates; the silver seeds and Tween 80 preferred to the formation of net-structured silver plates. The morphology evolution of the resultant silver nanoparticles was correlated with the crystallinity of the silver seeds and the adsorption ability of the organic modifiers on the crystal surfaces.     

An asymmetric full velocity difference car-following model

This paper presents a car-following model that considers the asymmetric characteristic of the velocity differences of the vehicles in a traffic stream. The problems of the prevalent general force (GF) model and the full velocity difference (FVD) model were solved. Furthermore, the optimal velocity (OV) model, the GF model, and the FVD model are proved to be the special cases of the proposed asymmetric full velocity difference (AFVD) model. The mathematical model is presented, followed by simulation analysis which demonstrates the properties of the AFVD model.     

The effect of 3-aminopropyltrimethoxysilane on the formation of NiFe2O4/SiO2 nanocomposites

NiFe₂O₄/SiO₂ nanocomposites were prepared using a sol–gel method with the addition of 3-aminopropyltrimethoxysilane (APS). Different phases and morphologies of NiFe₂O₄/SiO₂ nanocomposites were obtained when different amounts of APS were used. The structural properties of the products were examined by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Sheet-like morphology was observed at higher molar ratio of APS to NiFe₂O₄, while spherical NiFe₂O₄/SiO₂ nanoparticles separated from each other were formed at lower molar ratio of APS to NiFe₂O₄. The magnetic properties of the nanocomposites were also investigated, indicating that the interparticle interactions exhibit strong dependence on the molar ratio of APS to NiFe₂O₄.     

Structural and optical properties of ZnO thin films on (111) CaF2 substrates grown by magnetron sputtering

ZnO thin films were grown on (111) CaF₂ substrates by magnetron sputtering at room temperature. Structural and optical properties of the ZnO thin films were studied. XRD analysis showed that the ZnO thin films had the (002) preferential orientation. The transmittance of ZnO thin films was over 80% in the visible range. The optical band gap of the ZnO thin films was 3.26 eV. The optical constants (n,k)$(n,k)$ of the ZnO thin films in the wavelength range 300–1000 nm were obtained by infrared spectroscopic ellipsometry measurement. PL spectra of ZnO thin films showed strong UV near-band-edge emission peak at 376.5 nm and weak visible red emission at 643.49 nm using He–Cd laser as the light source, using a synchrotron radiation light source PL spectra showed three emission peak at 320 nm, 410 nm and 542 nm respectively.     

Phase transformation in Sm2O3 at high pressure: In situ synchrotron X-ray diffraction study and ab initio DFT calculation

Sm₂O₃ was compressed at room temperature up to 44.0 GPa and then decompressed back to ambient pressure. In situ X-ray diffraction was used to monitor the structural changes in the sample. A cubic to hexagonal phase transformation was observed in Sm₂O₃ for the first time. After decompression back to ambient pressure, the hexagonal phase was not quenchable and transformed to a monoclinic phase. Ab initio Density- Functional-Theory (DFT) calculations were performed to obtain theoretical data for comparison with the experimental results and elucidation of the transformation mechanism. A possible phase transformation mechanism that is consistent with the experimental results and theoretical calculations is proposed.     

All-optical dual-direction half-subtracter based on sum-frequency generation

We report a simple method to realize all-optical dual-direction half-subtracter at 40 Gb/s based on sum-frequency generation (SFG) using only one periodically poled lithium niobate (PPLN) waveguide. The SFG process generates the Borrow outputs and the combination of the outputs from PPLN after SFG results in the Difference. The operation performance of the proposed scheme is simulated, including eye diagrams, Q-factor, extinction ratio, and tunability. For different input optical powers, the length of the PPLN waveguide is optimized.     

Silica waveguide ring resonators with multi-turn structure

Optical waveguide ring resonator is the basic element of resonator integrated optic gyro (RIOG). In this paper, we report a novel configuration of optical waveguide ring resonator using a multi-turn structure. The characteristic of the light propagating across the crossed waveguides is analyzed using the finite difference beam propagation method. The relationship between the propagation loss and the intersection angle for arbitrary intersecting angles has been analyzed. Some crossed waveguides are fabricated in silica waveguides to verify the theoretical results. On this basis, the influences of the loop numbers and the excess loss of the crossed waveguide on the limited sensitivity of the RIOG have been analyzed. There is a critical intersection angle for certain resonator, only when the intersection angle is bigger than the critical angle, the gyro sensitivity can be improved by increasing the loop numbers. This will be helpful to how to determine the optimum length in resonator for its application in RIOG.     

A global design of high power Nd-Yb co-doped fiber lasers

A global optimization method - niche hybrid genetic algorithm (NHGA) based on fitness sharing and elite replacement is applied to optimize Nd³⁺-Yb³⁺ co-doped fiber lasers (NYDFLs) for obtaining maximum signal output power. With a objective function and different pumping powers, five critical parameters (the fiber length, L; the proportion of pump power for pumping Nd³⁺, η; Nd³⁺ and Yb³⁺ concentrations, N_Nd and N_Yb and output mirror reflectivity, R_out) of the given NYDFLs are optimized by solving the rate and power propagation equations. Results show that dividing equally the input pump power among 808 nm (Nd³⁺) and 940 nm (Yb³⁺) is not an optimal choice and the pump power of Nd³⁺ ions should be kept around 10-13.78% of the total pump power. Three optimal schemes are obtained by NHGA and the highest slope efficiency of the laser is able to reach 80.1%.