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61.
Photoactive two-dimensional covalent organic frameworks (2D-COFs) have become promising heterogenous photocatalysts in visible-light-driven organic transformations. Herein, a visible-light-driven selective aerobic oxidation of various small organic molecules by using 2D-COFs as the photocatalyst was developed. In this protocol, due to the remarkable photocatalytic capability of hydrazone-based 2D-COF-1 on molecular oxygen activation, a wide range of amides, quinolones, heterocyclic compounds, and sulfoxides were obtained with high efficiency and excellent functional group tolerance under very mild reaction conditions. Furthermore, benefiting from the inherent advantage of heterogenous photocatalysis, prominent sustainability and easy photocatalyst recyclability, a drug molecule (modafinil) and an oxidized mustard gas simulant (2-chloroethyl ethyl sulfoxide) were selectively and easily obtained in scale-up reactions. Mechanistic investigations were conducted using radical quenching experiments and in situ ESR spectroscopy, all corroborating the proposed role of 2D-COF-1 in photocatalytic cycle.  相似文献   
62.
63.
We study the well‐posedness of the fractional differential equations with infinite delay on Lebesgue–Bochner spaces and Besov spaces , where A and B are closed linear operators on a Banach space X satisfying ,  and . Under suitable assumptions on the kernels a and b, we completely characterize the well‐posedness of in the above vector‐valued function spaces on by using known operator‐valued Fourier multiplier theorems. We also give concrete examples where our abstract results may be applied.  相似文献   
64.
In this paper, we study the well-posedness of the third-order differential equation with finite delay(P_3): αu'"(t) + u"(t) = Au(t) + Bu'(t) + Fut +f(t)(t ∈ T := [0,2π]) with periodic boundary conditions u(0) = u(2π), u'(0) = u"(2π),u"(0)=u"(2π) in periodic Lebesgue-Bochner spaces Lp(T;X) and periodic Besov spaces B_(p,q)~s(T;X), where A and B are closed linear operators on a Banach space X satisfying D(A) ∩ D(B) ≠ {0}, α≠ 0 is a fixed constant and F is a bounded linear operator from Lp([-2π, 0]; X)(resp. Bp,qs([-2π, 0]; X)) into X, ut is given by ut(s) = u(t + s) when s ∈ [-2π,0]. Necessary and sufficient conditions for the Lp-well-posedness(resp. B_(p,q)~s-well-posedness)of(P_3) are given in the above two function spaces. We also give concrete examples that our abstract results may be applied.  相似文献   
65.
The rational designability and chemical tunability of metal-organic frameworks(MOFs)are enabling tributes to efficaciously enhance their room temperature phosphorescence(RTP)performance.A family of stable anionic MOFs,[Zn2(4,5-ImDC)2]M2(NKU-132,M=(CH3)2NH2or(CH2CH3)2NH2),featuring significant RTP have been synthesized.By rational cation selection and in-situ replacement from dimethylammonium to diethylammonium,the phosphorescence lifetime is increased from 30.88 to126.3 ms,along with less sensitivity to air.This work provides an anti-quenching and lifetime tuning example for RTP-MOFmaterials via facile host-guest chemistry.  相似文献   
66.
To utilize waste heat from fishing boats, an organic Rankine cycle/vapor compression cycle system was employed for ice making and a thermodynamic model was developed. Six working fluids were selected and compared in order to identify suitable working fluids which may yield high system efficiencies. The calculated results show that R600a is most suitable working fluid through comprehensive comparison of efficiency, size parameter, pressure ratio, coefficient of performance, system pressure and safety.  相似文献   
67.
A four-directional benzene-centered aliphatic polyamine, MXBDP, with high functionality and low volatility, is used to cure epoxy resin (DGEBA). Herein we originally report the isothermal cure kinetics and dynamic mechanical properties of DGEBA/MXBDP. Differential scanning calorimetry confirms that MXDBP is more reactive than commercial linear metaxylenediamine and branched Jeffamine T-403 and the isothermal curing reaction is autocatalytic. The Kamal model is found to be able to well describe the curing rate up to the onset of diffusion control, and the excellent match over the whole conversion range is achieved using the extended Kamal model. Interestingly, the isoconversional kinetic analysis indicates that the effective reaction activation energy (E α ) changes substantially with conversion, and ultimately decreases to a very small value (<10 kJ mol?1) because of the diffusion-controlled reaction kinetics. Then, dynamic mechanical analysis reveals that DGEBA/MXBDP exhibits the higher α- and β-relaxation temperatures and the much higher crosslink density than DGEBA/metaxylenediamine. Our experiment results support that MXBDP has the high reactivity and improved thermal resistance in combination with the advantages of the high functionality, low volatility and decreased CO2 absorption. Therefore, MXBDP may be especially suitable for room temperature-cure epoxy coatings and adhesives.  相似文献   
68.
Three new cobalt complexes, {[Co5(tci)2(bimb)33-O)2(H2O)2]·3DMF·4H2O} n (1), {[Co3(tci)2(bib)]·2DMF·2H2O} n (2) and {[Co(Htci)(bpea)0.5]·H2O} n (3) (H3tci = tris(2-carboxyethyl)isocyanurate, bimb = 4,4′-bis(imidazol-1-yl)biphenyl, bib = 1,4-bis(imidazol-1-yl)benzene, bpea = 1,2-bis(4-pyridyl)ethane, DMF = N,N′-dimethylformamide), have been successfully synthesized through the assembly of Co(II) ions, H3tci and different N-donor ligands, respectively. All complexes were structurally characterized by single crystal X-ray diffraction, elemental analyses, IR spectra, thermogravimetric (TG) analyses and X-ray powder diffraction (XRPD). Complex 1 exhibits a 3D three-fold parallel interpenetrated 3D → 3D structure with (65·8) CdSO4 topology. Complex 2 is built from [Co32-Ocarboxyl)2(CO2)4] clusters and linear bib ligands, displaying a two-fold parallel interpenetrated (3,8)-connected (43)2(46·618·84) topology, while complex 3 is a 3D pillar-layered structure involving an infinite -Co-(µ2-Ocarboxyl)(CO2)-Co-chain. The diverse structures of the three complexes indicate that the skeletons of different N-donor ligands play an important role in the assembly of such different frameworks. In addition, magnetic investigation indicates that besides spin-orbit coupling of Co(II) ions, there exist antiferromagnetic exchange interactions in Co5 and Co3 clusters of 1 and 2, respectively.  相似文献   
69.
Chemomics is an interdisciplinary study using approaches from chemoinformatics,bioinformatics,synthetic chemistry,and other related disciplines.Biological systems make natural products from endogenous small molecules (natural product building blocks) through a sequence of enzyme catalytic reactions.For each reaction,the natural product building blocks may contribute a group of atoms to the target natural product.We describe this group of atoms as a chemoyl.A chemome is the complete set of chemoyls in an organism.Chemomics studies chemomes and the principles of natural product syntheses and evolutions.Driven by survival and reproductive demands,biological systems have developed effective protocols to synthesize natural products in order to respond to environmental changes;this results in biological and chemical diversity.In recent years,it has been realized that one of the bottlenecks in drug discovery is the lack of chemical resources for drug screening.Chemomics may solve this problem by revealing the rules governing the creation of chemical diversity in biological systems,and by developing biomimetic synthesis approaches to make quasi natural product libraries for drug screening.This treatise introduces chemomics and outlines its contents and potential applications in the fields of drug innovation.  相似文献   
70.
Poly(ethylene glycol) functionalized carbon nanotubes (CNTs-PEG) have attracted great research interest due to their good biocompatibility and wide applications in biomedical areas, such as drug delivery, bioimaging and photothermal therapy. The biodistribution studies are fundamental and essential to the biomedical applications and toxicological evaluations of CNTs-PEG, while isotopic labeling is the most adopted method for the quantitation of CNTs in vivo. Herein, we studied the biodistribution of hydroxyl terminated CNTs-PEG (CNTs-PEG-OH) in mice using 125I-labeling technique. The blood concentrations and accumulation levels of CNTs-PEG-OH in different organs were quantitatively analyzed by detecting the radioactivity of 125I labeled on CNTs-PEG-OH. The results indicated that CNTs-PEG-OH were quickly cleared from blood circulation and distributed to the entire body, except brain. CNTs-PEG-OH were mainly sequestrated by liver after intravenous injection. The hepatic accumulation decreased along with time elapse. Prolonging the PEG chains led to the decrease of hepatic accumulation, while the biodistribution pattern was similar. The implications to the biomedical applications and safety evaluations of CNTs-PEG are discussed.  相似文献   
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