染料敏化TiO2/WO3薄膜电池的光电变色

用光电化学方法研究了染料Ru(П) (4, 4′di COOEt 2, 2′bpy)2 (2, 2′bpy 4, 4′di CONH L tyrosineethylester) (PF6)2 (简写为Ru4)敏化TiO2 纳米结构电极的光电转换过程,同时,在导电玻璃上电沉积得到WO3 薄膜.结果表明,染料敏化的TiO2 多孔膜具有光电转换性能, WO3 薄膜具有良好的电致变色效应,将前者与电沉积得到的WO3 薄膜组成电池,在白光照射下可产生显著的颜色变化,有望用于自供电源的电色灵巧窗(Self poweredsmartwindow).     

Plasmon-Enhanced Electrochemiluminescence at the Single-Nanoparticle Level

Plasmon-enhanced electrochemiluminescence (ECL) at the single-nanoparticle (NP) level was investigated by ECL microscopy. The Au NPs were assembled into an ordered array, providing a high-throughput platform that can easily locate each NP in sequential characterizations. A strong dependence of ECL intensity on Au NP configurations was observed. We demonstrate for the first time that at the single-particle level, the ECL of Ru(bpy)₃²⁺-TPrA was majorly quenched by small Au NPs (<40 nm), while enhanced by large Au ones (>80 nm) due to the localized surface plasmon resonance (LSPR). Notably, the ECL intensity was further increased by the coupling effect of neighboring Au NPs. Finite Difference Time Domain (FDTD) simulations conformed well with the experimental results. This plasmon enhanced ECL microscopy for arrayed single NPs provides a reliable tool for screening electrocatalytic activity at a single particle.     

Synthesis of FeS2/CoS heterostructure microspheres as anodes for high-performance Li-ion batteries

Journal of Solid State Electrochemistry - FeS2/CoS and FeS2/CoS/C composites were synthesized by solvothermal method and following vapor phase vulcanization at mild temperature with binary oxide...     

Efficient and mild swern oxidation using a new sulfoxide and bis(trichloromethyl)carbonate

A new type of sulfoxide, 4-(2-(2-(methylsulfinyl) ethyl)-4-nitrophenyl)- morpholine (I), was designed and prepared in good yield. Upon the combination of I and bis(trichloromethyl)carbonate, the Swern oxidation of primary and secondary alcohols was significantly promoted under mild conditions, which afforded the corresponding aldehydes or ketones in good yields. It is noteworthy that the reoxidation of the isolated by-product sulfide V could be further recycled in Swern oxidation.     

Dimethoxycarbonyl Groups Surrounding a Symmetric Diaminobistetrazole Ring: Exploring New Green Energetic Materials

A novel oxygen‐containing dimethoxycarbonyl diaminobistetrazole ( 1 ) was synthesized via a facile strategy. The sodium salt ( 2 ) based on this ligand was prepared and these two compounds were fully characterized by using elemental analysis, IR and mass spectrometry and single‐crystal X‐ray diffraction. Their density, heats of formation, thermal stability and sensitivity, as well as the energetic properties from EXPLO5 code were investigated. These newly synthesized compounds possess high positive heats of formation and detonation heats. Compound 1 exhibits good detonation performance and acceptable stability, and might be a potential eco‐friendly alternative of lead azide. The present study contributes to the development of tetrazole derivatives as new energetic materials.     

Selective catalytic reduction of NO by C2H2 over Ce-Al2O3 catalyst with rate-determining step of NO oxidation

Ce-Al2O3 catalysts prepared by co-precipitation are investigated both in NO oxidation by O2 and in selective catalytic reduction of NO by C2H2(C 2 H 2-SCR).It is found that C2H2-SCR is initiated and controlled by NO oxidation to NO 2 over Al2O3.Ce loading on Al2O3 is almost inactive for NO oxidation below 350 C,since NO2 strongly adsorbs on cerium oxide,leading to the active sites being blocked,which was characterized by temperature-programmed desorption of NO and NO 2 and Fourier transform infrared spectroscopy after NO+O 2 coadsorption over the samples.However,in the case of C2H2-SCR,Ce loading on Al 2 O 3 significantly improves the reaction by accelerating the NO oxidation step in the temperature range of 250-450 C,since the nitrate species produced by NO 2 adsorption is an active intermediate required by C2H 2-SCR.     

车辆-轨道系统垂向随机振动的辛方法分析

将轨道视为无限长的周期结构,建立车辆轨道垂向耦合模型. 使用虚拟激励法将随机的轨道不平顺激励转化为确定性的简谐激励,再用辛数学方法求解轨道结构的频率响应特性和耦合系统的响应功率谱. 整个计算模型只有26个自由度,求解过程快速而精确.数值算例中,将该方法与常规有限元方法进行了比较,验证了方法的高效性和正确性,讨论了车辆速度对系统随机响应的影响.      

Effects of heat treatment and SOC on fire behaviors of lithium-ion batteries pack

Journal of Thermal Analysis and Calorimetry - Numerous lithium-ion battery fire accidents raise comprehensive safety concerns in modern society. In this paper, an experimental study was conducted...     

A High-Yield and Cost-Effective Synthesis of Spirotetramat

Russian Journal of Organic Chemistry - cis-8-Methoxy-1,3-diazaspiro[4.5]decane-2,4-dione, the key intermediate in the synthesis of spirotetramat, was synthesized by catalytic hydrogenation,...     

From β-Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic-Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra

Two new sodium aluminum borates, Na₃AlB₈O₁₅ and Na₃Al₂B₇O₁₅, have been successfully synthesized by the high-temperature solution method. They crystallize in the different space groups, P2₁/c and P2/c, respectively. The B−O configurations of β-Na₂B₆O₁₀, Na₃AlB₈O₁₅ and Na₃Al₂B₇O₁₅ are compared to feature complicated different dimensional open-framework structures caused by the substitution of [BO₄] by [AlO₄] covalent tetrahedra. Moreover, the experimental results indicate that Na₃AlB₈O₁₅ and Na₃Al₂B₇O₁₅ have short ultraviolet (UV) cutoff edges (<187 nm). The first-principles calculations show that Na₃AlB₈O₁₅ and Na₃Al₂B₇O₁₅ have moderate birefringence (0.075 and 0.041@1064 nm, respectively).