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排序方式: 共有149条查询结果,搜索用时 15 毫秒
11.
Nonlinear Dynamics - In this paper, a novel fixed-time second-order sliding mode (SOSM) controller has been developed for a class of nonlinear systems with output constraints. Based on the output... 相似文献
12.
Yanan Jiang Wenjie Ma Yujuan Qiao Yifei Xue Jiahao Lu Jun Gao Nannan Liu Fei Wu Ping Yu Lei Jiang Lanqun Mao 《Angewandte Chemie (International ed. in English)》2020,59(31):12795-12799
Biological ion channels and ion pumps with sub‐nanometer sizes modulate ion transport in response to external stimuli. Realizing such functions with sub‐nanometer solid‐state nanopores has been an important topic with wide practical applications. Herein, we demonstrate a biomimetic photoresponsive ion channel and photodriven ion pump using a porphyrin‐based metal–organic framework membrane with pore sizes comparable to hydrated ions. We show that the molecular‐size pores enable precise and robust optoelectronic ion transport modulation in a broad range of concentrations, unparalleled with conventional solid‐state nanopores. Upon decoration with platinum nanoparticles to form a Schottky barrier photodiode, photovoltage across the membrane is generated with “uphill” ion transport from low concentration to high concentration. These results may spark applications in energy conversion, ion sieving, and artificial photosynthesis. 相似文献
13.
染料敏化TiO2/WO3薄膜电池的光电变色 总被引:2,自引:0,他引:2
用光电化学方法研究了染料Ru(П) (4, 4′di COOEt 2, 2′bpy)2 (2, 2′bpy 4, 4′di CONH L tyrosineethylester) (PF6)2 (简写为Ru4)敏化TiO2 纳米结构电极的光电转换过程,同时,在导电玻璃上电沉积得到WO3 薄膜.结果表明,染料敏化的TiO2 多孔膜具有光电转换性能, WO3 薄膜具有良好的电致变色效应,将前者与电沉积得到的WO3 薄膜组成电池,在白光照射下可产生显著的颜色变化,有望用于自供电源的电色灵巧窗(Self poweredsmartwindow). 相似文献
14.
用状态向量法,引出陀螺线性系统的广义本征问题,证明了本征向量之间的加权共轭辛正交关系,以及用本征向量对任意状态向量的展开定理。运用反对称矩阵胞块组成的LDL~T分解,将本征方程导向辛本征问题的标准型。这套方法适用于陀螺系统K阵不正定的情形。对于辛本征问题用SH变换将矩阵化为半边三对角线胞块阵或三对角线胞块阵,然后再求解其全部本征解。为陀螺系统的模态分析打下了基础。 相似文献
15.
Yinwu Li Jiahao Liu Dr. Xiao Huang Prof. Dr. Ling-Bo Qu Prof. Dr. Cunyuan Zhao Prof. Dr. Robert Langer Prof. Dr. Zhuofeng Ke 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(60):13785-13798
As a new type of bifunctional catalyst, the Lewis acid transition-metal (LA-TM) catalysts have been widely applied for hydrogen activation. This study presents a mechanistic framework to understand the LA-TM-catalyzed H2 activation through DFT studies. The mer(trans)-homolytic cleavage, the fac(cis)-homolytic cleavage, the synergetic heterolytic cleavage, and the dissociative heterolytic cleavage should be taken as general mechanisms for the field of LA-TM catalysis. Four typical LA-TM catalysts, the Z-type κ4-L3B-Rh complex tri(azaindolyl)borane-Rh, the X-type κ3-L2B-Co complex bis-phosphino-boryl (PBP)-Co, the η2-BC-type κ3-L2B-Pd complex diphosphine-borane (DPB)-Pd, and the Z-type κ2-LB-Pt complex (boryl)iminomethane (BIM)-Pt are selected as representative models to systematically illustrate their mechanistic features and explore the influencing factors on mechanistic variations. Our results indicate that the tri(azaindolyl)borane-Rh catalyst favors the synergetic heterolytic mechanism; the PBP-Co catalyst prefers the mer(trans)-homolytic mechanism; the DPB-Pd catalyst operates through the fac(cis)-homolytic mechanism, whereas the BIM-Pt catalyst tends to undergo the dissociative heterolytic mechanism. The mechanistic variations are determined by the coordination geometry, the LA-TM bonding nature, the electronic structure of the TM center, and the flexibility or steric effect of the LA ligands. The presented mechanistic framework should provide helpful guidelines for LA-TM catalyst design and reaction developments. 相似文献
16.
The stationary random responses of nonlinear shear-type Multi-Degrees-of-Freedom (MDOF) hysteretic system are analyzed by
using the Pseudo Excitation Method (PEM) combined with the Equivalent Linearization Method (ELM). The solution of the equivalent
linear system is obtained by iteratively solving complex algebraic equations instead of the Lyapunov equations. The efficiency
of this method is much higher for practical engineering systems with many degrees-of-freedom.
Supported by NNSFC (Project No. 19772009), NKBRSF fund (No. G1999032805) and Doctoral Funding of State Education Ministry
(No. 97014120). 相似文献
17.
应用光电化学方法研究了两种菁类染料Cy3和Cy5复合敏化TiO2纳米晶电极的光电化学行为.结合两种染料的紫外-可见光谱和循环伏安曲线,确定了Cy3和Cy5的电子基态和激发态能级位置.结果表明两种染料的激发态能级位置能与TiO2纳米粒子导带边位置相匹配,复合敏化可以显著提高TiO2纳米晶的光电流,使TiO2纳米晶电极吸收波长由紫外光区红移至可见光区和近红外区.复合敏化降低了染料Cy3 在电极吸附时的聚集程度,使其单色光的转换效率(IPCE)提高了169%,复合敏化电极总的光电转换效率η为2.09%,分别是Cy3和Cy5单独敏化时光电转换效率的2.069 和1.229倍. 相似文献
18.
受非均匀调制演变随机激励结构响应快速精确计算 总被引:5,自引:4,他引:5
本文假定结构受到非均匀调制的演变随机激励,亦即其调制函数是时间与频率二者的函数,导出了有关的虚拟激励算法,并采用精细逐步积分格式,进行时变功率谱计算,获得了很高的计算效率和精度。 相似文献
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